1H,1H,2H,2H-perfluorooctyltriallylsilane | 193828-95-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 1H,1H,2H,2H-perfluorooctyltriallylsilane
• 英文别名: Tri(prop-2-en-1-yl)(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane；tris(prop-2-enyl)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
• CAS: 193828-95-4
• 化学式: C₁₇H₁₉F₁₃Si
• 分子量: 498.403
• InChiKey: NTSTZKPGQWYESW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.12
• 重原子数：
  31
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  1H,1H,2H,2H-perfluorooctyltriallylsilane 在 硼烷 、 sodium hydroxide 、 双氧水 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 以76%的产率得到
  参考文献：
  名称：

  Synthesis of perfluoroalkyl-containing multifunctional groups compounds for textile finishing

  摘要：

  A new kind of perfluoroalkyl-containing multifunctional groups compound was designed. Treatment of 1H,1H,2H,2H-perfluorooctyltrichlorosilane (4) with allylmagnesium bromide provided key intermediate 1H,1H,2H,2H-perfluorooctyltriallylsilane (2). Hydroboration followed by oxidation, epoxidation and dihydroxylation of 2 gave perfluoroalkyl-containing multifunctional groups compound 1a, 1b and 1c, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(01)00495-x
• 作为产物：
  描述：

  1H,1H,2H-全氟-1-辛烯 在 chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex 三氯硅烷 、 magnesium 作用下， 以 乙醚 为溶剂， 反应 30.0h， 生成 1H,1H,2H,2H-perfluorooctyltriallylsilane
  参考文献：
  名称：

  Synthesis of perfluoroalkyl-containing multifunctional groups compounds for textile finishing

  摘要：

  A new kind of perfluoroalkyl-containing multifunctional groups compound was designed. Treatment of 1H,1H,2H,2H-perfluorooctyltrichlorosilane (4) with allylmagnesium bromide provided key intermediate 1H,1H,2H,2H-perfluorooctyltriallylsilane (2). Hydroboration followed by oxidation, epoxidation and dihydroxylation of 2 gave perfluoroalkyl-containing multifunctional groups compound 1a, 1b and 1c, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(01)00495-x

文献信息

• Synthesis of perfluoroalkyl-containing multifunctional groups compounds for textile finishing
  作者：Feng-Ling Qing、Min Ji、Ronghua Lu、Kelu Yan、Zhiping Mao

  DOI：10.1016/s0022-1139(01)00495-x

  日期：2002.1

  A new kind of perfluoroalkyl-containing multifunctional groups compound was designed. Treatment of 1H,1H,2H,2H-perfluorooctyltrichlorosilane (4) with allylmagnesium bromide provided key intermediate 1H,1H,2H,2H-perfluorooctyltriallylsilane (2). Hydroboration followed by oxidation, epoxidation and dihydroxylation of 2 gave perfluoroalkyl-containing multifunctional groups compound 1a, 1b and 1c, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.