Catalyst compositions useful in the production of insulating polyurethane or polyisocyanurate foam are disclosed. The catalyst compositions impart increased stability of a mixture of the catalyst, a halogen-containing blowing agent, and a polyol. These catalyst compositions comprise of at least 10% of a tetraalkylguanidine and at least 10% of a tertiary amine catalyst with an isocyanate reactive group. These improved catalysts can be used with any halogenated blowing agent, and provide substantial stability benefits with the use of hydrofluoroolefins and hydrofluorochloroolefins. In an exemplary embodiment, a process includes providing a pre-mix comprising a hydrohaloolefin blowing agent, at least one polyol, water, and a catalyst comprising 10-50% tetramethylguanidine and 10-90% of one or more of an amine catalyst containing an isocyanate reactive group.
本发明公开了用于生产绝缘聚
氨酯或聚异
氰脲酸酯泡沫塑料的催化剂组合物。这些催化剂组合物提高了催化剂、含卤发泡剂和多元醇混合物的稳定性。这些催化剂组合物包括至少 10%的四烷基
胍和至少 10%的带有
异氰酸酯活性基团的叔胺催化剂。这些改良催化剂可与任何卤代发泡剂一起使用,并在使用氢
氟烯烃和氢
氟氯烯烃时具有显著的稳定性优势。在一个示例性实施方案中,一种工艺包括提供一种预混物,该预混物包含一种氢卤烯烃发泡剂、至少一种多元醇、
水和一种催化剂,该催化剂包含 10-50%的
四甲基胍和 10-90%的一种或多种含有
异氰酸酯反应基团的胺催化剂。