bis(4-hydroxyphenyl)-4-biphenylyl(cyclohexyl)methane | 866141-24-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: bis(4-hydroxyphenyl)-4-biphenylyl(cyclohexyl)methane
• 英文别名: 4,4'-[([1,1'-Biphenyl]-4-yl)(cyclohexyl)methylene]diphenol；4-[cyclohexyl-(4-hydroxyphenyl)-(4-phenylphenyl)methyl]phenol
• CAS: 866141-24-4
• 化学式: C₃₁H₃₀O₂
• 分子量: 434.578
• InChiKey: JSPFDEMGCYKVCL-UHFFFAOYSA-N

物化性质

• 熔点：
  239.5 °C
• 沸点：
  623.6±50.0 °C(Predicted)
• 密度：
  1.162±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  33
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  biphenylcyclohexyl ketone 、 硫代乙酸 、 苯酚 在 三氟甲磺酸 作用下， 以 水 、 甲苯 为溶剂， 以59.2 g (51%)的产率得到bis(4-hydroxyphenyl)-4-biphenylyl(cyclohexyl)methane
  参考文献：
  名称：

  ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND

  摘要：

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。

  公开号：

  US20100129753A1

文献信息

• POLYMERIZABLE COMPOUNDS AND POLYMERIZABLE COMPOSITIONS
  申请人：Adeka Corporation

  公开号：EP2098544A1

  公开（公告）日：2009-09-09

  A polymerizable compound represented by general formula (1): wherein A represents a ring assembly composed of at least two 6-membered rings each optionally having a substituent; X1 and X2 each represent a (meth)acryloyloxy group; and Y1 and Y2 each independently represent a single bond, an optionally branched alkylene group having 1 to 8 carbon atoms, an ether linkage, -COO-, -OCO-, a 6-membered ring optionally having a substituent, a naphthalene ring optionally having a substituent, or a combination thereof; the substituent being a hydrogen atom, a halogen atom, a nitrile group, an optionally branched alkyl group having 1 to 8 carbon atoms, an optionally branched alkoxy group having 1 to 8 carbon atoms, or an optionally branched alkenyl group having 2 to 8 carbon atoms, wherein the alkyl, alkoxy, or alkenyl group may have its -CH2- moiety replaced with a sulfur atom or an oxygen atom and may have its hydrogen atom replaced with a halogen atom or a nitrile group.

  通式(1)代表的可聚合化合物： 其中 A 代表由至少两个 6 元环组成的环组件，每个 6 元环可选择具有一个取代基； X1 和 X2 各自代表(甲基)丙烯酰氧基；以及 Y1 和 Y2 各自独立地代表单键、具有 1 至 8 个碳原子的可选支链亚烷基、醚键、-COO-、-OCO-、可选择具有一个取代基的 6 元环、可选择具有一个取代基的萘环或它们的组合；取代基为氢原子、卤素原子、腈基、具有 1 至 8 个碳原子的任选支链烷基、具有 1 至 8 个碳原子的任选支链烷氧基或具有 2 至 8 个碳原子的任选支链烯基，其中烷基、烷氧基或烯基的-CH2-分子可被硫原子或氧原子取代，其氢原子可被卤素原子或腈基取代。
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND -DIKETONE COMPOUND
  申请人：Adeka Corporation

  公开号：EP2175320A1

  公开（公告）日：2010-04-14

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R1 is a C1-C20 alkyl group; R2 represents R11, OR11, COR11, SR11, CONR12R13, or CN; R11, R12, and R13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可碱显影的感光树脂组合物含有(J)可光聚合的不饱和化合物，其结构是由(B)具有β-二酮分子的化合物或具有β-酮酯基的化合物与(A)具有至少两个(甲基)丙烯酰基和一个羟基的化合物的(甲基)丙烯酰基发生加成反应，然后将加成产物的羟基与(C)多碱性酸酐酯化而成。具有 β-二酮分子的化合物最好是通式 (I) 所代表的新型 β-二酮化合物： 其中 R1 是 C1-C20 烷基；R2 代表 R11、OR11、COR11、SR11、CONR12R13 或 CN；R11、R12 和 R13 分别是氢、C1-C20 烷基等；a 是 0 至 3；b 是 0 至 4。
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2175320B1

  公开（公告）日：2013-03-13
• POLYMERIZABLE COMPOUND AND POLYMERIZABLE COMPOSITION
  申请人：Irisawa Masatomi

  公开号：US20100320419A1

  公开（公告）日：2010-12-23

  A polymerizable compound represented by general formula (1): wherein A represents a ring assembly composed of at least two 6-membered rings each optionally having a substituent; X 1 and X 2 each represent a (meth)acryloyloxy group; and Y 1 and Y 2 each independently represent a single bond, an optionally branched alkylene group having 1 to 8 carbon atoms, an ether linkage, —COO—, —OCO—, a 6-membered ring optionally having a substituent, a naphthalene ring optionally having a substituent, or a combination thereof; the substituent being a hydrogen atom, a halogen atom, a nitrile group, an optionally branched alkyl group having 1 to 8 carbon atoms, an optionally branched alkoxy group having 1 to 8 carbon atoms, or an optionally branched alkenyl group having 2 to 8 carbon atoms, wherein the alkyl, alkoxy, or alkenyl group may have its —CH 2 — moiety replaced with a sulfur atom or an oxygen atom and may have its hydrogen atom replaced with a halogen atom or a nitrite group.
• US8066906B2
  申请人：——

  公开号：US8066906B2

  公开（公告）日：2011-11-29