A task to be achieved by the present invention is to provide a method for producing a coagulate having a porous structure with ease using an aqueous urethane resin composition without subjecting the composition to a step of heating, foaming, or the like. The present invention provides a method for producing a coagulate, comprising: incorporating, into an aqueous urethane resin composition containing an aqueous urethane resin (A) having an acid value of 0.01 mg KOH/g or more, a thickening agent (B) having an oxyethylene group content of 2 × 10-2 mol/g or less in an amount in the range of from 0.01 to 30 parts by mass, relative to 100 parts by mass of the aqueous urethane resin (A), to thicken the composition; and then coagulating the thickened composition using a coagulant (C) containing a metal salt (c-1). By the method of the invention, a porous structure can be formed from an aqueous urethane resin composition without subjecting the composition to heating or foaming step, and therefore a coagulate having a porous structure can be stably obtained with ease.
本发明要完成的一项任务是提供一种方法,利用
水性聚
氨酯
树脂组合物轻松生产具有多孔结构的凝结物,而无需对组合物进行加热、发泡等步骤。本发明提供了一种生产凝结物的方法,包括:在含有酸值为 0.01 毫克 KOH/g 或更高的
水性聚
氨酯
树脂 (A) 的
水性聚
氨酯
树脂组合物中加入
增稠剂 (B),
增稠剂 (B) 的氧
乙烯基含量为 2 × 10-2 摩尔/克或更少,其用量范围为 0.相对于 100 重量份的
水性聚
氨酯
树脂 (A) 而言,
增稠剂 (B) 的用量范围为 0.01 至 30 重量份,以增稠该组合物;然后使用含有
金属盐 (c-1) 的凝固剂 (C) 使增稠后的组合物凝固。通过本发明的方法,可以在不对
水性聚
氨酯
树脂组合物进行加热或发泡的情况下使其形成多孔结构,因此可以轻松稳定地获得具有多孔结构的凝结物。