2,3-Dimethyl-1-butylimidazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑啉类
• 英文名称: 2,3-Dimethyl-1-butylimidazole
• 英文别名: 1-butyl-2,3-dimethyl-2H-imidazole
• 化学式: C₉H₁₈N₂
• 分子量: 154.25
• InChiKey: TYOCDPIZUIQUSO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• [EN] COMPOUNDS CONTAINING ALKYL-CYANO-BORATE OR ALKYL-CYANO-FLUOROBORATE ANIONS<br/>[FR] COMPOSÉS CONTENANT LES ANIONS ALKYLE, CYANO, BORATE OU ALKYLE, CYANO, FLUOROBORATE
  申请人：MERCK PATENT GMBH

  公开号：WO2013010641A1

  公开（公告）日：2013-01-24

  The invention relates to new compounds containing alkyl/alkenyl-cyano- borate or alkyl/a!kenyl-cyano-fluoroborate anions, their preparation and their use, in particular as part of electrolyte formulations for electrochemical or optoelectronic devices.

  该发明涉及包含烷基/烯基-氰基硼酸或烷基/烯基-氰基氟硼酸阴离子的新化合物，它们的制备及其用途，尤其是作为电化学或光电子设备电解质配方的一部分。
• [EN] IONIC LIQUIDS BASED ON OXALIC ACID MONO ESTERS<br/>[FR] LIQUIDES IONIQUES À BASE DE MONOESTERS DE L'ACIDE OXALIQUE
  申请人：BASF SE

  公开号：WO2014056844A1

  公开（公告）日：2014-04-17

  Monosubstituted oxalic acid derivatives of the general formula (I) [A]+[O-C(O)-C(O)-O-X]-, wherein the meaning is: for [A]+, a cation made from an organic moiety A having a formally positively charged heteroatom selected from the group consisting of nitrogen, phosphorus and sulfur, X is a C1 to C30 organic residue, and wherein the following compounds (I) are disclaimed:tetramethylammonium monomethyloxalate methyltri(alkyl)ammonium monomethyloxalate trimethyl(1-hydroxyethyl)ammonium monomethyloxalate methyltriethylammonium monomethyloxalate tetraethylammonium monomethyloxalate n-propyltriethylammonium mono-n-propyloxalate n-butyltriethylammonium mono-n-butyloxalate benzyltriethylammonium monobenzyloxalate cyclohexyldimethylammonium monomethyloxalate dimethyl-phenylammonium monomethyloxalate. Tetrabutylammonium monomethyloxalate N-methylpyridinium monomethyloxalate N-ethylpyridinium monoethyloxalate N-n-propylpyridinium mono-n-propyloxalate N-n-butylpyridinium mono-n-butyl-oxalate N-benzylpyridinium monobenzyloxalate N-methyl-isochinolinium monomethyloxalate N-ethyl-isochinolinium monoethyloxalate N-n-propyl-isochinoliniummono-n-propyloxalate N-n-butyl-isochinolinium mono-n-butyloxalate N-benzyl-isochinolinium monobenzyloxalate.

  单取代草酸衍生物的一般式(I) [A]+[O-C(O)-C(O)-O-X]-，其中含义为：对于[A]+，是由有机基团A形成的阳离子，其正式带正电的杂原子选自氮、磷和硫组成的群，X是一个C1到C30的有机残基，且以下化合物(I)被否认：四甲基铵单甲氧草酸酯 甲基三(烷基)铵单甲氧草酸酯 三甲基(1-羟乙基)铵单甲氧草酸酯 甲基三乙基铵单甲氧草酸酯 四乙基铵单甲氧草酸酯 正丙基三乙基铵单正丙氧草酸酯 正丁基三乙基铵单正丁氧草酸酯 苄基三乙基铵单苄氧草酸酯 环己基二甲基铵单甲氧草酸酯 二甲基苯基铵单甲氧草酸酯。 四丁基铵单甲氧草酸酯 N-甲基吡啶铵单甲氧草酸酯 N-乙基吡啶铵单乙氧草酸酯 N-正丙基吡啶铵单正丙氧草酸酯 N-正丁基吡啶铵单正丁氧草酸酯 N-苄基吡啶铵单苄氧草酸酯 N-甲基异喹啉铵单甲氧草酸酯 N-乙基异喹啉铵单乙氧草酸酯 N-正丙基异喹啉铵单正丙氧草酸酯 N-正丁基异喹啉铵单正丁氧草酸酯 N-苄基异喹啉铵单苄氧草酸酯。
• Method of producing nitrile compounds
  申请人：——

  公开号：US20040260112A1

  公开（公告）日：2004-12-23

  The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and &egr;-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.

  本发明涉及通过与氢氰酸反应从不饱和有机化合物制备腈化合物。更具体地，它涉及制备用于合成己二腈的腈化合物，己二腈是制造主要化学化合物如六亚甲基二胺和ε-己内酰胺的重要化学中间体。该发明提供了一种制备至少含有一个腈官能团的有机化合物的方法，通过在氢氰酸和至少含有一个乙烯不饱和度的有机化合物之间进行氢氰化反应来实现。该反应在催化系统的存在下进行，该催化系统包括从镍、铂和钯组成的金属元素和一个有机磷配体，反应介质另外还包括至少在进行氢氰化反应的温度下处于液态的离子液体。
• Bis(perfluoralkyl)phosphinous acids and derivatives and use thereof
  申请人：Hoge Berthold

  公开号：US20110124873A1

  公开（公告）日：2011-05-26

  The invention relates to bis(perfluoroalkyl)phosphinous acids, bis(perfluoroalkyl)thiophosphinous acids and derivatives, the synthesis thereof and the use thereof, in particular for the synthesis of air-stable metal complexes for catalytic processes.

  这项发明涉及双(全氟烷基)膦酸、双(全氟烷基)硫膦酸及其衍生物，其合成和用途，特别是用于合成用于催化过程的空气稳定金属配合物。
• Process of telomerizing conjugated dienes
  申请人：Celanese Chemicals Europe GmbH

  公开号：EP1201634A1

  公开（公告）日：2002-05-02

  The present invention is related to a process for telomerizing a conjugated diene which comprises reacting said conjugated diene with a compound containing active hydrogen in the presence of a catalyst system comprising at least one transition metal compound, at least one phosphorus-containing compound, and at least one salt which forms a liquid under the conditions of the telomerization process.

  本发明涉及一种用于对共轭二烯进行缩聚的方法，包括在存在至少一种过渡金属化合物、至少一种含磷化合物和至少一种在缩聚过程条件下形成液体的盐的催化剂体系的情况下，将所述共轭二烯与含活性氢的化合物反应的过程。