A matrix isolation and DFT study of the generation and characterization of monomeric vapour phase platinum chlorides
作者:Adam J. Bridgeman、Germán Cavigliasso、Neil Harris、Nigel A. Young
DOI:10.1016/s0009-2614(01)01369-0
日期:2002.1
Molecular platinum monochloride (PtCl) and platinum dichloride (PtCl2) have been prepared from platinum atoms and chlorine doped argon in a hollow-cathode sputtering device, matrix isolated in solid argon and characterized using electronic, infrared and X-ray absorption spectroscopies together with high level DFT calculations.
在空心阴极溅射装置中,由铂原子和氯掺杂的氩气制备了分子一氯化铂(PtCl)和二氯化铂(PtCl 2),基质在固体氩气中分离,并利用电子,红外和X射线吸收光谱以及高级DFT计算。