(2,3-epoxypropyl)-1,3,5-triazabenzene-2,4,6(1H,3H,5H)-trione | 146692-58-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: (2,3-epoxypropyl)-1,3,5-triazabenzene-2,4,6(1H,3H,5H)-trione
• 英文别名: (2,3-epoxypropyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione；(2,3-epoxypropyl)isocyanuric acid；2,3-epoxypropyl isocyanurate；monoglycidylisocyanuric acid；MONOGLYCIDYL ISOCYANURATE；glycidyl isocyanurate；1-[(Oxiran-2-yl)methyl]-1,3,5-triazinane-2,4,6-trione；1-(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 146692-58-2
• 化学式: C₆H₇N₃O₄
• 分子量: 185.139
• InChiKey: NBZYOWJKOWTTRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.3
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  91
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  氰尿酸 、 环氧氯丙烷 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 10.0h， 生成 (2,3-epoxypropyl)-1,3,5-triazabenzene-2,4,6(1H,3H,5H)-trione
  参考文献：
  名称：

  Epoxy-Triazinetrione-Functionalized Magnetic Nanoparticles as an Efficient Magnetic Nanoadsorbent for the Removal of Malachite Green and Pb(II) from Aqueous Solutions

  摘要：

  In this study, a new epoxy-triazinetrione (ETT)-functionalized magnetic nanoadsorbent (Fe3O4-ETT) has been developed for the removal of malachite green (MG) and Pb(II) from aqueous solutions. Fe3O4-ETT as a nano-adsorbent was successfully synthesized through chemical modification of Fe3O4 nanoparticles with ETT. Characterization of Fe3O4-ETT nanoparticles using Fourier transform infrared, field emission scanning electron microscopy, transmission electron microscopy, energydispersive X-ray, X-ray diffraction, thermogravimetric analysis, vibrating sample magnetometer, and Brunauer-Emmett-Teller (BET) analyses revealed that the Fe3O4 nanoparticles were effectively modified with ETT. Numerous amine and hydroxyl groups of the triazine ring on the nano-Fe3O4 particles were mainly responsible for the adsorption of cationic organic dye and heavy metals through multiple interactions. Based on the BET analysis, an improved surface area from 42,000 to 84,788 m(2) kg(-1) was achieved after the surface modification of Fe3O4 NPs by ETT. The adsorption isotherm experiments revealed that the adsorption processes of MG and Pb(II) were better described via applying the Freundlich isotherm model. Moreover, the kinetic pseudosecond-order model better described the adsorption data. The results also showed that the MG and Pb(II) pollutants could be adsorbed by the Fe3O4-ETT through two different adsorption mechanisms, including electrostatic interactions and surface complexation, respectively. In addition, the magnetic nano-adsorbent can be regenerated and reused for MG and Pb(II) removal from waters in several adsorption cycles. Thus, the excellent regeneration, low cost, and an easy synthesis route make Fe3O4-ETT an efficient nano-adsorbent for purification of water and wastewater contaminated by organic and inorganic pollutants.

  DOI：

  10.1021/acs.jced.0c00063

文献信息

• MONOGLYCIDYL ISOCYANURATE COMPOUND AND PRODUCTION METHOD THEREFOR
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US20190135795A1

  公开（公告）日：2019-05-09

  There are provided a novel isocyanurate compound having a glycidyl group as a substituent to be bonded to a nitrogen atom. A monoglycidyl isocyanurate compound of the following Formula (1), (2), or (3). (wherein two R 1 s are each a C 2-10 alkyl group, two R 2 s are each a C 1-5 alkylene group, two R 3 s are each a C 1-2 alkyl group, two R 4 s are each a C 1-2 alkylene group, and two R 5 s are each a C 1-2 alkyl group.)

  提供了一种新的异氰酸酯化合物，其具有作为取代基的环氧丙烯基与氮原子结合。以下是一种单环氧丙烯基异氰酸酯化合物的化学式（1）、（2）或（3）。其中两个R1均为C2-10烷基基团，两个R2均为C1-5烷基烯基团，两个R3均为C1-2烷基基团，两个R4均为C1-2烷基烯基团，两个R5均为C1-2烷基基团。
• Alternating copolymers of isobutylene type monomers
  申请人：——

  公开号：US20030170394A1

  公开（公告）日：2003-09-11

  A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

  一种共聚物组成物，包括至少30摩尔％的残基的共聚物，该残基来自给体单体和受体单体的以下交替残基。 该共聚物含有至少15摩尔％的异丁烯型给体单体和至少15摩尔％的丙烯酸单体作为受体单体。 该共聚物基本上不含马来酸或富马酸单体片段，且该共聚物组成物基本上不含路易斯酸和过渡金属。 还披露了一种热固性组合物，其中包括具有功能基的反应物，具有至少两个与第一反应物中的功能基反应的交联剂，以及包括共聚物组成物的共聚物流控制剂，以及用热固性组合物涂覆的基板。
• Albumin-fixed resin, process for its production, method of using it to remove noxious substances from solutions containing them, and its use in removing noxious substances from blood
  申请人：TEIJIN LIMITED

