Methyl-vinyl-bis-(isopropyloxy)-silan | 17865-41-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Methyl-vinyl-bis-(isopropyloxy)-silan
• 英文别名: Ethenyl-methyl-di(propan-2-yloxy)silane
• CAS: 17865-41-7
• 化学式: C₉H₂₀O₂Si
• 分子量: 188.342
• InChiKey: RVZXYYFNTDJNFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.63
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  perfluoro-4-methyl-2-pentene 、 Methyl-vinyl-bis-(isopropyloxy)-silan 在 二叔丁基过氧化物 作用下， 反应 80.0h， 以99%的产率得到ethenyl-[3,4,5,6,6,6-hexafluoro-2-methyl-3,5-bis(trifluoromethyl)hexan-2-yl]oxy-methyl-propan-2-yloxysilane
  参考文献：
  名称：

  Synthesis of methylvinylpolyfluoroalkoxysilanes by photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene

  摘要：

  A new method was elaborated for the synthesis of vinylsilanes with polyfluoroalkoxy substituents at the silicon atom using the photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene in the presence of di-tert-butyl peroxide at room temperature.

  DOI：

  10.1007/bf01430653

文献信息

• Some new aspects of conjugate addition of grignard and alkyllithium reagents to vinylsilanes
  作者：Kohei Tamao、Ryuichiro Kanatani、Makoto Kumada

  DOI：10.1016/s0040-4039(01)90072-3

  日期：1984.1

  A structure and reactivity relationship has been determined on the reaction of isopropyl and n-butyl Grignard reagents and n-butyllithium with vinyl-(alkoxy)silanes and (amino)silanes. The addition to the vinyl group has been analyzed in terms of the nucleophile HOMO-vinyl group LUMO interaction.

  的结构和反应性的关系已在异丙基和的反应确定Ñ丁基格氏试剂和Ñ丁基锂与乙烯基（烷氧基）硅烷和（氨基）硅烷。已经根据亲核体HOMO-乙烯基基团LUMO的相互作用分析了乙烯基的加成基团。
• Synthesis of methylvinylpolyfluoroalkoxysilanes by photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene
  作者：N. A. Chernyavskaya、M. A. Kurykin

  DOI：10.1007/bf01430653

  日期：1996.12

  A new method was elaborated for the synthesis of vinylsilanes with polyfluoroalkoxy substituents at the silicon atom using the photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene in the presence of di-tert-butyl peroxide at room temperature.
• TAMAO, KOHEI;KANATANI, RYUICHIRO;KUMADA, MAKOTO, TETRAHEDRON LETT., 1984, 25, N 18, 1905-1908
  作者：TAMAO, KOHEI、KANATANI, RYUICHIRO、KUMADA, MAKOTO

  DOI：——

  日期：——