monophenyl isophthalate | 37970-35-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: monophenyl isophthalate
• 英文别名: 3-Phenoxycarbonylbenzoic acid
• CAS: 37970-35-7
• 化学式: C₁₄H₁₀O₄
• 分子量: 242.231
• InChiKey: CDMACSHLSBAJGG-UHFFFAOYSA-N

物化性质

• 熔点：
  139 °C
• 沸点：
  447.0±28.0 °C(Predicted)
• 密度：
  1.306±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  一氧化碳 、 sodium phenoxide 、 3-碘苯甲酸 在 palladium diacetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 60.0 ℃ 、101.32 kPa 条件下， 反应 30.0h， 以71%的产率得到monophenyl isophthalate
  参考文献：
  名称：

  Bumagin, N. A.; Nikitin, K. V.; Andryukhova, N. P., Doklady Chemistry, 1991, vol. 318, # 4-6, p. 155 - 159

  摘要：

  DOI：

文献信息

• Alpha-olefins and olefin polymers and processes therefor
  申请人：——

  公开号：US20030171508A1

  公开（公告）日：2003-09-11

  Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.

  本文披露了聚合乙烯、无环烯烃、和/或选择性环烯烃，以及可选的烯酸酯或羧酸和其他单体的过程。这些聚合反应由选择的过渡金属化合物催化，有时还有其他辅助催化剂。由于其中一些聚合反应表现出一些活性聚合反应的特征，因此可以轻松制备嵌段共聚物。许多聚合物通常具有新颖的特性，特别是在微观结构方面，这使得其中一些聚合物具有不寻常的性质。披露了许多新颖的催化剂，以及制备它们的一些新颖过程。制造的聚合物可用作弹性体、模塑树脂、粘合剂等。本文还描述了通过使用镍化合物具有选择的α-二亚胺配体和选择的Lewis或Bronsted酸作为催化剂体系，或通过将选择的α-二亚胺镍配合物与乙烯接触来合成线性α-烯烃的合成方法。
• Polymerization of olefins
  申请人：——

  公开号：US20040102591A1

  公开（公告）日：2004-05-27

  Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.

  本文披露了一种聚合乙烯、无环烯烃和/或选定的环状烯烃，以及可选的选定的烯酸酯或羧酸和其他单体的过程。这些聚合物由选定的过渡金属化合物催化，有时也由其他协同催化剂催化。由于其中一些聚合物表现出一些活性聚合物的特征，因此可以轻松制备嵌段共聚物。许多生产的聚合物通常是新颖的，特别是在其微结构方面，这使得其中一些聚合物具有不寻常的性质。披露了许多新颖的催化剂，以及制备它们的一些新颖过程。制造的聚合物可用作弹性体、模塑树脂、粘合剂等。本文还描述了通过使用镍化合物具有选定的α-二亚胺配体和选定的Lewis或Bronsted酸的催化剂体系，或通过将选定的α-二亚胺镍配合物与乙烯接触，合成线性α-烯烃的方法。
• Process for the production of substantially monoester-free diaryl esters of aromatic dicarboxylic acids
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0273147A2

  公开（公告）日：1988-07-06

  An improved process for the preparation of a diaryl ester containing only small amounts of the corresponding monoesters comprises reacting a mixture of an aryl diacid, a monohydroxy aromatic compound and a catalyst, cooling, adding a controlled amount of water, and cooling further. Typically, diaryl esters, such as diphenyl isophthalate (DPI), contain­ing only about 1-5% of the monoester, such as monophenyl iso­phthalate are obtained upon addition to the reaction mixture of approximately 5-15% by weight of water at 60°-80°C, followed by cooling to about 15°-35°C.

  制备仅含有少量相应单酯的二芳基酯的改进工艺包括：使芳基二酸、单羟基芳香族化合物和催化剂的混合物反应，冷却，加入控制量的水，然后进一步冷却。 通常，在反应混合物中加入约 5-15% （重量百分比）的水，温度为 60°-80°C，然后冷却至约 15°-35°C，即可得到仅含有约 1-5% 的单酯（如间苯二甲酸二苯酯 (DPI)）的二芳基酯。
• Polyester resin exhibiting optical anisotropy in molten state and composition thereof
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0337728A2

  公开（公告）日：1989-10-18

  A polyester resin comprises 35 to 90 mole percent of the unit (I), 0.5 to 20 mole percent of the unit (II), 0.5 to 45 mole percent of the unit (III) and 0.5 to 45 mole percent of the unit (IV), exhibiting the anisotropy in its molten state. It may further comprise 0.5 to 45 mole percent of the unit (V). The composition is here presented, comprising the polyester resin as defined above and up to 95 percent by weight of an inorganic filler.

  一种聚酯树脂包含 35 至 90 摩尔百分率的单元 (I)、0.5 至 20 摩尔百分率的单元 (II)、0.5 至 45 摩尔百分率的单元 (III) 和 0.5 至 45 摩尔百分率的单元 (IV)，在熔融状态下表现出各向异性。它还可进一步包含 0.5 至 45 摩尔%的单元 (V)。这里介绍的组合物包括上文定义的聚酯树脂和高达 95%（重量）的无机填料。
• Filled sprayed polyurea elastomers
  申请人：TEXACO DEVELOPMENT CORPORATION

  公开号：EP0366297A2

  公开（公告）日：1990-05-02

  Filler material can be advantageously incorporated into spray elastomers, when the filler is dispensed into the spray pattern from a first reactive stream containing a aromatic polyisocyanate and a second reactive stream comprising an amine-terminated polyether having a molecular weight of more than 1500 prepared by the reductive amination of polyols and having more than 50% of its active hydrogen in the form of amine hydrogens, and a chain extender.

  当填料从包含芳香族多异氰酸酯的第一反应流和包含胺封端聚醚的第二反应流中分配到喷型中时，填料可以很好地掺入喷型弹性体中，胺封端聚醚的分子量大于 1500，由多元醇还原胺化制备而成，其 50%以上的活性氢以胺氢根的形式存在，还包含扩链剂。