  公开号：EP0028937A2

  公开（公告）日：1981-05-20

  The invention provides an albumin-fixed resin comprising a crosslinked water-insoluble resin and albumin chemically bound thereto, said water-insoluble resin being a crosslinked epoxy resin containing 1 to 30 milliequivalents of amino groups and 1 to 50 milliequivalents of hydroxyl groups per gram thereof, said albumin being bound ionically to the amino groups and by hydrogen bonding to the hydroxyl groups, and the amount of said albumin fixed being at least 25% by weight based on the epoxy resin. Also provided is a process for producing the albumin-fixed resin, which process comprises (1) (a) subjecting a polyepoxy compound containing at least two epoxy groups in the molecule, and a polyamine compound containing at least two primary and/or secondary amino groups in the molecule to addition reaction in an inert medium to produce a fully crosslinked resin, or (b) subjecting said polyepoxy and polyamine compounds to addition reaction to produce an incompletely crosslinked pre-polymer, and then reacting the pre-polymer with at least one organic polyisocyanate, organic polyisothiocyanate or organic polycarboxylic acid halide to crosslink the pre-polymer fully, and (2) contacting the resulting crosslinked epoxy resin containing 1 to 30 milliequivalents of amino groups and 1 to 50 milliequivalents of hydroxyl groups per gram thereof intimately with an aqueous solution containing albymin, optionally after partially neutralizing the amino groups of the epoxy resin. The albumin-fixed resin is useful for removing noxious substances capable of binding to albumin, such as bilirubin, from the blood of a warm-blooded animal.

  本发明提供了一种白蛋白固定树脂，包括交联的水不溶性树脂和与之化学结合的白蛋白，所述水不溶性树脂是一种交联环氧树脂，每克含有 1 至 30 毫当量的氨基和 1 至 50 毫当量的羟基，所述白蛋白通过离子键与氨基结合，并通过氢键与羟基结合，所述固定白蛋白的量至少为环氧树脂重量的 25%。 还提供了一种生产白蛋白固定树脂的工艺，该工艺包括 (1) (a) 将分子中含有至少两个环氧基团的聚环氧化合物和分子中含有至少两个伯氨基 和/或仲氨基的聚胺化合物在惰性介质中进行加成反应，生成全交联树脂、或 (b) 使所述聚环氧化合物和聚胺化合物进行加成反应，生成不完全交联的预聚 物，然后使该预聚物与至少一种有机多异氰酸酯、有机多异硫氰酸酯或有 机多羧酸卤化物反应，使该预聚物完全交联，以及 (2) 将得到的每克含有 1 至 30 毫当量氨基和 1 至 50 毫当量羟基的交联环氧树脂 与含有白胺的水溶液紧密接触，可选择在部分中和环氧树脂的氨基之后进 行。 白蛋白固定树脂可用于去除温血动物血液中能与白蛋白结合的有害物质，如胆红素。
• Verfahren zur Herstellung elektrisch isolierender Verbundwerkstoffe
  申请人：SIEMENS AKTIENGESELLSCHAFT

  公开号：EP0132746A1

  公开（公告）日：1985-02-13

  Elektrisch isolierende Verbundwerkstoffe auf der Basis vemetzter Epoxidharze und einer Faserverstärkung aus einem Polymermaterial, eiche ein hohes Festigkertsniveau aufweisen, werden dann erhalten, wenn die Vernetzung der Epoxidharze durch anionische Polymerisation unter Verwendung von tertiären Aminen der allgemeinen Formel als Polymerisationskatalysator erfolgt.

  以交联环氧树脂和高分子材料纤维增强体为基础的电绝缘复合材料具有很高的强度，当环氧树脂通过阴离子聚合交联时，使用通式为 作为聚合催化剂，通过阴离子聚合交联得到具有高强度的环氧树脂和纤维增强材料。
• Method for solidifying triglycidyl isocyanurate
  申请人：NISSAN CHEMICAL INDUSTRIES LTD.

  公开号：EP0232869A2

  公开（公告）日：1987-08-19

  A method for producing pulverizable solid triglycidyl isocyanurate, which comprises dispersing triglycidyl isocyanurate powder as seed to molten triglycidyl isocyanurate formed by the reaction of isocyanuric acid with epichlorohydrin, at a temperature of from 70 to 115°C and cooling the dispersion.

  一种生产可粉碎固体异氰尿酸三缩水甘油酯的方法，包括将异氰尿酸三缩水甘油酯粉末作为种子分散到异氰尿酸与环氧氯丙烷反应形成的熔融异氰尿酸三缩水甘油酯中，温度为 70 至 115°C，然后冷却分散液。