6-(二丁氨基)-1,8-二氮杂二环[5.4.0]十一碳-7-烯 | 106847-76-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环庚烷
• 中文名称: 6-(二丁氨基)-1,8-二氮杂二环[5.4.0]十一碳-7-烯
• 中文别名: 6-(二丁基氨基)-1,8-二氮杂二环[5.4.0]十一碳-7-烯；6-(二丁基氨基)-1,8-二氮杂双环[5.4.0]-7-十一烯
• 英文名称: 6-(Dibutylamino)-1,8-diazabicyclo[5.4.0]undec-7-ene
• 英文别名: N,N-dibutyl-2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepin-10-amine
• CAS: 106847-76-1
• 化学式: C₁₇H₃₃N₃
• 分子量: 279.5
• InChiKey: MGKYTFDYDXZTEM-UHFFFAOYSA-N

物化性质

• 沸点：
  312 °C(lit.)
• 密度：
  0.942 g/mL at 25 °C(lit.)
• 闪点：
  >230 °F
• 溶解度：
  不溶于水
• 稳定性/保质期：
  如果按照规定使用和储存，则不会分解，没有已知的危险反应，应避免与强氧化物接触。

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  18.8
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险品标志：
  C
• 安全说明：
  S26
• 危险类别码：
  R34
• 海关编码：
  2933990090
• WGK Germany：
  3
• 危险品运输编号：
  UN 1760

制备方法与用途

用途：聚合反应加速剂。

文献信息

• [EN] PROCESS FOR THE SYNTHESIS OF FLUORALKYL SULFONATE SALTS<br/>[FR] PROCÉDÉ DE SYNTHÈSE DE SELS DE SULFONATE DE FLUORALKYLE
  申请人：SOLVAY SPECIALTY POLYMERS IT

  公开号：WO2015049239A1

  公开（公告）日：2015-04-09

  A process for the preparation of the fluoroalkyl sulfonate salt of a nitrogen-based organic base said process comprising the step of reacting a fluoroalkyl sulfonyl halide with an organic base selected from the group consisting of tertiary amines, pyridines, amidines and guanidines.

  一种制备氟烷基磺酸盐的氮基有机碱的过程，该过程包括将氟烷基磺酰卤与从三级胺、吡啶、脲和胍组成的有机碱反应的步骤。
• AMIDINE GROUP - OR GUANIDINE GROUP - CONTAINING SILANE
  申请人：SIKA TECHNOLOGY AG

  公开号：US20170081348A1

  公开（公告）日：2017-03-23

  A silane of the formula (I) containing at least one aliphatic amidine group- or guanidine group-containing alkoxy group, to a method for producing same, to conversion products thereof, and to the use thereof as a catalyst in curable compositions, in particular based on silane group-containing polymers. The silane of the formula (I) is largely odorless and non-volatile at room temperature. The silane accelerates the hydrolysis and condensation reaction of silane groups very effectively without impairing the storage stability of silane group-containing polymers. Additionally, the silane is very tolerable in silane group-containing compositions, whereby such compositions are not prone to separate, migrate, or evaporate the catalyst.

  公式（I）中含有至少一个脂肪族酰胺基或含有酰胺基的胍基的烷氧基团的硅烷，以及生产同类产物的方法，以及将其用作固化组合物中的催化剂的用途，特别是基于含硅烷基的聚合物。公式（I）中的硅烷在室温下基本无味且不挥发。该硅烷有效加速硅烷基的水解和缩合反应，而不会影响含硅烷基聚合物的储存稳定性。此外，该硅烷在含硅烷基的组合物中具有很高的耐受性，因此这些组合物不容易分离、迁移或挥发出催化剂。
• GLYCOSYLATED VALPROIC ACID ANALOGS AND USES THEREOF
  申请人：HEYMAN Norman S.

  公开号：US20130029924A1

  公开（公告）日：2013-01-31

  Glycosylated valproic acid and its analogs are provided. In some embodiments, the glycosylated valproic acid and its analogs have improved solubility and are ideal for drug delivery to treat a variety of diseases.

  提供了糖基化的丙戊酸及其类似物。在某些实施方式中，糖基化的丙戊酸及其类似物具有改善的溶解性，并且非常适合用于药物输送以治疗各种疾病。
• HYDROXYSILANE AND POLYMER CONTAINING SILANE GROUPS
  申请人：SIKA TECHNOLOGY AG

  公开号：US20160102110A1

  公开（公告）日：2016-04-14

  Special hydroxysilanes, which can be obtained by reacting β-(3,4-epoxycyclohexyl)alkyltrialkoxysilanes with secondary amines, and adducts of the hydroxysilanes in the form of polymers containing silane groups. The hydroxysilanes can be produced having high purity in a simple process and are very stable in storage after production. The polymers containing silane groups that can be obtained by means of the hydroxysilanes have advantageous properties. The polymers enable moisture-curing compositions, which contain no isocyanate groups and which are suitable as elastic adhesives and sealants.

  特殊的羟基硅烷可以通过将β-(3,4-环氧环己基)烷基三烷氧基硅烷与二级胺发生反应获得，并以含硅基团的聚合物形式存在。这些羟基硅烷可以通过简单的工艺制备高纯度，并在生产后储存时非常稳定。通过这些羟基硅烷可以获得具有优越性能的含硅基团的聚合物。这些聚合物使得含有羟基硅烷的水固化组合物成为可能，这些组合物不含异氰酸酯基团，适用于弹性胶粘剂和密封剂。
• AMIDINE CATALYST FOR CURABLE COMPOSITIONS
  申请人：SIKA TECHNOLOGY AG

  公开号：US20180179165A1

  公开（公告）日：2018-06-28

  The present invention relates to an amidine of the formula (I) and its use as a catalyst for crosslinking a curable composition. The amidine of the formula (I) contains at least one aliphatic amidine group. It is substantially odorless and nonvolatile at room temperature and accelerates the crosslinking of curable compositions very efficiently, without impairing the storage stability of the compositions. It is particularly suitable for compositions based on polymers containing silane groups, with which it is compatible, as a result of which such compositions do not have a tendency to separation or migration or evaporation of the catalyst.

  本发明涉及一种公式（I）的酰胺衍生物及其作为可固化组合物交联催化剂的用途。公式（I）的酰胺衍生物包含至少一个脂肪族酰胺基团。该酰胺衍生物在室温下几乎无味且不挥发，在不损害组合物的储存稳定性的情况下，能够高效地加速可固化组合物的交联反应。它特别适用于基于含有硅烷基的聚合物的组合物，因为它与这些聚合物兼容，从而使得这些组合物不具有催化剂分离、迁移或挥发的倾向。