2,2-dimethylpropyl 2,2-dimethylpropanesulfinyl sulfone | 82360-14-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: 2,2-dimethylpropyl 2,2-dimethylpropanesulfinyl sulfone
• 英文别名: 2,2-Dimethyl-propyl 2,2-dimethyl-propanesulfinyl sulfone；1-(2,2-dimethylpropylsulfonylsulfinyl)-2,2-dimethylpropane
• CAS: 82360-14-3
• 化学式: C₁₀H₂₂O₃S₂
• 分子量: 254.415
• InChiKey: HNSAPVVECVPGEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  78.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  silver niopentanesulfinate 、 2,2-dimethylpropanesulfinyl chloride 以 乙醚 为溶剂， 反应 3.0h， 以10%的产率得到2,2-dimethylpropyl 2,2-dimethylpropanesulfinyl sulfone
  参考文献：
  名称：

  .alpha.-Disulfoxide formation during the m-chloroperoxybenzoic acid oxidation of S-(2,2-dimethylpropyl) 2,2-dimethylpropanethiosulfinate

  摘要：

  DOI：

  10.1021/ja00385a035

文献信息

• Chemical ionization and electron impact mass spectra of thiosulfinates, thiosulfonates and sulfinyl sulfones
  作者：Fillmore Freeman、Christos N. Angeletakis

  DOI：10.1002/oms.1210170303

  日期：1982.3

  AbstractThe chemical ionization and electron impact mass spectra of some thiosulfinates, thiosulfonates and sulfinyl sulfones have been studied. The electron impact mass spectra of four of the six thiosulfonates show molecular ions of less than 1%. Inconclusive evidence was obtained for sulfenyl sulfinate type intermediates in the electron impact spectra of thiosulfonates. The electron impact spectra of thiosulfonates were similar to those of thiosulfonates. The chemical ionization (isobutane) mass spectra of thiosulfinates and thiosulfonates generally show protonated molecular ions [MH]+as base peaks and [MH+1]+and [MH+2]+peaks.
• FREEMAN, F.;ANGELETAKIS, C. N., J. AMER. CHEM. SOC., 1982, 104, N 21, 5766-5774
  作者：FREEMAN, F.、ANGELETAKIS, C. N.

  DOI：——

  日期：——
• .alpha.-Disulfoxide formation during the m-chloroperoxybenzoic acid oxidation of S-(2,2-dimethylpropyl) 2,2-dimethylpropanethiosulfinate
  作者：Fillmore Freeman、Christos N. Angeletakis

  DOI：10.1021/ja00385a035

  日期：1982.10

表征谱图