p-acetoxybenzoyloxy-benzoic acid | 114943-43-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: p-acetoxybenzoyloxy-benzoic acid
• 英文别名: 4-(4-acetoxybenzoyloxy)benzoic acid；4-(4-Acetoxy-benzoyloxy)-benzoesaeure；4-Acetoxy-benzoesaeure-(4-carboxy-phenyl)-ester；Acetyl-(p-oxy-benzoyl)-(p-oxy-benzoesaeure)；4-{[4-(Acetyloxy)benzoyl]oxy}benzoic acid；4-(4-acetyloxybenzoyl)oxybenzoic acid
• CAS: 114943-43-0
• 化学式: C₁₆H₁₂O₆
• 分子量: 300.268
• InChiKey: JZJLRNMWQPRPOY-UHFFFAOYSA-N

物化性质

• 熔点：
  216 °C(Solv: ethyl acetate (141-78-6))
• 沸点：
  497.2±30.0 °C(Predicted)
• 密度：
  1.346±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  89.9
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  p-acetoxybenzoyloxy-benzoic acid 在 氨 、 丙酮 作用下， 生成 4-(4-羟基-苯甲酰氧基)-苯甲酸
  参考文献：
  名称：

  Fischer,E.; Kadisade, Chemische Berichte, 1919, vol. 52, p. 74

  摘要：

  DOI：
• 作为产物：
  描述：

  对羟基苯甲酸 生成 p-acetoxybenzoyloxy-benzoic acid
  参考文献：
  名称：

  Klepl, Journal fur praktische Chemie (Leipzig 1954), 1883, vol. <2> 28, p. 217

  摘要：

  DOI：

文献信息

• Low glass temperature organosiloxanes
  申请人：Consortium fur elektrochemische Industrie GmbH

  公开号：US06040411A1

  公开（公告）日：2000-03-21

  Organosiloxanes having low transition temperatures comprise at least one group of the general formula 1 --(CH.sub.2).sub.p --(O).sub.q --C.sub.6 H.sub.4 --Z--(COO).sub.s --[A--M].sub.t --E--(CH.sub.2 --CH.sub.2 --O).sub.a --VN (1) and, if desired, a group of the general formula 2 --(CH.sub.2).sub.m --(O).sub.n --(A).sub.t --Q--X (2) where VN is a group --COO--CH.dbd.CH.sub.2, --COO--C(CH.sub.3).dbd.CH.sub.2, --(CH.sub.2).sub.u --OCH.dbd.CH.sub.2, --CH.dbd.CH.sub.2 or an oxiranyl group and X, Z, A, M, Q, E, m, n, p, q, r, s, t, u, v and a are as defined herein.

  具有低转变温度的有机硅化合物至少包括以下一种通式1的基团--(CH.sub.2).sub.p --(O).sub.q --C.sub.6 H.sub.4 --Z--(COO).sub.s --[A--M].sub.t --E--(CH.sub.2 --CH.sub.2 --O).sub.a --VN (1)，以及如有需要，一种通式2的基团--(CH.sub.2).sub.m --(O).sub.n --(A).sub.t --Q--X (2)，其中VN为--COO--CH.dbd.CH.sub.2，--COO--C(CH.sub.3).dbd.CH.sub.2，--(CH.sub.2).sub.u --OCH.dbd.CH.sub.2，--CH.dbd.CH.sub.2或环氧基团，而X、Z、A、M、Q、E、m、n、p、q、r、s、t、u、v和a的定义如本文所述。
• Organosiloxane mit niedriger Glastemperatur
  申请人：Consortium für Elektrochemische Industrie GmbH

  公开号：EP0887399A1

  公开（公告）日：1998-12-30

  Die Organosiloxane weisen mindestens eine Gruppe der allgemeinen Formel 1         -(CH2)p-(O)q-C6H4-Z-(COO)s-[A-M]t-E-(CH2-CH2-O)a-VN     (1)    und gegebenenfalls eine Gruppe der allgemeinen Formel 2         -(CH2)m-(O)n-(A)t-Q-X     (2)    auf, wobei VNeine Gruppe -COO-CH=CH2, -COO-C(CH3)=CH2, -(CH2)u-OCH=CH2, -CH=CH2 oder eine Oxiranylgruppe bedeutet und X, Z, A, M, E, Q, m, n, p, q, r, s, t, u, v und a die in Anspruch 1 angegebenen Bedeutungen aufweisen.

  有机硅氧烷至少有一个通式 1 的基团 -(CH2)p-(O)q-C6H4-Z-(COO)s-[A-M]t-E-( - -O)a-VN (1) 和可选的通式 2 的基团 -( )m-(O)n-(A)t-Q-X (2) 其中 VN 是-COO-CH= 、-COO-C(CH3)= 、-( )u-OCH= 、-CH= 或环氧乙烷基团，且 X、Z、A、M、E、Q、m、n、p、q、r、s、t、u、v 和 a 具有权利要求 1 所述的含义。
• Hempel, Erika; Lindau, Juergen; Roetz, Uwe, Molecular Crystals and Liquid Crystals (1969-1991), 1990, vol. 193, p. 199 - 204
  作者：Hempel, Erika、Lindau, Juergen、Roetz, Uwe、Fischer, Hartmut、Utschick, Hermann、Kuschel, Frank

  DOI：——

  日期：——
• Polymer Whiskers Composed of <i>p</i>-Oxybenzoyl and <i>p</i>-Mercaptobenzoyl Having Graded Compositions
  作者：Kazufumi Kobashi、Kunio Kimura、Yuhiko Yamashita

  DOI：10.1021/ma035962f

  日期：2004.10.1

  Preparation of polymer whiskers composed of p-oxybenzoyl (O) units and p-mercaptobenzoyl (S) units having graded composition was examined by the polymerization of S-acetyl-4-mercaptobenzoic acid (AMBA) and 4-(4-acetoxybenzoyloxy)benzoic acid (OO) or 4-[4-(4-acetoxybenzoyloxy)benzoyloxy]benzoic acid (OOO). Polymerizations were carried out in liquid paraffin at 300 degreesC for 6 h. The polymerization concentration was 1.0% and the molar ratio of O units in feed was 50%. Polymerization of AMBA and OO yielded copolymer whiskers by means of the crystallization of oligomers, which were 15 mum in average length and 0.4 mum in average width. The length and the width increased with polymer yield but the length increased preferentially rather than the width. The number of whiskers was constant during polymerization. The content of O units in the whiskers (chi(O)) prepared for 8 min was 62 mol % and then decreased to 49 mol % after 6 h. This fact revealed that the center part of the whisker was rich in O units, and the outer and tip parts were rich in S units. This whisker possessed a graded composition from O units to S units along the directions of the length and width. The oligomers rich in O unit sequences were preferentially precipitated in the early stage of polymerization, and afterward the oligomers poor in O units were precipitated to form the whiskers leading to a graded composition. Polymerization of AMBA and OOO yielded copolymer whiskers with a larger gradient composition than that of whiskers prepared from AMBA and OO.
• Anschuetz, Justus Liebigs Annalen der Chemie, 1925, vol. 442, p. 41
  作者：Anschuetz

  DOI：——

  日期：——