Bis(2,2,6,6-tetramethylpiperidin-1-yl) decanediperoxoate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: Bis(2,2,6,6-tetramethylpiperidin-1-yl) decanediperoxoate
• 英文别名: bis(2,2,6,6-tetramethylpiperidin-1-yl) decanediperoxoate
• 化学式: C₂₈H₅₂N₂O₆
• 分子量: 512.7
• InChiKey: ASZLHRGZQJHPRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  36
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  77.5
• 氢给体数：
  0
• 氢受体数：
  8

文献信息

• [EN] METHOD OF PREPARING FUNCTIONAL ORGANOSILANOL COMPOUNDS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS ORGANOSILANOLS FONCTIONNELS
  申请人：DOW SILICONES CORP

  公开号：WO2020142281A1

  公开（公告）日：2020-07-09

  A method of preparing an organosilanol compound is disclosed. The method comprises reacting (A) an initial organosilicon compound and (B) water in the presence of (C) a catalyst. The catalyst (C) is selected from: (C1) [(C8H12irCI]2 [(p-cymene)RuCl2]2; and (C3) Pd/C. The initial organosilicon compound (A) has the general formula HO-Si(R)2- [Si(R)2O]a-OSi(R)2-Y and the organosilanol compound has the general formula HO-Si(R)2- [Si(R)2O]a-OSi(R)2-Y, where each R is an independently selected hydrocarbyl group; Y comprises a functional moiety selected from alkoxysilyl moieties, epoxide moieties, and acryloxy moieties, with the proviso that Y is other than the acryloxy moieties when the catalyst (C) is (C3) Pd/C; and subscript a is 0 or 1. The organosilanol compound prepared by the method is also provided.

  公开了一种制备有机硅醇化合物的方法。该方法包括在催化剂（C）的存在下，将（A）一种初始有机硅化合物和（B）水反应。催化剂（C）选自：（C1）[(C8H12irCI)2][(p-cymene)RuCl2]2；和（C3）Pd/C。初始有机硅化合物（A）具有一般式HO-Si（R）2-[Si（R）2O]a-OSi（R）2-Y，有机硅醇化合物具有一般式HO-Si（R）2-[Si（R）2O]a-OSi（R）2-Y，其中每个R是独立选择的烃基团；Y包括从烷氧基硅烷基团、环氧基团和丙烯氧基团中选择的官能团，但当催化剂（C）为（C3）Pd/C时，Y除丙烯氧基团外；下标a为0或1。还提供了通过该方法制备的有机硅醇化合物。
• METHOD OF PREPARING FUNCTIONAL ORGANOSILANOL COMPOUNDS
  申请人：Dow Silicones Corporation

  公开号：EP3906243A1

  公开（公告）日：2021-11-10
• MULTIFUNCTIONAL ORGANOSILICON COMPOUND AND RELATED METHODS, COMPOUNDS, AND COMPOSITIONS
  申请人：Dow Silicones Corporation

  公开号：EP3906245A1

  公开（公告）日：2021-11-10
• [EN] MULTIFUNCTIONAL ORGANOSILICON COMPOUND AND RELATED METHODS, COMPOUNDS, AND COMPOSITIONS<br/>[FR] COMPOSÉ D'ORGANOSILICIUM MULTIFONCTIONNEL ET PROCÉDÉS, COMPOSÉS ET COMPOSITIONS ASSOCIÉS
  申请人：DOW SILICONES CORP

  公开号：WO2020142443A1

  公开（公告）日：2020-07-09

  A multifunctional organosilicon compound is provided which has the general formula XSi([OSiR2]p-0-SiR2Y)a(R1)3-a- ln the formula, X is selected from H and ethylenically un saturated moieties; each Y independently comprises a functional moiety selected from alkoxysilyl moieties, acryloxy moieties, and epoxide moieties; each R is an independently selected hydrocarbyl group; each R1 is an independently selected hydrocarbyl group; subscript a is 1, 2, or 3; and each subscript b is independently 0, 1, or 2. A method of preparing the multifunctional organosilicon compound is also provided. The method comprises reacting (A) an organosilanol compound and (B) a silane compound having at least two hydrolysable groups. A functionalized siloxane compound prepared from the multifunctional organosilicon compound, a method of preparing the functionalized siloxane compound, and an adhesive comprising the functionalized siloxane compound are also provided.
• [EN] PREPARATION OF MULTIFUNCTIONAL ORGANOSILICON COMPOUNDS<br/>[FR] PRÉPARATION DE COMPOSÉS D'ORGANOSILICIUM MULTIFONCTIONNELS
  申请人：DOW SILICONES CORP

  公开号：WO2022006207A1

  公开（公告）日：2022-01-06

  A method of preparing a multifunctional organosilicon compound is provided. The method comprises reacting (A) an organosilanol compound comprising a functional moiety selected from alkoxysilyl moieties and acryloxy moieties and (B) a hydridosilane compound having at least two hydrolysable groups in the presence of (C) an acetate salt. A multifunctional organosilicon compound prepared according to the method is also provided.