Thiotris(trimethylsilylthio)phosphor | 63853-23-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Thiotris(trimethylsilylthio)phosphor
• 英文别名: tris(trimethylsilyl)tetrathiophosphate；tetrathiophosphoric acid tris-trimethylsilanyl ester；sulfanylidene-tris(trimethylsilylsulfanyl)-λ5-phosphane
• CAS: 63853-23-6
• 化学式: C₉H₂₇PS₄Si₃
• 分子量: 378.808
• InChiKey: PJFMTAVVXKYCKW-UHFFFAOYSA-N

物化性质

• 沸点：
  363.8±25.0 °C(Predicted)
• 密度：
  1.057±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.92
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  108
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dichlorobis(triethylphosphine)palladium(II) 、 Thiotris(trimethylsilylthio)phosphor 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  (S)P(SSiMe3)3 als Ausgangsverbindung für die Synthese neuer Palladium-Clusterkomplexe

  摘要：

  The silylated derivative of thiophosphoric acid (S)P(SSiMe3)(3) is used as a convenient starting compound for the synthesis of multinuclear Pd cluster complexes. (S)P(SSiMe3)(3) reacts with Pd(acac)(2)/PPh3 and [PdCl2(PPh3)(2)] to give the following crystalline compounds: [Pd-2(PS4)Cl(PEt3)(3)] (1), [Pd-2(PS4)(PEt3)(4)]Cl (2), [Pd-3(PS4(PS3)(PEt3)(4)] (3), [Pd-6(PS4)(4)(PPh3)(6)] (4) and [Pd-6(PS2(OEt)(2))(2)(mu(3)-s)(mu(2)-SH)(2)(PPh3)(4)] (5). The above mentioned compounds have been characterised by X-ray structure determination.

  DOI：

  10.1002/(sici)1521-3749(199912)625:12<2064::aid-zaac2064>3.0.co;2-1

文献信息

• Preisenberger, Max; Pyykkoe, Pekka; Schier, Annette, Inorganic Chemistry, 1999, vol. 38, p. 5870 - 5875
  作者：Preisenberger, Max、Pyykkoe, Pekka、Schier, Annette、Schmidbaur, Hubert

  DOI：——

  日期：——
• (S)P(SSiMe3)3 als Ausgangsverbindung für die Synthese neuer Palladium-Clusterkomplexe
  作者：Stefan Wirth、Dieter Fenske

  DOI：10.1002/(sici)1521-3749(199912)625:12<2064::aid-zaac2064>3.0.co;2-1

  日期：1999.12

  The silylated derivative of thiophosphoric acid (S)P(SSiMe3)(3) is used as a convenient starting compound for the synthesis of multinuclear Pd cluster complexes. (S)P(SSiMe3)(3) reacts with Pd(acac)(2)/PPh3 and [PdCl2(PPh3)(2)] to give the following crystalline compounds: [Pd-2(PS4)Cl(PEt3)(3)] (1), [Pd-2(PS4)(PEt3)(4)]Cl (2), [Pd-3(PS4(PS3)(PEt3)(4)] (3), [Pd-6(PS4)(4)(PPh3)(6)] (4) and [Pd-6(PS2(OEt)(2))(2)(mu(3)-s)(mu(2)-SH)(2)(PPh3)(4)] (5). The above mentioned compounds have been characterised by X-ray structure determination.