1-Methyl-1-[6-(1-methylpiperidin-1-ium-1-yl)hexyl]piperidin-1-ium

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1-Methyl-1-[6-(1-methylpiperidin-1-ium-1-yl)hexyl]piperidin-1-ium
• 化学式: C18H38N2+2
• 分子量: 282.5
• InChiKey: SHVYPTOWNDGXEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• COMPOSITION OF MATTER AND STRUCTURE OF ZEOLITE UZM-55
  申请人：UOP LLC

  公开号：US20180099267A1

  公开（公告）日：2018-04-12

  A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M + m R r Al 1-x E x Si y O z where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions.

  一种新的具有MTT框架的晶体铝硅酸盐沸石已被合成，被指定为UZM-55。这种沸石由以下经验公式表示： M + m R r Al 1-x E x Si y O z 其中M代表从锌或周期表中的第1组（IUPAC 1）、第2组（IUPAC 2）、第3组（IUPAC 3）或镧系元素中选择的一种或多种金属，包括钠、钾或钠和钾离子的组合，R是由反应物R1和R2派生的有机结构导向剂或剂，其中R1是二异丙醇胺，R2是螯合二胺，E是从包括镓、铁、硼和混合物等元素组中选择的一种元素。由UZM-55制成的催化剂在多种烃转化反应中有用途。
• COMPOSITION OF MATTER AND STRUCTURE OF ZEOLITE UZM-55 AND USE IN ISOMERIZATION OF AROMATIC MOLECULES
  申请人：UOP LLC

  公开号：US20180170835A1

  公开（公告）日：2018-06-21

  Isomerization processes such as the isomerization of ethylbenzene and xylenes, are catalyzed by the new crystalline aluminosilicate zeolite comprising a novel framework type that has been designated UZM-55. This zeolite is represented by the empirical formula: M + m RAl 1-x E x Si y O z where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions.

  乙苯和二甲苯等异构化过程，是由一种新型的结晶铝硅酸盐沸石催化，这种沸石具有一种被指定为UZM-55的新型框架类型。这种沸石可以用经验公式表示为：M+mRAl1-xExSiyOz，其中M代表从锌或周期表中的第1组（IUPAC 1）、第2组（IUPAC 2）、第3组（IUPAC 3）或镧系元素中选择的金属或金属，包括钠、钾或钠和钾离子的组合，R是由反应物R1和R2派生的有机结构导向剂或导向剂，其中R1是二异丙醇胺，R2是螯合二胺，E是从由镓、铁、硼和混合物组成的组中选择的一个元素。由UZM-55制成的催化剂在各种烃转化反应中有用途。
• SYNTHESIS OF MSE-FRAMEWORK TYPE MOLECULAR SIEVES
  申请人：WESTON SIMON C.

  公开号：US20130115163A1

  公开（公告）日：2013-05-09

  A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1 yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1′-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1′-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).

  合成具有MSE框架类型的结晶分子筛的方法包括结晶化一个反应混合物，该混合物包含水的来源、一个四价元素Y的氧化物的来源，Y选自至少一个硅、锡、钛、钒和锗中，可选地包含一个三价元素X的来源、一个碱金属或碱土金属M的来源，以及一个有机二价阳离子Q的来源，例如3-羟基-1-(4-(1-甲基哌啶-1-ium-1-基)丁基)喹哪啶-1-ium、3-羟基-1-(5-(1-甲基哌啶-1-ium-1-基)戊基)喹哪啶-1-ium、1,1′-(丁烷-1,4-二基)双(1-甲基哌啶-1-ium)、1,1′-(戊烷-1,5-二基)双(1-甲基哌啶-1-ium)、1,1′-(己烷-1,6-二基)双(1-甲基哌啶-1-ium)和1,1′-((3as,6as)-八氢蒽-2,5-二基)双(1-甲基哌啶-1-ium)。
• CATALYST COMPRISING AN IZM-2 ZEOLITE AND AT LEAST ONE METAL, AND ITS USE IN THE TRANSFORMATION OF HYDROCARBONS
  申请人：Guillon Emmanuelle

  公开号：US20110190562A1

  公开（公告）日：2011-08-04

  A catalyst is described which comprises at least one IZM-2 zeolite, at least one matrix and at least one metal selected from metals from groups VIII, VIB and VIIB, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO 2 :aY 2 O 3 :bM 2/n O, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal with valency n, a and b respectively representing the number of moles of Y 2 O 3 and M 2/n O; and a is in the range 0.001 to 0.5 and b is in the range 0 to 1.

  催化剂包含至少一种IZM-2沸石，至少一种基质和至少一种选自第VIII、VIB和VIIB族金属的金属，所述沸石的化学组成用无水基的摩尔氧化物的通式表示为：XO2:aYO3:bM2/nO，其中X代表至少一种四价元素，Y代表至少一种三价元素，M为至少一种碱金属和/或碱土金属，其价数为n，a和b分别代表YO3和M2/nO的摩尔数；a的范围为0.001到0.5，b的范围为0到1。
• ZEOLITE HAVING A ONE-DIMENSIONAL CHANNEL SYSTEM, 10-MEMBERED RINGS AND 12-MEMBERED RINGS
  申请人：UOP LLC

  公开号：US20180099875A1

  公开（公告）日：2018-04-12

  A new crystalline aluminosilicate zeolite comprising a novel framework has been synthesized that has been designated UZM-55. This zeolite is represented by a three-dimensional framework of at least SiO 2 tetrahedral units and an empirical composition in the as-synthesized and anhydrous basis expressed by an empirical formula of: M m n+ R r Al x E y SiO z where M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, R is a structure directing agent or agents such as 1,6-bis(N-methylpiperidinium)hexane, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions including methanol to hydrocarbons (MTH).

  一种新的结晶铝硅酸盐沸石，具有新颖的框架结构，已被合成，被命名为UZM-55。这种沸石由至少SiO2四面体单元构成的三维框架表示，其合成后无水基础上的经验组成为由经验公式表示： Mm+n+RrAlxEySiOz 其中M代表来自锌或第1组（IUPAC 1）、第2组（IUPAC 2）、第3组（IUPAC 3）或周期表中镧系的一种或多种金属，R是结构导向剂或结构导向剂如1,6-双（N-甲基哌啶基）己烷，E是选自镓、铁、硼和混合物组中的元素。由UZM-55制成的催化剂在各种烃转化反应中具有用途，包括甲醇至烃（MTH）。