dichloroplatinum;ethene;methylsulfinylmethane | 31902-28-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 亚砜
• 英文名称: dichloroplatinum;ethene;methylsulfinylmethane
• CAS: 31902-28-0；39722-87-7
• 化学式: C₄H₁₀Cl₂OPtS
• 分子量: 372.175
• InChiKey: FHYNYVMWNMOCGF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.17
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dichloroplatinum;ethene;methylsulfinylmethane 以 neat (no solvent, solid phase) 为溶剂， 生成 {Pt(Me2SO)(μ-Cl)Cl}2
  参考文献：
  名称：

  cis-Influence determination of ethylene and benzyl cyanide ligands in the complexes cis-[Pt(Me2SO)(C2H4)Cl2] and cis-[Pt(Me2SO)-(PhCH2CN)Cl2] on the basis of X-ray structure data. IR and 1H, 13C and 195Pt NMR characterization of the cis-[Pt(Me2SO)LCl2] series

  摘要：

  Complexes of the cis-[Pt(Me2SO)LCl2] series (L = Me2SO, Me2S, C2H4, MeCN, PhCH2CN, PhCN, C5H5N, 2Me-C5H4N and NH3) were prepared by known methods and characterized by IR and H-1, C-13{H-1}, Pt-195{H-1} NMR spectra. Structures of cis-[Pt(Me2SO)(C2H4)Cl2] and cis-[Pt(Me2SO)(PhCH2CN)Cl2] were determined by X-ray analysis. cis-[Pt(Me2SO((C2H4)Cl2] Crystallizes in the orthorhombic space group Pmnb. The unit cell parameters are a = 8.200(1), b = 12.924(3), c = 8.574(1) angstrom, V = 908.7(3) angstrom 3, rho-calc = 2.72 gcm-3, Z = 4. cis-[Pt(Me2SO)(PhCH2CN)Cl2] crystallizes in the monoclinic space group P2(1)/n. The unit cell parameters are: a = 12.223(4), b = 16.605(4), c = 6.779(2) angstrom, gamma = 91.10(2)-degrees, V = 1375.6(7) angstrom 3, rho-calc = 2.23 g cm-3 , Z = 4. On the basis of the X-ray structure data cis- and trans-influence of C2H4 and PhCH2CN ligands were determined.

  DOI：

  10.1016/s0020-1693(00)85437-7
• 作为产物：
  描述：

  无水蔡斯盐 在 Me₂SO 作用下， 以 水 为溶剂， 生成 dichloroplatinum;ethene;methylsulfinylmethane
  参考文献：
  名称：

  Sarhan, Jamil K. K.; Green, Michael; Al-Najjar, Ibrahim M., Journal of the Chemical Society, Dalton Transactions, 1984, p. 771 - 778

  摘要：

  DOI：

文献信息

• Neighboring group effects on the stability of azaplatinacyclobutane rings in (2-aminoethyl)platinum(II) compounds
  作者：Michael Green、Jamil K. K. Sarhan、Ibrahim M. Al-Najjar

  DOI：10.1021/om00082a002

  日期：1984.4
• GREEN, M.;SARHAN, J. K. K.;AL-NAJJAR, IBRAHIM, M., ORGANOMETALLICS, 1984, 3, N 4, 520-524
  作者：GREEN, M.、SARHAN, J. K. K.、AL-NAJJAR, IBRAHIM, M.

  DOI：——

  日期：——
• De Renzi,A. et al., Gazzetta Chimica Italiana, <hi>1978</hi>, vol. 108, p. 45 - 50
  作者：De Renzi,A. et al.

  DOI：——

  日期：——
• Sarhan, Jamil K. K.; Green, Michael; Al-Najjar, Ibrahim M., Journal of the Chemical Society, Dalton Transactions, 1984, p. 771 - 778
  作者：Sarhan, Jamil K. K.、Green, Michael、Al-Najjar, Ibrahim M.

  DOI：——

  日期：——
• cis-Influence determination of ethylene and benzyl cyanide ligands in the complexes cis-[Pt(Me2SO)(C2H4)Cl2] and cis-[Pt(Me2SO)-(PhCH2CN)Cl2] on the basis of X-ray structure data. IR and 1H, 13C and 195Pt NMR characterization of the cis-[Pt(Me2SO)LCl2] series
  作者：Vadim Yu. Kukushkin、Vitalii K. Belsky、Vadim E. Konovalov、Gayana A. Kirakosyan、Leonid V. Konovalov、Anatolii I. Moiseev、Valentina M. Tkacbuk

  DOI：10.1016/s0020-1693(00)85437-7

  日期：1991.7

  Complexes of the cis-[Pt(Me2SO)LCl2] series (L = Me2SO, Me2S, C2H4, MeCN, PhCH2CN, PhCN, C5H5N, 2Me-C5H4N and NH3) were prepared by known methods and characterized by IR and H-1, C-13H-1}, Pt-195H-1} NMR spectra. Structures of cis-[Pt(Me2SO)(C2H4)Cl2] and cis-[Pt(Me2SO)(PhCH2CN)Cl2] were determined by X-ray analysis. cis-[Pt(Me2SO((C2H4)Cl2] Crystallizes in the orthorhombic space group Pmnb. The unit cell parameters are a = 8.200(1), b = 12.924(3), c = 8.574(1) angstrom, V = 908.7(3) angstrom 3, rho-calc = 2.72 gcm-3, Z = 4. cis-[Pt(Me2SO)(PhCH2CN)Cl2] crystallizes in the monoclinic space group P2(1)/n. The unit cell parameters are: a = 12.223(4), b = 16.605(4), c = 6.779(2) angstrom, gamma = 91.10(2)-degrees, V = 1375.6(7) angstrom 3, rho-calc = 2.23 g cm-3 , Z = 4. On the basis of the X-ray structure data cis- and trans-influence of C2H4 and PhCH2CN ligands were determined.