1,4-Bis-(p-cresyl)terephthalat | 4135-49-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 1,4-Bis-(p-cresyl)terephthalat
• 英文别名: terephthalic acid di-p-tolyl ester；Terephthalsaeure-di-p-tolylester；1,4-Benzenedicarboxylic acid, bis(4-methylphenyl) ester；bis(4-methylphenyl) benzene-1,4-dicarboxylate
• CAS: 4135-49-3
• 化学式: C₂₂H₁₈O₄
• mdl: MFCD00658310
• 分子量: 346.383
• InChiKey: XOGHUKBCGNLXOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-Bis-(p-cresyl)terephthalat 在 三氯化铝 、 氯苯 作用下， 生成 1,4-di(2-hydroxy-5-methylbenzoyl)benzene
  参考文献：
  名称：

  A Study of the Double Fries Rearrangement^1,2

  摘要：

  DOI：

  10.1021/ja01554a071
• 作为产物：
  描述：

  对甲酚 、 对苯二甲酰氯 生成 1,4-Bis-(p-cresyl)terephthalat
  参考文献：
  名称：

  A Study of the Double Fries Rearrangement^1,2

  摘要：

  DOI：

  10.1021/ja01554a071

文献信息

• PACKAGING MATERIAL HAVING BIREFRINGENT PATTERN
  申请人：TAKAHASHI Kouki

  公开号：US20100162666A1

  公开（公告）日：2010-07-01

  A packaging material, having at least one optically anisotropic layer which is made from substantially the same layer-forming composition and includes two or more regions different in birefringence property.

  一种包装材料，具有至少一层光学各向异性层，该层由基本相同的层形成组成，并包括两个或更多具有不同双折射性质的区域。
• Transfer Material, and Process for Producing Liquid Crystal Cell Substrate and Liquid Crystal Display Device Using the Same
  申请人：Amimori Ichiro

  公开号：US20090174857A1

  公开（公告）日：2009-07-09

  A novel transfer material is disclosed. The transfer material comprises, at least, a support, and, thereon, an optically uniaxial or biaxial anisotropic layer and a photosensitive polymer layer. A novel process for producing a liquid crystal cell substrate is also disclosed. The process comprises, at least, [1] laminating a transfer material as set forth in any one of claims 1 to 11 on a substrate; [2] removing the support from the transfer material laminated on the substrate; and [3] exposing the photosensitive polymer layer disposed on the substrate to light.

  本发明公开了一种新的转移材料。该转移材料包括至少一种支撑材料，在其上有一层光学单轴或双轴各向异性层和一层光敏聚合物层。本发明还公开了一种生产液晶电池基板的新工艺。该工艺至少包括以下步骤：[1]将任一权利要求1至11所述的转移材料层压在基板上；[2]从层压在基板上的转移材料中去除支撑材料；[3]将放置在基板上的光敏聚合物层暴露在光线下。
• SURFACE-MODIFIED INORGANIC NITRIDE, COMPOSITION, THERMALLY CONDUCTIVE MATERIAL, DEVICE PROVIDED WITH THERMALLY CONDUCTIVE LAYER
  申请人：FUJIFILM Corporation

  公开号：EP3653575A1

  公开（公告）日：2020-05-20

  A first object of the present invention is to provide a surface-modified inorganic nitride having excellent dispersibility. Furthermore, a second object of the present invention is to provide a composition, a thermally conductive material, and a device with a thermally conductive layer which contain the surface-modified inorganic nitride. The surface-modified inorganic nitride of the present invention includes an inorganic nitride, and a compound which is represented by General Formula (I) and is adsorbed onto a surface of the inorganic nitride. In General Formula (1), n represents an integer of 3 or greater. X represents an aromatic hydrocarbon ring group or an aromatic heterocyclic group. Y represents a single bond, -O-, -CO-, -CO-O-, -O-CO-, -S-, -CS-, -NRA-, -N=N-, or a divalent unsaturated hydrocarbon group. RA represents a hydrogen atom or an alkyl group. R1 and R2 each independently represent a substituent. Here, at least one of R1 or R2 represents a monovalent organic group containing a specific functional group selected from the group A of specific functional groups. In General Formula (1), a plurality of X's may be the same as or different from each other. Moreover, a plurality of X's may be the same as or different from each other.

