1-Methyl-1-[2-(1-methylpiperidin-1-ium-1-yl)ethyl]piperidin-1-ium

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1-Methyl-1-[2-(1-methylpiperidin-1-ium-1-yl)ethyl]piperidin-1-ium
• 化学式: C₁₄H₃₀N₂
• mdl: MFCD02110475
• 分子量: 226.406
• InChiKey: AIWZCTOUXBMFJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,2-二哌啶基乙烷 、 碘甲烷 以 乙腈 为溶剂， 生成 1-Methyl-1-[2-(1-methylpiperidin-1-ium-1-yl)ethyl]piperidin-1-ium
  参考文献：
  名称：

  Synthesis of Al-MTW with low Si/Al ratios by combining organic and inorganic structure directing agents

  摘要：

  富含铝的MTW型沸石具有较大的孔隙可进入性、高布朗斯特酸性和对正癸烷裂解的高活性。

  DOI：

  10.1039/c5nj01203a

文献信息

• IONIC LIQUID CONTAINING ALLYLSULFONATE ANION
  申请人：Watahiki Tsutomu

  公开号：US20120157680A1

  公开（公告）日：2012-06-21

  PROBLEM: Providing a novel ionic liquid, which is low-cost, environment-friendly, and has low viscosity and melting point. MEANS FOR SOLVING THE PROBLEM: The present invention is the invention of the ionic liquid represented by the general formula [1]: wherein, R 1 to R 3 and n pieces of R 4 each independently represent hydrogen atom or alkyl group having 1 to 4 carbon atoms, R 5 to R 7 each independently represent alkyl group, aralkyl group, or aryl group, R 8 represents alkyl group, aralkyl group, aryl group, or the one represented by the general formula [2]: (wherein T represents alkylene chain having 1 to 8 carbon atoms, n represents 1 or 2, and R 1 to R 7 are the same as the above-described), X represents nitrogen atom or phosphorus atom, n represents 1 or 2. When n is 1, R 3 and R 4 are bound and may form cyclohexene ring together with the adjacent carbon atoms. In addition, when X is nitrogen atom, R 5 to R 7 or R 5 to R 6 may form hetero ring with nitrogen atom binding thereto}.

  问题：提供一种新型离子液体，成本低、环保，并具有低粘度和熔点。 解决问题的方法：本发明是一种由通式[1]表示的离子液体的发明：其中，R1到R3和n个R4分别独立表示氢原子或具有1到4个碳原子的烷基基团，R5到R7分别独立表示烷基基团、芳基烷基基团或芳基基团，R8表示烷基基团、芳基烷基基团、芳基基团或由通式[2]表示的基团：（其中T表示具有1到8个碳原子的烷基链，n表示1或2，R1到R7与上述相同），X表示氮原子或磷原子，n表示1或2。当n为1时，R3和R4结合并且可能与相邻碳原子一起形成环己烯环。此外，当X为氮原子时，R5到R7或R5到R6可能与结合在一起的氮原子形成杂环}。
• POLYMER COMPOUND AND LIGHT-EMITTING ELEMENT USING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3045486A1

  公开（公告）日：2016-07-20

  A polymer compound comprising a constitutional unit represented by the following formula (1) and a constitutional unit represented by the following formula (X) and/or a constitutional unit represented by the following formula (Y), wherein the content of the hydroxyl groups contained in the polymer compound is less than 0.02 mol%: [wherein, Ar1 represents an arylene group and this group optionally has a substituent.] [wherein, aX1 and aX2 each independently represent an integer of 0 or more. ArX1 and ArX3 each independently represent an arylene group or a divalent heterocyclic group and these groups each optionally have a substituent. ArX2 and ArX4 each independently represent an arylene group, a divalent heterocyclic group or a divalent group in which at least one arylene group and at least one divalent heterocyclic group are bonded directly to each other, and these groups each optionally have a substituent. When there are a plurality of ArX2 and a plurality of ArX4, each of them may be the same or different. RX1, RX2 and RX3 each independently represent an alkyl group, an aryl group or a monovalent heterocyclic group and these groups each optionally have a substituent. When there are a plurality of RX2 and a plurality of RX3, each of them may be the same or different.] [wherein, ArY1 represents an arylene group, a divalent heterocyclic group or a divalent group in which at least one arylene group and at least one divalent heterocyclic group are bonded directly to each other, and these groups each optionally have a substituent.].

