lithium;copper(1+);ethene

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: lithium;copper(1+);ethene
• 化学式: 2C₂H₃*Cu*Li
• 分子量: 124.579
• InChiKey: CIKZXHLLSZREDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.39
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  lithium;copper(1+);ethene 、 生成 、 4-甲氧基联苯
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  copper(l) iodide 、 乙烯基-锂 生成 lithium;copper(1+);ethene
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Anomolous deprotonation of tricarbony(η5-1-arlycyclohexadienyl)iron complexes
  作者：Andrei V. Malkov、G.Richard Stephenson

  DOI：10.1016/0022-328x(94)05269-h

  日期：1995.3

  1-Aryl substituted cyclohexadienyl complexes provide the first example of deprotonation from C-6 of tricarbonyl(cyclohexadienyl)iron(1+) complexes, and in the case of ortho-substituted aryl substituents, a reversed regiocontrol of nucleophile addition.

  1-芳基取代的环己二烯基配合物提供了三羰基（环己二烯基）铁（1+）配合物从C-6脱质子化的第一个例子，在邻位取代的芳基取代基的情况下，亲核试剂加成的反向区域控制。
• Larock, Richard G.; Leach, Douglas R., Organometallics, 1982, vol. 1, # 50, p. 74 - 81
  作者：Larock, Richard G.、Leach, Douglas R.

  DOI：——

  日期：——
• Diastereoselective synthesis of chiral α-aminoorganotributyltins via ring-opening of 2-tributylstannyloxazolidines
  作者：Vincent Coeffard、Jean-Christophe Cintrat、Erwan Le Grognec、Isabelle Beaudet、Jean-Paul Quintard

  DOI：10.1016/j.jorganchem.2005.11.070

  日期：2006.4

  Reactions of 2-tributylstannyloxazolidines 2a-d (cis or trans), derived from (R)-phenylglycinol protected as N-carbamate, with lithium diorganocuprates in presence of boron trifluoride in diethyl ether provide the corresponding functionalized tributylstannyl-alpha-aminoalcohols 3-10 with diastereoselectivities close to 85:15 in favour of the (S,R)-isomer. The stereochemical trend is preserved using allyltributyltin as nucleophile and TiCl2(Oi-Pr)(2) as Lewis acid in dichloromethane. The assignments of the (S,R) or (RR) configurations in 3-10 were achieved on the basis of physicochemical data combined with a radiocrystallographic structure. Stereochemical preferences were rationalized by consideration of the interactions occurring in the iminium intermediates. (c) 2005 Elsevier B.V. All rights reserved.