tricrotyl phosphite | 51666-84-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 英文名称: tricrotyl phosphite
• 英文别名: phosphoric acid tri-but-2t-enyl ester；Phosphorigsaeure-tri-but-2t-enylester；tris[(E)-but-2-enyl] phosphite
• CAS: 51666-84-3
• 化学式: C₁₂H₂₁O₃P
• 分子量: 244.271
• InChiKey: XAFPIDGLBPEFCC-OTWDQPKHSA-N

物化性质

• 沸点：
  98-99 °C(Press: 1 Torr)
• 密度：
  0.9757 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tricrotyl phosphite 在 dirhodium tetraacetate 、 对甲苯磺酰叠氮 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 (1R,2S,5R,6S)-2-[((E)-But-2-enyl)oxy]-6-methyl-2-oxo-3-oxa-2λ⁵-phospha-bicyclo[3.1.0]hexane-1-carboxylic acid (R)-4,4-dimethyl-2-oxo-tetrahydro-furan-3-yl ester
  参考文献：
  名称：

  Substituent effects in the double diastereotopic differentiation of α-diazophosphonates via intramolecular cyclopropanation

  摘要：

  The investigation of substituent effects in the double diastereotopic differentiation of substituted alpha-diazophosphonates using intramolecular cyclopropanation catalyzed by Rh-2(OAc)(4) is reported. Carbene facial selectivity in these transformations is dictated by substrate control in either of two ways: (i) exploitation of (R)-pantolactone as an auxiliary incorporated into the carboester functionality while probing olefinic substituent effects, or (ii) utilization of chiral, non-racemic allylic alcohols incorporated into the phosphonate moiety. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(03)00081-8
• 作为产物：
  描述：

  巴豆醇 在 三乙胺 、 三氯化磷 作用下， 以 乙醚 为溶剂， 生成 tricrotyl phosphite
  参考文献：
  名称：

  Substituent effects in the double diastereotopic differentiation of α-diazophosphonates via intramolecular cyclopropanation

  摘要：

  The investigation of substituent effects in the double diastereotopic differentiation of substituted alpha-diazophosphonates using intramolecular cyclopropanation catalyzed by Rh-2(OAc)(4) is reported. Carbene facial selectivity in these transformations is dictated by substrate control in either of two ways: (i) exploitation of (R)-pantolactone as an auxiliary incorporated into the carboester functionality while probing olefinic substituent effects, or (ii) utilization of chiral, non-racemic allylic alcohols incorporated into the phosphonate moiety. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(03)00081-8

文献信息

• Method for producing allyl compound
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20040092777A1

  公开（公告）日：2004-05-13

  A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent having a structure different from that of the allyl starting material compound in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a monodentate phosphite compound having a structure of the following formula (1): P(OR 1 )(OR 2 )(OR 3 )   (1) wherein R 1 , R 2 and R 3 are respectively independently an alkyl group which may have a substituent, carbon chains of R 1 , R 2 and R 3 may have at least one carbon-carbon double bond or triple bond, and at least two optional groups of R 1 , R 2 and R 3 may bond to each other to form at least one cyclic structure.

  一种制备具有与烯丙基起始材料化合物不同组成式的烯丙基化合物的方法，包括在至少包含选择自周期表8至10族过渡金属的过渡金属化合物和具有以下式（1）结构的单齿磷酸酯化合物催化剂存在下，将烯丙基起始材料化合物与具有不同于烯丙基起始材料化合物的结构的氧亲核试剂反应，其中式（1）中，R1、R2和R3分别独立地是可以具有取代基的烷基，R1、R2和R3的碳链可以具有至少一个碳-碳双键或三键，并且R1、R2和R3的至少两个可选基团可以结合形成至少一个环状结构。
• Nonaqueous electrolyte solution, electricity storage device using same, and phosphonoformic acid compound used in same
  申请人：UBE INDUSTRIES, LTD.

  公开号：US10374256B2

  公开（公告）日：2019-08-06

  The present invention provides a nonaqueous electrolytic solution capable of suppressing worsening of heat stability of a negative electrode and improving safety of an energy storage device while maintaining high-load charging and discharging cycle properties at a high temperature, an energy storage device using the same, and a phosphonoformic acid compound to be used for the same. The nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent contains 0.001 to 5% by mass of at least one selected from a phosphonoformic acid compound having at least one carbon-carbon unsaturated bond, which is represented by the following general formula (I), and a phosphonoformic acid compound having a carbon-carbon unsaturated bond or two phosphonocarbonyl groups, which is represented by the following general formula (II). In the formula (I), each of R1 to R3 is an aliphatic organic group, provided that at least one of R1 to R3 represents a carbon-carbon unsaturated bond-containing aliphatic organic group. In the formula (II), each of R4 and R5 represents an alkyl group, a cycloalkyl group, or an aryl group, and R4 and R5 may be bonded to each other to form a ring structure. m represents 1 or 2; when m is 1, then R6 represents an aryl group; when m is 2, then R6 represents an alkylene group, an alkenylene group, or an alkynylene group; and a part of hydrogen atoms of R4 to R6 may be substituted with a halogen atom.

  本发明提供了一种在高温下保持高负荷充放电循环特性的同时，能够抑制负极热稳定性恶化并提高储能装置安全性的非水性电解溶液、使用该溶液的储能装置以及用于该溶液的膦甲酸化合物。具有溶解在非水溶剂中的电解质盐的非水电解溶液含有 0.001%至 5%（以质量计）的至少一种选自具有至少一个碳碳不饱和键的膦甲酸化合物（由以下通式 (I) 表示）和具有一个碳碳不饱和键或两个膦酰基的膦甲酸化合物（由以下通式 (II) 表示）。 在式 (I) 中，R1 至 R3 中的每一个都是脂肪族有机基团，条件是 R1 至 R3 中至少有一个代表含碳碳不饱和键的脂肪族有机基团。 在式 (II) 中，R4 和 R5 各自代表烷基、环烷基或芳基，且 R4 和 R5 可相互键合以形成环状结构。m 代表 1 或 2；当 m 为 1 时，则 R6 代表芳基；当 m 为 2 时，则 R6 代表亚烷基、亚烯基或亚炔基；且 R4 至 R6 的部分氢原子可被卤原子取代。
• Pudowik, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 2755,2758; engl. Ausg. S. 2794, 2796
  作者：Pudowik

  DOI：——

  日期：——
• MORITA, IWAO;TADA, SHIN-ICHI;KUNIMOTO, KATSUTOSHI;TSUDA, MASAMI;KISE, MAS+, CHEM. AND PHARM. BULL., 35,(1987) N 9, 3898-3904
  作者：MORITA, IWAO、TADA, SHIN-ICHI、KUNIMOTO, KATSUTOSHI、TSUDA, MASAMI、KISE, MAS+

  DOI：——

  日期：——
• NONAQUEOUS ELECTROLYTE SOLUTION, ELECTRICITY STORAGE DEVICE USING SAME, AND PHOSPHONOFORMIC ACID COMPOUND USED IN SAME
  申请人：Ube Industries, Ltd.

  公开号：EP3086397B1

  公开（公告）日：2018-10-10