[Silanediylbis(methylene)]bis(trimethylsilane) | 118467-00-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: [Silanediylbis(methylene)]bis(trimethylsilane)
• 英文别名: trimethyl(trimethylsilylmethylsilylmethyl)silane
• CAS: 118467-00-8
• 化学式: C₈H₂₄Si₃
• 分子量: 204.535
• InChiKey: XANIWMVNBWRPAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.75
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (三甲基硅基)甲基氯化镁 在 lithium aluminium tetrahydride 、 三氯硅烷 作用下， 生成 Tris-(trimethylsilyl-methyl)-silan 、 (trimethylsilylmethyl)silane 、 [Silanediylbis(methylene)]bis(trimethylsilane)
  参考文献：
  名称：

  Synthesis and characterization of mono-, bis-, tris- and tetrakis(trimethylsilylmethyl)silanes: (Me3SiCH2)xSiH4−x (x = 1−4)

  摘要：

  The mono-, bis-, tris-, and tetrakis(trimethylsilylmethyl)silanes, (Me3SiCH2)(x)SiH4-x (x = 1-4), have been prepared for use as "models" of the various Si-centered functional units in a complex, highly branched polycarbosilane polymer of the approximate composition, "(SiH2CH2)n". These compounds have been characterized by GC, IR, H-1, C-13, Si-29 NMR, MS, and elemental analysis. The IR and NMR data for this series of compounds show distinct trends on increasing substitution, which are related to the structural differences within the series.

  DOI：

  10.1016/0022-328x(91)86347-s

文献信息

• Synthesis and characterization of mono-, bis-, tris- and tetrakis(trimethylsilylmethyl)silanes: (Me3SiCH2)xSiH4−x (x = 1−4)
  作者：Chris.K. Whitmarsh、Leonard V. Interrante

  DOI：10.1016/0022-328x(91)86347-s

  日期：1991.10

  The mono-, bis-, tris-, and tetrakis(trimethylsilylmethyl)silanes, (Me3SiCH2)(x)SiH4-x (x = 1-4), have been prepared for use as "models" of the various Si-centered functional units in a complex, highly branched polycarbosilane polymer of the approximate composition, "(SiH2CH2)n". These compounds have been characterized by GC, IR, H-1, C-13, Si-29 NMR, MS, and elemental analysis. The IR and NMR data for this series of compounds show distinct trends on increasing substitution, which are related to the structural differences within the series.