3-(2-Methoxyethoxy)-1-[3-(2-methoxyethoxy)butylsulfonyl]butane

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: 3-(2-Methoxyethoxy)-1-[3-(2-methoxyethoxy)butylsulfonyl]butane
• 英文别名: 3-(2-methoxyethoxy)-1-[3-(2-methoxyethoxy)butylsulfonyl]butane
• 化学式: C₁₄H₃₀O₆S
• 分子量: 326.45
• InChiKey: HCRDZNNTBMNHBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  21
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  79.4
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• Crosslinked functional binders and their use in silicon-containing anodes of lithium-ion batteries
  申请人：UT-Battelle, LLC

  公开号：US10897045B2

  公开（公告）日：2021-01-19

  A crosslinked polymer composition comprising: (i) a base polymer containing a multiplicity of at least one type of functional group selected from amino, amido, thiol, carboxylic acid, carboxylic acid ester, and epoxy groups; (ii) a multiplicity of hydroxylated benzene rings covalently linked to the base polymer, wherein each hydroxylated benzene ring contains at least two hydroxy groups, and with at least two of the hydroxy groups on said hydroxylated benzene rings being free as OH groups; and (iii) a multiplicity of crosslinking groups that crosslink at least two of said functional groups in the base polymer. The invention is also directed to lithium-ion batteries in which the above-described composition is incorporated in an electrode of the battery, and also directed to methods of operating a lithium-ion battery in which the above-described crosslinked polymer composition is incorporated in an electrode thereof.

  一种交联聚合物组合物，包括(i) 含有至少一种选自氨基、氨基、硫醇、羧酸、羧酸酯和环氧基团的官能团的多元性基体聚合物；(ii) 与基质聚合物共价连接的羟基化苯环，其中每个羟基化苯环含有至少两个羟基，且所述羟基化苯环上的羟基中至少有两个游离为羟基；以及 (iii) 与基质聚合物中至少两个所述官能团交联的交联基团。本发明还涉及锂离子电池，在该电池的电极中加入了上述组合物，本发明还涉及锂离子电池的操作方法，在该电池的电极中加入了上述交联聚合物组合物。
• Block graft copolymer binders and their use in silicon-containing anodes of lithium-ion batteries
  申请人：UT-Battelle, LLC

  公开号：US11005101B2

  公开（公告）日：2021-05-11

  A graft copolymer composition comprising the following structure: wherein: Ax represents a polymer backbone having a number of polymerized monomer units x; [By] represents a multiplicity of a graft polymer side chain having a number of polymerized monomer units y, and at least a portion of the monomer units in By contains a group —C(O)OM, with M independently selected from H and alkali metals; [C] represents a multiplicity of positions on the polymer backbone Ax where the graft polymer side chain B or any other graft polymer side chain is not attached; the subscript w represents a grafting density of the group By, wherein w is an integer within a range of 10-50%; and the subscript z represents a density of the group C, wherein z=(100−w) %. The invention is also directed to lithium-ion batteries in which the above-described composition is incorporated in an anode of the battery.

  一种接枝共聚物组合物，由以下结构组成： 其中Ax 代表具有一定数量聚合单体单元 x 的聚合物主链；[By] 代表具有一定数量聚合单体单元 y 的接枝聚合物侧链的倍数，By 中至少一部分单体单元含有基团 -C(O)OM，M 独立选自 H 和碱金属；[C]代表聚合物骨架 Ax 上未连接接枝聚合物侧链 B 或任何其他接枝聚合物侧链的位置的倍数；下标 w 代表基团 By 的接枝密度，其中 w 是 10-50% 范围内的整数；下标 z 代表基团 C 的密度，其中 z=(100-w) %。本发明还涉及锂离子电池，在电池的阳极中加入了上述组合物。
• BLOCK GRAFT COPOLYMER BINDERS AND THEIR USE IN SILICON-CONTAINING ANODES OF LITHIUM-ION BATTERIES
  申请人：UT-Battelle, LLC

  公开号：US20190229337A1

  公开（公告）日：2019-07-25

  A graft copolymer composition comprising the following structure: wherein: A x represents a polymer backbone having a number of polymerized monomer units x; [B y ] represents a multiplicity of a graft polymer side chain having a number of polymerized monomer units y, and at least a portion of the monomer units in B y contains a group —C(O)OM, with M independently selected from H and alkali metals; [C] represents a multiplicity of positions on the polymer backbone A x where the graft polymer side chain B or any other graft polymer side chain is not attached; the subscript w represents a grafting density of the group B y , wherein w is an integer within a range of 10-50%; and the subscript z represents a density of the group C, wherein z=(100−w) %. The invention is also directed to lithium-ion batteries in which the above-described composition is incorporated in an anode of the battery.
• CROSSLINKED FUNCTIONAL BINDERS AND THEIR USE IN SILICON-CONTAINING ANODES OF LITHIUM-ION BATTERIES
  申请人：UT-Battelle, LLC

  公开号：US20190319269A1

  公开（公告）日：2019-10-17

  A crosslinked polymer composition comprising: (i) a base polymer containing a multiplicity of at least one type of functional group selected from amino, amido, thiol, carboxylic acid, carboxylic acid ester, and epoxy groups; (ii) a multiplicity of hydroxylated benzene rings covalently linked to the base polymer, wherein each hydroxylated benzene ring contains at least two hydroxy groups, and with at least two of the hydroxy groups on said hydroxylated benzene rings being free as OH groups; and (iii) a multiplicity of crosslinking groups that crosslink at least two of said functional groups in the base polymer. The invention is also directed to lithium-ion batteries in which the above-described composition is incorporated in an electrode of the battery, and also directed to methods of operating a lithium-ion battery in which the above-described crosslinked polymer composition is incorporated in an electrode thereof.
• ELECTRON CONDUCTIVE POLYMER COMPOSITES AND THEIR USE AS ELECTRODE MATERIALS
  申请人：UT-Battelle, LLC

  公开号：US20200176762A1

  公开（公告）日：2020-06-04

  A composite material comprising particles containing (i) a core comprising an organic polymer material that is ion-permeable, not electron conductive, and possesses reversible electrochemical activity (e.g., aromatic polyimide, polyquinone, and radical-containing polymers), and (ii) an electron conductive polymer (e.g., polythiophene, poly(3,4-ethylenedioxythiophene), polypyrrole, polyaniline, polyacetylene, or poly(p-phenylene vinylene), alkyl-substituted derivatives thereof, hydrophilized derivatives thereof, or copolymer thereof) coated onto and encapsulating the core. Also described herein are batteries (e.g., lithium-ion) in which at least the cathode contains the composite material described above. Also described herein are capacitors in which at least one electrode contains the composite material described above.