But-3-enyl-chloro-diphenyl-silane | 155449-14-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: But-3-enyl-chloro-diphenyl-silane
• 英文别名: But-3-enyl-chloro-diphenylsilane；but-3-enyl-chloro-diphenylsilane
• CAS: 155449-14-2
• 化学式: C₁₆H₁₇ClSi
• 分子量: 272.849
• InChiKey: VLORCGPICYGUDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.56
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  But-3-enyl-chloro-diphenyl-silane 在 sodium hydroxide 作用下， 以81%的产率得到But-3-enyl-diphenyl-silanol
  参考文献：
  名称：

  Intramolecular iodosilyletherization of alkenylsilanols with bis(2,4,6-trimethylpyridine)iodine(I) hexafluorophosphate

  摘要：

  Whereas iodonium ion-induced intramolecular cyclization of 3-butenyldiphenylsilanol proceeded via exo mode cyclization to give 5-iodomethyl-2,2-diphenyl-1-oxa-2-silacyclopentane selectively, iodosilyletherization of 4-methyl-3-pentenyldiphenylsilanol afforded 6,6-dimethyl-5-iodo-2,2-diphenyl-1-oxa-2-silacyclohexane exclusively via endo mode cyclization. The oxasilacycloalkanes were converted into the corresponding 1,3-diol and 1,4-diol by oxidative cleavage of the carbon-silicon bond. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0040-4039(96)01499-2
• 作为产物：
  描述：

  3-Butenylmagnesium bromide 、 二苯二氯硅烷 以68%的产率得到But-3-enyl-chloro-diphenyl-silane
  参考文献：
  名称：

  Intramolecular iodosilyletherization of alkenylsilanols with bis(2,4,6-trimethylpyridine)iodine(I) hexafluorophosphate

  摘要：

  Whereas iodonium ion-induced intramolecular cyclization of 3-butenyldiphenylsilanol proceeded via exo mode cyclization to give 5-iodomethyl-2,2-diphenyl-1-oxa-2-silacyclopentane selectively, iodosilyletherization of 4-methyl-3-pentenyldiphenylsilanol afforded 6,6-dimethyl-5-iodo-2,2-diphenyl-1-oxa-2-silacyclohexane exclusively via endo mode cyclization. The oxasilacycloalkanes were converted into the corresponding 1,3-diol and 1,4-diol by oxidative cleavage of the carbon-silicon bond. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0040-4039(96)01499-2

文献信息

• Intramolecular iodosilyletherization of alkenylsilanols with bis(2,4,6-trimethylpyridine)iodine(I) hexafluorophosphate
  作者：Koji Takaku、Hiroshi Shinokubo、Koichiro Oshima

  DOI：10.1016/s0040-4039(96)01499-2

  日期：1996.9

  Whereas iodonium ion-induced intramolecular cyclization of 3-butenyldiphenylsilanol proceeded via exo mode cyclization to give 5-iodomethyl-2,2-diphenyl-1-oxa-2-silacyclopentane selectively, iodosilyletherization of 4-methyl-3-pentenyldiphenylsilanol afforded 6,6-dimethyl-5-iodo-2,2-diphenyl-1-oxa-2-silacyclohexane exclusively via endo mode cyclization. The oxasilacycloalkanes were converted into the corresponding 1,3-diol and 1,4-diol by oxidative cleavage of the carbon-silicon bond. Copyright (C) 1996 Elsevier Science Ltd