三(二氯丙基)亚磷酸酯 | 26604-52-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 中文名称: 三(二氯丙基)亚磷酸酯
• 英文名称: phosphorous acid tris-(2,3-dichloro-propyl) ester
• 英文别名: Tris(2,3-dichloropropyl) phosphite
• CAS: 26604-52-4
• 化学式: C₉H₁₅Cl₆O₃P
• 分子量: 414.908
• InChiKey: FCFIEBVTVHJMQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  O,O-Bis(2,3-dichloropropyl)phosphorous acid chloride 、 三(二氯丙基)亚磷酸酯 、 丙醛 生成 phosphorous acid 1-[bis-(2,3-dichloro-propoxy)-phosphoryl]-propyl ester bis-(2,3-dichloro-propyl) ester
  参考文献：
  名称：

  Process of preparing organic phosphorus compounds

  摘要：

  公开号：

  US03014944A1
• 作为产物：
  描述：

  2,3-二氯-1-丙醇 生成 三(二氯丙基)亚磷酸酯
  参考文献：
  名称：

  MAMEDOV, S. A.;ALIEV, F. YU., MATER. 3 RESP. KONF. MOL. UCHENYX-XIKIKOV, POSVYASHCH. 80-LETIYU AKAD. M.+

  摘要：

  DOI：

文献信息

• MANUFACTURING METHOD FOR POLYCARBONATE
  申请人：——

  公开号：US20020037838A1

  公开（公告）日：2002-03-28

  A method for manufacturing polycarbonate by melt-polycondensing bisphenol and carbonic acid diester uses as catalyst an alkali metal compound and/or alkaline earth metal compound (a). The catalyst is added to the bisphenol prior to the melt polycondensation, in an effective amount, i.e., the amount of alkali metal compound and/or alkaline earth metal compound (a) that acts effectively as a catalyst, is contained in said bisphenol, and is controlled to have the same catalytic activity as 1×10 −8 to 1×10 −6 mole of bisphenol disodium salt per mole of pure bisphenol A. The method conducts the reaction efficiently from the initial stage in a stable manner to obtain polycarbonate with good color, good heat stability and color stability during molding and the like.

  一种通过熔融缩聚双酚和碳酸二酯制造聚碳酸酯的方法，使用碱金属化合物和/或碱土金属化合物（a）作为催化剂。催化剂在熔融缩聚之前被添加到双酚中，添加的量是有效的，即碱金属化合物和/或碱土金属化合物（a）的量作为催化剂是包含在双酚中的，并且被控制为具有与1×10^-8至1×10^-6摩尔双酚二钠盐相同的催化活性。该方法从初始阶段开始有效地进行反应，稳定地获得具有良好颜色、良好热稳定性和成型过程中颜色稳定性的聚碳酸酯。
• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Urea condensate-sewer sludge products
  申请人：——

  公开号：US20030022959A1

  公开（公告）日：2003-01-30

  Aqueous or solid nitrogen containing compound compounds are produced by heating urea with wet solid sewer sludge thereby producing a urea-urea condensate-sewer sludge composition in a process to dry out the sewer sludge. The urea reacts with itself and with the compounds in the sewer sludge. The urea and/or urea condensate reacts with the sulfur containing compounds thereby reducing the odor from heating the sewer sludge. The urea-urea condensate-sewer sludge composition is useful as a bio-fertilizer, may be utilized to fight grass, forest, building fires, flame retard other flammable organic material by applying it on or incorporating it in these flammable organic materials and may be reacted with aldehydes to produce resins. Carbonization auxiliaries, such as phosphorus containing compounds, metal containing compounds that will accelerate carbonization, heat reflector, surfactant and fillers may be added to or reacted with the aqueous or solid urea-urea condensate-sewer sludge composition.

  通过将尿素与湿固体污水污泥加热，产生尿素-尿素缩合物-污水污泥组合物，从而生产含氮水溶液或固体化合物，用于干燥污水污泥的过程。尿素与自身以及污水污泥中的化合物发生反应。尿素和/或尿素缩合物与含硫化合物反应，从而减少加热污水污泥产生的气味。尿素-尿素缩合物-污水污泥组合物可用作生物肥料，可用于对抗草地、森林、建筑物火灾，阻燃其他易燃有机材料，将其涂抹或加入这些易燃有机材料中，并可与醛类反应产生树脂。碳化助剂，如含磷化合物、含金属化合物、加速碳化的热反射材料、表面活性剂和填充剂可以添加到或与含氮水溶液或固体尿素-尿素缩合物-污水污泥组合物反应。
• Optical parts and sulfur-containing poly (thio)ester (co)polymer
  申请人：——

  公开号：US20030204030A1

  公开（公告）日：2003-10-30

  A poly(thio)ester (co)polymer which comprises a repeating structural unit represented by the formula (1-A) as an essential structural unit: 1 [wherein R 11 is a divalent aliphatic hydrocarbon group which may contain at least one sulfur atom in a sulfide group; R 12 is a mono- or poly-cyclic aliphatic or aromatic dicarboxylic acid residue; and X 11 and X 12 are each independently an oxygen atom or sulfur atom, and when X 11 and X 12 are the oxygen atoms, R 11 is a divalent aliphatic hydrocarbon group containing at least one sulfur atom in the sulfide group]; and an optical component obtainable by molding the poly(thio)ester (co)polymer. The poly(thio)ester (co)polymer is excellent in transparency and optical characteristics (e.g., a higher refractive index, higher Abbe number, and lower birefringence), and has also good mechanical characteristics and thermal characteristics, and further is excellent in melt fluidity and injection moldability.

  一种聚（硫）酯（共）聚合物，其包括由公式（1-A）表示的重复结构单元作为必要的结构单元：1 [其中，R11是一个双价的脂肪族碳氢基团，可以在硫化物基团中含有至少一个硫原子；R12是一个单环或多环的脂肪族或芳香族二羧酸残基；X11和X12分别是氧原子或硫原子，当X11和X12是氧原子时，R11是一个含有至少一个硫原子的双价脂肪族碳氢基团]；以及通过模塑聚（硫）酯（共）聚合物获得的光学组件。该聚（硫）酯（共）聚合物在透明度和光学特性（例如更高的折射率、更高的阿贝数和更低的双折射率）方面表现出色，同时具有良好的机械特性和热特性，并且在熔融流动性和注塑性方面表现出色。
• CURRENT BREAKER CASE AND CURRENT BREAKER USING THE SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20150001054A1

  公开（公告）日：2015-01-01

  A current breaker case including a polycarbonate resin composition that includes a polycarbonate-polyorganosiloxane copolymer and has a viscosity-average molecular weight of 18000 to 25000.

  一个电流断路器外壳，包括一种聚碳酸酯树脂组成物，其中包括聚碳酸酯-聚有机硅共聚物，并具有粘度平均分子量在18000至25000之间。