  一种聚合物化合物，由下式（1）代表的构型单元和下式（X）代表的构型单元和/或下式（Y）代表的构型单元组成、 其中聚合物化合物中所含羟基的含量小于 0.02 摩尔%： [其中，Ar1 代表芳烯基团，该基团可选择具有一个取代基。］ [其中，aX1 和 aX2 各自独立地代表 0 或 0 以上的整数。ArX1 和 ArX3 各自独立地代表芳烯基团或二价杂环基团，且这些基团各自可选地具有取代基。ArX2 和 ArX4 各自独立地代表芳烯类基团、二价杂环基团或其中至少一个芳烯类基团和至少一个二价杂环基团直接相互键合的二价基团，这些基团各自可选地具有取代基。当有多个 ArX2 和多个 ArX4 时，它们可以相同或不同。RX1、RX2 和 RX3 各自独立地代表烷基、芳基或单价杂环基团，且这些基团各自可选地具有取代基。当有多个 RX2 和多个 RX3 时，它们可以相同或不同]。 [其中，ArY1 代表芳烯基团、二价杂环基团或其中至少一个芳烯基团和至少一个二价杂环基团直接相互键合的二价基团，且这些基团各自可选择具有取代基。］
• Polymer compound and light emitting device using the same
  申请人：Sumitomo Chemical Company, Limited

  公开号：US10818843B2

  公开（公告）日：2020-10-27

  A polymer compound comprising a constitutional unit represented by the following formula (1) and a constitutional unit represented by the following formula (X) and/or a constitutional unit represented by the following formula (Y), wherein the content of the hydroxyl groups contained in the polymer compound is less than 0.02 mol %: Ar1  (1) [wherein, Ar1 represents an arylene group and this group optionally has a substituent.] [wherein, aX1 and aX2 each independently represent an integer of 0 or more. ArX1 and ArX3 each independently represent an arylene group or a divalent heterocyclic group and these groups each optionally have a substituent. ArX2 and ArX4 each independently represent an arylene group, a divalent heterocyclic group or a divalent group in which at least one arylene group and at least one divalent heterocyclic group are bonded directly to each other, and these groups each optionally have a substituent. When there are a plurality of ArX2 and a plurality of ArX4, each of them may be the same or different. RX1, RX2 and RX3 each independently represent an alkyl group, an aryl group or a monovalent heterocyclic group and these groups each optionally have a substituent. When there are a plurality of RX2 and a plurality of RX3, each of them may be the same or different.] ArY1  (Y) [wherein, ArY1 represents an arylene group, a divalent heterocyclic group or a divalent group in which at least one arylene group and at least one divalent heterocyclic group are bonded directly to each other, and these groups each optionally have a substituent.].

  一种聚合物化合物，由下式（1）代表的构型单元和下式（X）代表的构型单元和/或下式（Y）代表的构型单元组成、 其中聚合物化合物中所含羟基的含量小于 0.02 摩尔%： Ar1 (1) [其中，Ar1 代表芳烯基团，该基团可选择具有一个取代基。］ [其中，aX1 和 aX2 各自独立地代表 0 或 0 以上的整数。ArX1 和 ArX3 各自独立地代表芳烯基团或二价杂环基团，并且这些基团各自可选地具有一个取代基。ArX2 和 ArX4 各自独立地代表芳烯类基团、二价杂环基团或其中至少一个芳烯类基团和至少一个二价杂环基团直接相互键合的二价基团，这些基团各自可选地具有取代基。当有多个 ArX2 和多个 ArX4 时，它们可以相同或不同。RX1、RX2 和 RX3 各自独立地代表烷基、芳基或单价杂环基团，且这些基团各自可选地具有取代基。当有多个 RX2 和多个 RX3 时，它们可以相同或不同]。 ArY1 (Y) [其中，ArY1 代表芳烯类基团、二价杂环基团或至少一个芳烯类基团和至少一个二价杂环基团直接相互键合的二价基团，且这些基团各自可选择具有一个取代基。］
• POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20160211452A1

  公开（公告）日：2016-07-21

  A polymer compound comprising a constitutional unit represented by the following formula (1) and a constitutional unit represented by the following formula (X) and/or a constitutional unit represented by the following formula (Y), wherein the content of the hydroxyl groups contained in the polymer compound is less than 0.02 mol %: Ar 1   (1) wherein Ar 1 represents an arylene group and this group optionally has a substituent, wherein, Ar Y1 represents an arylene group, a divalent heterocyclic group or a divalent group in which at least one arylene group and at least one divalent heterocyclic group are bonded directly to each other, and these groups each optionally have a substituent.
• US8546609B2
  申请人：——

  公开号：US8546609B2

  公开（公告）日：2013-10-01