N-(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)prop-2-enamide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: N-(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)prop-2-enamide
• 化学式: C₁₂H₂₂N₂O₂
• 分子量: 226.32
• InChiKey: KFPKGGLOJPMJPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  52.6
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• Decreasing method of N-oxyl compound
  申请人：Mitsubishi Rayon co., Ltd.

  公开号：US20030078425A1

  公开（公告）日：2003-04-24

  There is provided a superior decreasing method of an N-oxyl compound contained in an easily polymerizable material, according to which the N-oxyl compound contained in an easily polymerizable material can be sufficiently decreased and loss of the easily polymerizable material is little. The easily polymerizable material containing an N-oxyl compound and an acid are contacted with each other. In addition, not only the N-oxyl compound but also an organic titanium group compound contained in the easily polymerizable material can be sufficiently decreased.

  提供了一种优越的减少N-氧化物化合物的方法，该方法适用于易聚合材料中含有的N-氧化物化合物，根据该方法，易聚合材料中含有的N-氧化物化合物可以充分减少，易聚合材料的损失很小。将含有N-氧化物化合物和酸的易聚合材料相互接触。此外，不仅可以充分减少易聚合材料中的N-氧化物化合物，还可以充分减少易聚合材料中的有机钛化合物。
• FILM-FORMING COMPOSITION AND SHEET
  申请人：Toppan Printing Co., Ltd.

  公开号：EP2554589A1

  公开（公告）日：2013-02-06

  To provide a composition for forming a film and its resultant film which has a high level of adhesiveness to a substrate and has good gas barrier properties. < Solution > To prepare the composition for forming a film by adding a silane coupling agent to an aqueous dispersion liquid in which a cellulose nanofiber is dispersed in an aqueous medium. Alternatively, to prepare the composition for forming a film by blending an aqueous dispersion liquid (a) which contains a cellulose nanofiber and has a pH 4-9 with a hydrolysis liquid (b) which contains alkoxysilane hydrolysates and has a pH 2-4 by a weight ratio of "cellulose nanofiber" / "alkoxysilane (in terms of SiO2)" in the range from 0.1 to 5.

  提供一种用于形成薄膜的组合物及其所形成的薄膜，该薄膜与基材的粘合度高，且具有良好的气体阻隔性能。 通过向水性分散液中添加硅烷偶联剂制备成膜用组合物，在水性介质中分散纤维素纳米纤维。或者，将含有纳米纤维素且 pH 值为 4-9 的水性分散液 (a) 与含有烷氧基硅烷水解物且 pH 值为 2-4 的水解液 (b) 按 0.1 至 5 的 "纳米纤维素"/"烷氧基硅烷（以 SiO2 计）"重量比混合，制备成膜用组合物。
• Methods of forming dental composites and compositions for reduced shrinkage stress
  申请人：DENTSPLY SIRONA INC.

  公开号：US10780026B2

  公开（公告）日：2020-09-22

  A method of forming a dental composite includes photopolymerizing a dental composition. The dental composition includes a free-radically polymerizable (meth)acrylate resin, 75 percent by weight or greater of filler particles, and about 0.005 percent to about 5 percent by weight of at least one polymerizable stable radical. The photopolymerizing forms the dental composite such that the dental composite has a flexural modulus of about 9500 MPa or greater and the polymerizable stable radical reduces shrinkage stress of the dental composite caused by the photopolymerizing by 10% or greater. A method of forming a dental composite composition includes combining a free-radically polymerizable (meth)acrylate resin, 75 percent by weight or greater of filler particles, and about 0.005 percent to about 5 percent by weight of at least one polymerizable stable radical to form the dental composite composition.

  形成牙科复合材料的方法包括对牙科组合物进行光聚合。牙科组合物包括可自由基聚合的（甲基）丙烯酸酯树脂、75%（按重量计）或更多的填料颗粒，以及约 0.005%至约 5%（按重量计）的至少一种可聚合的稳定基。光聚合形成牙科复合材料，使牙科复合材料具有约 9500 兆帕或更大的弯曲模量，可聚合稳定基使光聚合引起的牙科复合材料收缩应力降低 10%或更大。形成牙科复合材料组合物的方法包括将可自由基聚合的（甲基）丙烯酸酯树脂、75%（重量）或更多的填料颗粒和约 0.005%至约 5%（重量）的至少一种可聚合稳定基组合在一起，形成牙科复合材料组合物。
• Crosslinkable polymeric compositions with methyl-radical scavengers and articles made therefrom
  申请人：Dow Global Technologies LLC

  公开号：US10851221B2

  公开（公告）日：2020-12-01

  Crosslinkable polymeric compositions for use in, for instance, cable insulation layers, comprise an ethylene-based polymer, an organic peroxide, a crosslinking coagent, and a methyl-radical scavenger comprising at least one derivative of 2, 2, 6, 6-tetramethyl-1-piperidinyloxyl (“TEMPO”), wherein ratio of crosslinking coagent to organic peroxide is less than 1.72:1 on a molar basis. A crosslinked article prepared from a crosslinkable polymeric composition is also disclosed, the crosslinkable polymeric composition comprising, inter alia, a methyl-radical scavenger comprising at least one TEMPO derivative. In addition, a coated conducttor comprising a conductive core and a polymeric layer at least partially surrounding the conductive core is disclosed, wherein at least a portion of the polymeric layer comprises the crosslinked article.

  用于电缆绝缘层等的可交联聚合物组合物包括乙烯基聚合物、有机过氧化物、交联剂和甲基自由基清除剂，甲基自由基清除剂包括至少一种 2，2，6，6-四甲基-1-哌啶基氧基（"TEMPO"）的衍生物，其中交联剂与有机过氧化物的摩尔比小于 1.72:1。还公开了一种由可交联聚合物组合物制备的交联制品，该可交联聚合物组合物除其他外包括至少一种 TEMPO 衍生物的甲基自由基清除剂。此外，还公开了一种涂层导体，包括导电芯和至少部分环绕导电芯的聚合物层，其中聚合物层的至少一部分包括交联制品。
• Peroxide-curable polyolefin composition
  申请人：Dow Global Technologies LLC

  公开号：US11174408B2

  公开（公告）日：2021-11-16

  A peroxide-curable polyolefin composition comprising a peroxide-curable polyolefin prepolymer, an organic peroxide, and 4-[[4,6-bis(octylthio)-1,3,5-triazin-2-yl]amino]-2,6-bis(1,1-dimethylethyl)-phenol. Also, a peroxide-cured polyolefin product prepared therefrom, methods of making and using same, and articles containing or made from same.

  一种过氧化物固化聚烯烃组合物，包含一种过氧化物固化聚烯烃预聚物、一种有机过氧化物和 4-[[4,6-双（辛基硫代）-1,3,5-三嗪-2-基]氨基]-2,6-双（1,1-二甲基乙基）-苯酚。此外，还包括由其制备的过氧化物固化聚烯烃产品、制造和使用方法，以及含有或由其制成的物品。