trioctyl isocyanurate | 1908-35-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: trioctyl isocyanurate
• 英文别名: 1,3,5-Trioctyl-1,3,5-triazin-2,4,6-trion; 1,2,3-Trioctyl-isocyanursaeure；Tri-n-octylisocyanurat；N,N',N''-tri(1-octyl)triazine-2,4,6-trione；1,3,5-trioctyl-[1,3,5]triazinane-2,4,6-trione；1,3,5-Trioctyl-1,3,5-triazinane-2,4,6-trione
• CAS: 1908-35-6
• 化学式: C₂₇H₅₁N₃O₃
• 分子量: 465.72
• InChiKey: GGOKMHATXAWPJX-UHFFFAOYSA-N

物化性质

• 沸点：
  257 °C(Press: 4 Torr)
• 密度：
  0.972±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  33
• 可旋转键数：
  21
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  正辛基异氰酸酯 在 sodium trimethylsilanolate 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 以83%的产率得到trioctyl isocyanurate
  参考文献：
  名称：

  研究为六甲基二硅氮烷催化的烷基异氰酸酯的三聚提供了合理的机制

  摘要：

  使用HMDS作为异氰酸酯三聚化的催化剂具有许多优点，因为预期的异氰脲酸酯不会被催化剂或由其降解引起的其他副产物污染。另外，HMDS具有低毒性，并且与工业应用兼容。本文介绍了六甲基二硅氮烷（HMDS）催化的辛基异氰酸酯的三聚。实验研究和机理考虑表明，三聚反应的真正催化剂是三甲基甲硅烷基辛胺，它是由HMDS与异氰酸辛酯的初步缩合产生的。

  DOI：

  10.1016/j.tet.2010.12.013

文献信息

• Process for producing a film-like and fibrous article of a wholly aromatic polyester
  申请人：TEIJIN LIMITED

  公开号：EP0070539A1

  公开（公告）日：1983-01-26

  A wholly aromatic polyester composition comprising (a) 100 parts by weight of a wholly aromatic polyester containing as a main component at least one compound selected from the group consisting of aromatic dicarboxylic acids, aromatic dihydroxy compounds and aromatic hydroxycarboxylic acids, and (b) from 5 to 300 parts by weight of a low-molecular-weight compound being substantially non-reactive with the wholly aromatic polyester and having a boiling point of at least about 200°C under atmospheric pressure and a molecular weight of not more than 1.000. The wholly aromatic polyester composition is produced advantageously by polycondensing in the molten state the polyester-forming starting mixture in the presence of the low-molecular-weight compound. A film-like or fibrous article of a wholly aromatic polyester may be produced by extracting the low-molecular-weight compound from a film-like or fibrous article of the wholly aromatic polyester composition.

  全芳香族聚酯组合物，包括 (a) 100 份（按重量计）全芳香族聚酯，其主要成分含有至少一种选自芳香族二 羧酸、芳香族二羟基化合物和芳香族羟基羧酸的化合物，以及 (b) 5 至 300 重量份的低分子量化合物，该化合物与全芳香族聚酯基本不发生 反应，在常压下沸点至少约为 200℃，分子量不超过 1.000。 全芳香族聚酯组合物的有利生产方法是在低分子量化合物存在下，在熔融状态下对聚酯形成起始混合物进行缩聚。 全芳香族聚酯的薄膜状或纤维状制品可通过从全芳香族聚酯组合物的薄膜状或纤维状制品中提取低分子量化合物而制成。
• Production of a film-like or fibrous structure of an aromatic polyester
  申请人：TEIJIN LIMITED

  公开号：EP0057387A2

  公开（公告）日：1982-08-11

  A process for producing a film-like or fibrous structure of an aromatic polyester, which comprises (1) forming an unstretched film-like or fibrous structure by melt-shaping a blend comprising 100 parts by weight of (A) an aromatic polyester having a high degree of polymerization derived from an aromatic dicarboxylic acid as a main acid component and an aliphatic diol and/or an alicyclic diol as a main glycol component and (B) 3 to 300 parts by weight of a low-molecular-weight compound being substantially non-reactive with the aromatic polyester (A) and having a boiling point of at least about 200°C under atmospheric pressure and a molecular weight of not more than 1,000, (2) stretching the resulting film-like or fibrous structure, (3) extracting at least a major portion of the low-molecular-weight compound from the stretched film-like or fibrous structure by using an organic solvent which does not substantially dissolve the aromatic polyester under the extracting conditions, and (4) if desired, heat-setting the film-like or fibrous structure after the stretching step (2) and/or the extracting step (3). The film-like or fibrous structure of an aromatic polyester prepared by the process substantially contains no low-molecular-weight compound or contains the low-molecular-weight compound in an amount of up to about 1 part by weight at most per 100 parts by weight of the aromatic polyester.

