2,2'-Dibenzylazobenzene | 53093-54-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 2,2'-Dibenzylazobenzene
• 英文别名: 2,2'-Dibenzyl-azobenzol；bis-(2-benzyl-phenyl)-diazene；Bis-(2-benzyl-phenyl)-diazen；o-Azodiphenylmethan；Diphenylmethan-(2 azo 2)-diphenylmethan；Bis-(2-benzyl-phenyl)-diimid；Bis(2-benzylphenyl)diazene
• CAS: 53093-54-2
• 化学式: C₂₆H₂₂N₂
• 分子量: 362.474
• InChiKey: CJMFJMOCFFFHRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2'-Dibenzylazobenzene 在 铬酸 、 溶剂黄146 作用下， 生成 2,2''-azo-di-benzophenone
  参考文献：
  名称：

  THE HAND OF HISTORY AND THE EQUITY-LEGITIMACY NEXUS

  摘要：

  DOI：

  10.1111/j.1475-4991.2000.tb00958.x
• 作为产物：
  描述：

  邻苄基苯胺 在 硫酸 、 sodium nitrite 作用下， 生成 2,2'-Dibenzylazobenzene
  参考文献：
  名称：

  Zahler,W.D.; Huisgen,R., Chemische Berichte, 1963, vol. 96, p. 765 - 770

  摘要：

  DOI：

文献信息

• Transfer Hydrogenation of Azoarenes to Hydrazoarenes by Ammonia Borane Complex Catalyzed by Au Nanoparticles
  作者：Elisavet‐Maria Zantioti‐Chatzouda、Dimitra Malliotaki、Manolis Stratakis

  DOI：10.1002/adsc.202300387

  日期：2023.9.5

  Minute amounts of supported Au nanoparticles on TiO2 (0.1 mol%) catalyze quantitatively at room temperature the transfer hydrogenation of azoarenes to hydrazoarenes by ammonia borane complex, in ethanol as solvent. At 1 mol% catalyst loading level and 2.5 molar equivalents of ammonia borane the process occurs instantaneously. The catalyst is recyclable and reusable. In the absence of reducing agent,

  TiO 2上的微量负载Au纳米颗粒（0.1 mol%）在室温下定量催化在乙醇作为溶剂中通过氨硼烷络合物将偶氮芳烃转移氢化为腙芳烃。在 1 mol% 催化剂负载水平和 2.5 摩尔当量氨硼烷下，该过程立即发生。该催化剂可回收、可重复使用。在没有还原剂的情况下，亚氮芳烃经历顺利的Au/TiO 2催化的有氧氧化回到偶氮芳烃。
• Reactivities of Nitrenes Generated by Photolysis of 2-(.omega.-Phenylalkyl)phenyl Azides
  作者：Shigeru Murata、Ryuichi Yoshidome、Youji Satoh、Noriyasu Kato、Hideo Tomioka

  DOI：10.1021/jo00110a052

  日期：1995.3

  In order to investigate the reactivity of a photolytically generated arylnitrene with an intramolecular CH bond, the photochemistry of 2-(omega-phenylalkyl)phenyl azides (1a-d) was examined. Irradiation of 1 in solution revealed that the insertion of the nitrene into an adjacent CH bond to give cyclic compounds 4 and 5 occurs favorably only when a reactive CH bond, such as benzylic, is located close to the nitrenic center. This process can compete with the formation of products derived from triplet nitrene, but not with the capture of didehydroazepine by DEA. On the other hand, irradiation of 1b in an Ar matrix at 12 K gave a mixture of the CH insertion product 4b and the didehydroazepine 15. The origin of the difference in reactivity of the nitrene observed in solutions and in a matrix, and the spin state of the nitrene involved in the CH insertion reaction, are discussed.
• 426. Internuclear cyclisation. Part V. The cyclisation of derivatives of diphenylmethane, benzophenone, and N-methyldiphenylamine
  作者：D. H. Hey、R. D. Mulley

  DOI：10.1039/jr9520002276

  日期：——
• Carre, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909, vol. 148, p. 493
  作者：Carre

  DOI：——

  日期：——
• Carre, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909, vol. 148, p. 102,672
  作者：Carre

  DOI：——

  日期：——