1,3,5-tris(dibromoamino)-2,4,6-triazine | 34850-98-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,3,5-tris(dibromoamino)-2,4,6-triazine
• 英文别名: Hexabrommelamin；hexa-N-bromo-[1,3,5]triazine-2,4,6-triamine；hexabromomelamine；2-N,2-N,4-N,4-N,6-N,6-N-hexabromo-1,3,5-triazine-2,4,6-triamine
• CAS: 34850-98-1
• 化学式: C₃Br₆N₆
• 分子量: 599.497
• InChiKey: LVOCWUFMTNEQMK-UHFFFAOYSA-N

物化性质

• 沸点：
  522.6±33.0 °C(Predicted)
• 密度：
  3.675±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  48.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-硝基-2-亚硝基丙烷 、 1,3,5-tris(dibromoamino)-2,4,6-triazine 以 二氯甲烷 为溶剂， 反应 20.0h， 以90%的产率得到2,4,6-tris-1,3,5-triazine
  参考文献：
  名称：

  Chemical properties of N'-cyanodiazene N-oxides. Reactions involving the nitrile group

  摘要：

  The reactivity of the nitrile group in N'-cyanodiazene N-oxides has been examined for the first time. A general approach to the synthesis of nitrogenous functional derivatives of azoxycarboxylic acids by reaction of N'-cyanodiazene N-oxides with nucleophiles (water, alcohol, and hydroxylamine) is described. A method of synthesis of novel azoxy-1,2,4-oxadiazoles and tetrazoles has been developed in which aliphatic, aromatic, or heterocyclic N'-cyanodiazene N-oxides are reacted with benzonitrile N-oxide or sodium azide. Trimerization of N-cyanodiazene N-oxides, catalyzed by anhydrous HCl, has given novel symm-triazines in which the heterocycle bears three diazene N-oxide groups.

  DOI：

  10.1007/bf00961253

文献信息

• Process for preparing amide derivatives from haloaminotriazines and acid
  申请人：American Cyanamid Company

  公开号：US05288865A1

  公开（公告）日：1994-02-22

  This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides. This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs. Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process. Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.

  这项发明提供了一种通过卤胺基三嗪和酸卤化物的反应制备酸酰胺衍生物的过程。该发明还提供了一种从由卤胺基三嗪和酸卤化物（如草酰氯、光气和光气类似物）衍生的酰胺衍生物制备异氰酸酯和异氰酸酯加合物的过程。三氯和六氯三嗪与氯甲酸酯和酸氯化物的反应制备了三聚氰胺衍生的酸酰胺。在这个过程中，副产物氯可以被回收利用。通过该发明的新颖过程可以制备酰胺、氨基甲酸酯、磺胺酰胺、磷酰胺和相关酰胺衍生物。
• ZLOTIN, S. G.;PODGURSKIJ, A. P. AJRAPETOVA N. V.;LUKYANOV, O. A., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1647-1653
  作者：ZLOTIN, S. G.、PODGURSKIJ, A. P. AJRAPETOVA N. V.、LUKYANOV, O. A.

  DOI：——

  日期：——
• Chemical properties of N'-cyanodiazene N-oxides. Reactions involving the nitrile group
  作者：S. G. Zlotin、A. I. Podgurskii、N. V. Airapetova、O. A. Luk'yanov

  DOI：10.1007/bf00961253

  日期：1991.7

  The reactivity of the nitrile group in N'-cyanodiazene N-oxides has been examined for the first time. A general approach to the synthesis of nitrogenous functional derivatives of azoxycarboxylic acids by reaction of N'-cyanodiazene N-oxides with nucleophiles (water, alcohol, and hydroxylamine) is described. A method of synthesis of novel azoxy-1,2,4-oxadiazoles and tetrazoles has been developed in which aliphatic, aromatic, or heterocyclic N'-cyanodiazene N-oxides are reacted with benzonitrile N-oxide or sodium azide. Trimerization of N-cyanodiazene N-oxides, catalyzed by anhydrous HCl, has given novel symm-triazines in which the heterocycle bears three diazene N-oxide groups.