  一种生产芳香族聚酯膜状或纤维状结构的工艺，包括 (1) 通过熔融定型混合料形成一种未拉伸的膜状或纤维状结构，该混合料包括：(A) 以芳香族二羧酸为主要酸组分，以脂肪族二元醇和/或脂环族二元醇为主要二元醇组分的具有高聚合度的芳香族聚酯；(B) 3 至 300 份（重量）与芳香族聚酯(A)基本不反应且沸点至少约为 200℃的低分子量化合物；(C) 100 份（重量）与芳香族聚酯(A)具有高聚合度的芳香族聚酯。(B) 3 至 300 重量份的低分子量化合物，该化合物基本上不与芳香族聚酯 (A) 反应，在常压下的沸点至少约为 200°C，分子量不超过 1、000, (2) 拉伸得到的薄膜状或纤维状结构、 (3) 使用在萃取条件下基本上不溶解芳香族聚酯的有机溶剂，从拉伸的膜状或纤维状结构中萃取至少大部分低分子量化合物，以及 (4) 如果需要，在拉伸步骤 (2) 和/或萃取步骤 (3) 之后对薄膜状或纤维状结构进行热固。 通过该工艺制备的芳香族聚酯的膜状或纤维状结构基本上不含低分子量化合物，或含低分子量化合物的量最多为每 100 份芳香族聚酯中约 1 份（重量）。
• Wholly aromatic polyester composition and process for producing it
  申请人：TEIJIN LIMITED

  公开号：EP0156966A1

  公开（公告）日：1985-10-09

  A wholly aromatic polyester composition comprising (a) 100 parts by weight of a wholly aromatic polyester containing as a main component at least one compound selected from the group consisting of aromatic dicarboxylic acids, aromatic dihydroxy compounds and aromatic hydroxycarboxylic acids, and (b) from 5 to 300 parts by weight of a low-molecular-weight compound, which is non-reactive with the wholly caromatic polyester and has a boiling point of at least 200 °C under atmospheric pressure and a molecular weight of not more than 1,000 and is selected from the group consisting of imide compounds of the formula (1)-a wherein A' represents a divalent aromatic group which may be substituted; R1 represents an aromatic group or linear or cyclic aliphatic group having a valence of n, each of which may be substituted; n is 1 or 2; and the imide ring is 5- or 6-membered, imide compounds of formula (1)-b wherein A2 represents a tetravalent aromatic group which may be substituted; R2 represents a monovalent linear or cyclic aliphatic group which may be substituted; and the imide rings are 5- or 6-membered, trialkyl isocyanurates of formula (1)-c wherein R3 represents a monovalent alkyl group,and diphenyl sulfone compounds of formula (1)-d wherein the phenyl rings may be substituted.

  全芳香族聚酯组合物，包括 (a) 100 份（按重量计）全芳香族聚酯，其主要成分含有至少一种选自芳香族二 羧酸、芳香族二羟基化合物和芳香族羟基羧酸的化合物，以及 (b) 5 至 300 重量份的低分子量化合物，该化合物与全芳香族聚酯不发生反应，在常 压下沸点至少为 200 °C，分子量不超过 1,000，且选自由式 (1)-a 的酰亚胺化 合物组成的组。 其中 A'代表可被取代的二价芳香族基团；R1 代表芳香族基团或价数为 n 的线性或环状脂肪族基团，每个基团均可被取代；n 为 1 或 2；亚胺环为 5 或 6 元环；式 (1)-b 的亚胺化合物 其中 A2 代表可被取代的四价芳香族基团；R2 代表可被取代的一价线性或环状脂肪族基团；亚胺环是式 (1)-c 的 5 或 6 元三烷基异氰尿酸酯 式(1)-d的二苯砜化合物，其中R3代表一价烷基。 其中的苯基环可能被取代。
• Mixtures of polyamideimides, containing 3,4'-diaminodiphenylether as diamine component, and of a plasticizer.
  申请人：TEIJIN LIMITED

  公开号：EP0210851A2

  公开（公告）日：1987-02-04

  A polyimide capable of forming a self-supporfing film, comprising a unit represented by the following formula (I) and a unit represented by the following formula (II) as main units forming the molecular chains of the polyimide; and an intimate mixture comprising (A) a polyamideimide comprising a unit of the following formula (II) and a unit of the following formula (IV) as main units forming the molecular chains of the polyamideimide, and (B) a plasticizing material for the polyamideimide (A).

  一种能形成自支撑薄膜的聚酰亚胺，由下式（I）代表的单元和下式（II）代表的单元组成 和下式（II）所代表的单元作为构成聚酰亚胺分子链的主单元 作为构成聚酰亚胺分子链的主单元；以及一种亲密混合物，其中包括 (A) 一种聚酰胺酰亚胺，包含下式（II）单元 和下式（IV）的一个单元 (B) 聚酰胺酰亚胺 (A) 的增塑材料。
• Application of the Study of Reactivity of Alkaline Salts of Isocyanuric Acid to the Synthesis of Mono- and Trisubstituted Isocyanurates
  作者：Muriel Chiron-Charrier、Paul Caubére

  DOI：10.1080/00397919308013795

  日期：1993.11

  Reactivity of alkaline salts of isocyanuric acid has been studied. It has been established that the nucleophilic substitution is not selective because of the protonic exchanges between salts and substituted derivatives. The synthesis of mono or trisubstituted derivative is due to secondary reactions and to solvent effects. With this study, it has been possible to settle a method to prepare mono and trisubstituted derivatives of isocyanuric acid.