  本发明的第一个目的是提供一种具有优异分散性的表面改性无机氮化物。此外，本发明的第二个目的是提供一种含有表面改性无机氮化物的组合物、导热材料和带有导热层的设备。 本发明的表面改性无机氮化物包括无机氮化物，以及由通式（I）表示并吸附在无机氮化物表面的化合物。 通式（1）中，n 代表 3 或更大的整数。X 代表芳香烃环基或芳香杂环基。Y 代表单键、-O-、-CO-、-CO-O-、-O-CO-、-S-、-CS-、-NRA-、-N=N-或二价不饱和烃基。RA 代表氢原子或烷基。R1 和 R2 各自独立地代表一个取代基。这里，R1 或 R2 中至少有一个代表含有选自特定官能团 A 组的特定官能团的一价有机基团。 在通式（1）中，多个 X 可以彼此相同或不同。此外，多个 X 可以彼此相同或彼此不同。
• COMPOSITION, THERMALLY CONDUCTIVE MATERIAL, DEVICE HAVING THERMAL CONDUCTION LAYER, AND METHOD OF PRODUCING THERMALLY CONDUCTIVE MATERIAL
  申请人：Fujifilm Corporation

  公开号：EP3733730A1

  公开（公告）日：2020-11-04

  A first object of the present invention is to provide a composition capable of forming a cured product (thermally conductive material) having excellent thermal conductivity. In addition, a second object of the present invention is to provide a thermally conductive material formed from the composition and a device with a thermally conductive layer. In addition, a third object of the present invention is to provide a method for manufacturing a thermally conductive material using the composition. The composition of the present invention includes a curing agent including an active hydrogen-containing functional group, and a main agent including a reactive group which reacts with the active hydrogen-containing functional group, in which the main agent and the curing agent respectively exhibit liquid crystallinity in a single state at a temperature of 150°C or lower.

  本发明的第一个目的是提供一种能够形成具有优异导热性的固化产品（导热材料）的组合物。此外，本发明的第二个目的是提供一种由该组合物形成的导热材料和一种带有导热层的装置。此外，本发明的第三个目的是提供一种使用该组合物制造导热材料的方法。 本发明的组合物包括含活性含氢官能团的固化剂和含与活性含氢官能团反应的活性基团的主剂，其中主剂和固化剂在 150°C 或更低的温度下分别表现出单一状态下的液态结晶性。
• Surface-modified inorganic substance, method for manufacturing same, resin composition, thermally conductive material, and device
  申请人：FUJIFILM Corporation

  公开号：US10633252B2

  公开（公告）日：2020-04-28

  A surface-modified inorganic substance is obtained by performing surface modification on a inorganic nitride by using an aldehyde compound such as a compound represented by General Formula I. A resin composition contains the surface-modified inorganic substance and a monomer having a group selected from the group consisting of an oxetanyl group, an oxiranyl group, and a (meth)acrylate group. ZZ—XX—CHO  General Formula I In the formula, ZZ represents a group selected from the group consisting of an amino group, a thiol group, a hydroxyl group, an isocyanate group, a carboxyl group, a carboxylic acid anhydride group, an oxetanyl group, an oxiranyl group, and a (meth)acrylate group, and XX represents a divalent linking group.

  通过使用醛化合物（如通式 I 所代表的化合物）对无机氮化物进行表面改性，可获得表 面改性无机物。树脂组合物包含表面改性无机物和单体，单体的基团选自氧杂环丁酰基、环氧丙烷基和（甲基）丙烯酸酯基。 ZZ-XX-CHO 通式 I 式中，ZZ 代表选自由氨基、硫醇基、羟基、异氰酸酯基、羧基、羧酸酐基、氧杂环丁 烯基、环氧丙烷基和(甲基)丙烯酸酯基组成的基团，XX 代表二价连接基团。