Bis[dimethyl(propan-2-yl)silyl]methyl-dimethyl-propan-2-ylsilane | 163678-62-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Bis[dimethyl(propan-2-yl)silyl]methyl-dimethyl-propan-2-ylsilane
• CAS: 163678-62-4
• 化学式: C₁₆H₄₀Si₃
• 分子量: 316.75
• InChiKey: KJGWYPVQJAFMPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.79
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Bis[dimethyl(propan-2-yl)silyl]methyl-dimethyl-propan-2-ylsilane 在 三甲基苯基硅烷 、 甲基锂 、 碘 作用下， 以 四氯化碳 为溶剂， 反应 121.0h， 生成 [bis[dimethyl(propan-2-yl)silyl]-[iodo(dimethyl)silyl]methyl]-dimethyl-propan-2-ylsilane
  参考文献：
  名称：

  Preparation of (iPrMe2Si)3CH and its use as a source of the bulky ligand (iPrMe2Si)3C

  摘要：

  The compound ((i)PrMe(2)Si)(3)CH has been made, and shown to be metallated slowly by MeLi in refluxing THF to give the lithium reagent ((i)PrMe(2)Si)(3)CLi. That the latter can be used to attach the bulky ligand ((i)PrMe(2)Si)(3)C to a metalloid or metal centre was demonstrated by treating it with Me(2)SiHCl to give a 77% yield of ((i)PrMe(2)Si)(3)CSiMe(2)H, which with iodine gave the iodide ((i)PrMe(2)Si)(3)CSiMe(2)I. Reactions of ((i)PrMe(2)Si)(3)CLi with Me(3)SiCl and SiCl4 likewise gave ((i)PrMe(2)Si)(3)CSiMe(3) and((i)PrMe(2)Si)(3)CSiCl3 in ca. 33% and 16% yields, respectively.

  DOI：

  10.1016/0022-328x(94)05156-6
• 作为产物：
  描述：

  三溴甲烷 、 二甲基异丙基氯硅烷 在 正丁基锂 作用下， 生成 Bis[dimethyl(propan-2-yl)silyl]methyl-dimethyl-propan-2-ylsilane
  参考文献：
  名称：

  Preparation of (iPrMe2Si)3CH and its use as a source of the bulky ligand (iPrMe2Si)3C

  摘要：

  The compound ((i)PrMe(2)Si)(3)CH has been made, and shown to be metallated slowly by MeLi in refluxing THF to give the lithium reagent ((i)PrMe(2)Si)(3)CLi. That the latter can be used to attach the bulky ligand ((i)PrMe(2)Si)(3)C to a metalloid or metal centre was demonstrated by treating it with Me(2)SiHCl to give a 77% yield of ((i)PrMe(2)Si)(3)CSiMe(2)H, which with iodine gave the iodide ((i)PrMe(2)Si)(3)CSiMe(2)I. Reactions of ((i)PrMe(2)Si)(3)CLi with Me(3)SiCl and SiCl4 likewise gave ((i)PrMe(2)Si)(3)CSiMe(3) and((i)PrMe(2)Si)(3)CSiCl3 in ca. 33% and 16% yields, respectively.

  DOI：

  10.1016/0022-328x(94)05156-6

文献信息

• Preparation of (iPrMe2Si)3CH and its use as a source of the bulky ligand (iPrMe2Si)3C
  作者：Abdulrahman I. Almansour、Colin Eaborn

  DOI：10.1016/0022-328x(94)05156-6

  日期：1995.3

  The compound ((i)PrMe(2)Si)(3)CH has been made, and shown to be metallated slowly by MeLi in refluxing THF to give the lithium reagent ((i)PrMe(2)Si)(3)CLi. That the latter can be used to attach the bulky ligand ((i)PrMe(2)Si)(3)C to a metalloid or metal centre was demonstrated by treating it with Me(2)SiHCl to give a 77% yield of ((i)PrMe(2)Si)(3)CSiMe(2)H, which with iodine gave the iodide ((i)PrMe(2)Si)(3)CSiMe(2)I. Reactions of ((i)PrMe(2)Si)(3)CLi with Me(3)SiCl and SiCl4 likewise gave ((i)PrMe(2)Si)(3)CSiMe(3) and((i)PrMe(2)Si)(3)CSiCl3 in ca. 33% and 16% yields, respectively.