hexa-Si-chloro-Si,Si'-cyclopentane-1,3-diyl-bis-silane | 18132-84-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: hexa-Si-chloro-Si,Si'-cyclopentane-1,3-diyl-bis-silane
• 英文别名: Hexa-Si-chlor-Si,Si'-cyclopentan-1,3-diyl-bis-silan；1,3-Bis-trichlorsilyl-cyclopentan；1,3-bis(trichlorosilyl)cyclopentane；Trichloro-(3-trichlorosilylcyclopentyl)silane
• CAS: 18132-84-8
• 化学式: C₅H₈Cl₆Si₂
• 分子量: 337.008
• InChiKey: ZXGMRGXRFGAHKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.22
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  环戊二烯 在 三氯硅烷 作用下， 生成 hexa-Si-chloro-Si,Si'-cyclopentane-1,3-diyl-bis-silane
  参考文献：
  名称：

  Mixed Germ Cell Tumor of the Ovary with Sarcomatous Component

  摘要：

  Germ cell tumors constitute a very complicated group of tumors of the ovary and their histogenesis is not yet clarified. Besides their histological heterogeneity, sarcomatous areas have also been described. A right ovarian mass was found in a 23-year-old female, who was being treated in the hospital for miscarriage. Disseminated omental metastases were detected during abdominal laparotomy. Pathological examination of the dissected material revealed the tumor to be a mixed germ cell tumor (immature teratoma and dysgerminoma) with sarcomatous component. Areas resembling granulosa cell tumor were also encountered. This ovarian tumor with many different histopathological features is presented with a review of the literature. The importance of thorough sampling in determining the type and extent of the malignant components is also emphasized due to their direct relation with the prognosis.

  DOI：

  10.1007/bf03032607
• 作为试剂：
  描述：

  二聚环戊二烯 、 三氯硅烷 、 正十六烷 在 stainless steel 、 氮气 、 hexa-Si-chloro-Si,Si'-cyclopentane-1,3-diyl-bis-silane 、 三氯硅烷 、 甲苯 、 正十六烷 作用下， 以 甲苯 为溶剂， 反应 1.0h， 以providing a mixture (203.6 g) of (2-cyclopentenyl)trichlorosilane (34.4 g, 76%), 1,3-bis(trichlorosilyl)cyclopentane (1.4%), unreacted trichlorosilane, toluene and hexadecane的产率得到三氯(环戊-2-烯-1-基)硅烷
  参考文献：
  名称：

  (2-Cyclopentenyl)chlorosilanes and their preparation methods

  摘要：

  本发明涉及（2-环戊烯基）氯硅烷衍生物及其制备方法。具体而言，本发明涉及一种非常经济的方法，该方法在升高的温度下，将由工业生产的低价二环戊二烯裂解产生的环戊二烯与含有硅氢键的硅烷化合物在沸点预定范围内的烃化合物中反应，从而也能够通过使用烃化合物来防止二环戊二烯聚合的问题。此外，在第10族金属化合物催化剂的存在下，本方法能够降低反应温度并增加反应难处理的烷基二氯硅烷的产量。（2-环戊烯基）氯硅烷可用于制备含有不饱和基团或功能性硅氧烷聚合物的有机硅化合物，或用于表面修饰或制造薄层。

  公开号：

  US20070191622A1

文献信息

• Mixed Germ Cell Tumor of the Ovary with Sarcomatous Component
  作者：Fevziye Kabukcuoglu、Ay∘im Sungun、Billur Akan Sentürk、Ismail Evren、Ridvan Ilhan

  DOI：10.1007/bf03032607

  日期：2001.3

  Germ cell tumors constitute a very complicated group of tumors of the ovary and their histogenesis is not yet clarified. Besides their histological heterogeneity, sarcomatous areas have also been described. A right ovarian mass was found in a 23-year-old female, who was being treated in the hospital for miscarriage. Disseminated omental metastases were detected during abdominal laparotomy. Pathological examination of the dissected material revealed the tumor to be a mixed germ cell tumor (immature teratoma and dysgerminoma) with sarcomatous component. Areas resembling granulosa cell tumor were also encountered. This ovarian tumor with many different histopathological features is presented with a review of the literature. The importance of thorough sampling in determining the type and extent of the malignant components is also emphasized due to their direct relation with the prognosis.
• (2-Cyclopentenyl)chlorosilanes and their preparation methods
  申请人：Yoo Bok Ryul

  公开号：US20070191622A1

  公开（公告）日：2007-08-16

  The present invention relates to (2-cyclopentenyl)chlorosilane derivatives and the preparation method thereof. In particular, it relates to a very economical process which reacts cyclopentadiene, which is formed by a cracking of industrially produced low-priced dicyclopentadiene, with a silane compound containing silicon-hydrogen bonds at elevated temperature in a hydrocarbon compound with a boiling point of a predetermined range, thus also enabling to prevent problematic production of dicyclopentadiene polymer by using the hydrocarbon compound. Further, in the presence of a group 10 metal compound catalyst, the process herein is capable of lowering the reaction temperature and increasing the yield in the reaction of sterically hindered alkyl-dichlorosilane. The (2-cyclopentenyl)chlorosilane may be useful in preparing an organic silicon compound containing an unsaturated group or a functional silicone polymer using the same, or in modifying the surface or manufacturing a thin layer.

  本发明涉及（2-环戊烯基）氯硅烷衍生物及其制备方法。具体而言，本发明涉及一种非常经济的过程，该过程在具有预定沸点范围的碳氢化合物中，通过在升高的温度下将工业生产的低价二环戊二烯裂解产生的环戊二烯与含有硅氢键的硅烷化合物反应，从而还能够通过使用碳氢化合物来防止产生问题的二环戊二烯聚合物的生产。此外，在第10族金属化合物催化剂的存在下，本过程能够降低反应温度并提高反应中的立体位阻烷基二氯硅烷的产量。 （2-环戊烯基）氯硅烷可以用于制备含有不饱和基团或功能性有机硅聚合物，或用于表面改性或制造薄层。