2,4-diamino-6-(2-ethylhexylamino)-1,3,5-triazine | 189265-90-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2,4-diamino-6-(2-ethylhexylamino)-1,3,5-triazine
• 英文别名: N~2~-(2-Ethylhexyl)-1,3,5-triazine-2,4,6-triamine；2-N-(2-ethylhexyl)-1,3,5-triazine-2,4,6-triamine
• CAS: 189265-90-5
• 化学式: C₁₁H₂₂N₆
• 分子量: 238.336
• InChiKey: RFDSORRZYTWYRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  103
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-乙基己胺 以78%的产率得到2,4-diamino-6-(2-ethylhexylamino)-1,3,5-triazine
  参考文献：
  名称：

  Method for modifying 1,3,5-triazine derivatives

  摘要：

  一种用于修改1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢原子的存在下，通过加热并将至少具有一个氨基或单取代氨基团的1,3,5-三嗪衍生物与醇反应，将烷基基团或烯基基团引入每个氨基或单取代氨基团；另一种用于修改1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢原子的存在下，通过加热并将至少具有一个氨基或单取代氨基团的1,3,5-三嗪衍生物与二元醇反应，将具有羟基的烷基基团引入每个氨基或单取代氨基团；以及通过这些方法获得的1,3,5-三嗪衍生物。因此产生的各种改性取代的1,3,5-三嗪衍生物通常作为混合物获得。这些衍生物可以通过常规有机化合物分离方法分离为高纯度的化合物，并且这些化合物可用于规范中提到的各种应用。

  公开号：

  US06127538A1

文献信息

• METHODS FOR MODIFYING 1,3,5-TRIAZINE DERIVATIVES
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0882720A1

  公开（公告）日：1998-12-09

  A method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with an alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce an alkyl or alkenyl group into each amino or monosubstituted amino group; another method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with a dihydric alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce a hydroxylated alkyl group into each amino or monosubstituted amino group; and 1,3,5-triazine derivatives obtained by the methods. The various modified substituted 1,3,5-triazine derivatives thus produced are generally obtained as a mixture. These derivatives can be isolated as high-purity compounds by a general separation method for organic compounds, and the compounds are usable in the various applications mentioned in the specification. According to applications (for example, use as modifier additives, in particular a flame-retardant and a plasticizer for resins), the reaction mixture can be used as it is without being separated. Many of the substituted triazine derivatives obtained have been relatively difficult to synthesize or expensive. Since many of the derivatives are interesting with respect to their physical properties, e.g., solubility in water and in various organic solvents, high-temp. stability, melting point, boiling point, and basicity, they are thought to have a wider range of applications than conventional ones.

  一种改性 1，3，5-三嗪衍生物的方法，其特征在于在金属催化剂和氢的存在下，通过加热使任一环碳原子上具有至少一个氨基或单取代氨基的 1，3，5-三嗪衍生物与醇反应，从而在每个氨基或单取代氨基中引入一个烷基或烯基；另一种改性 1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢气存在下，使任一环碳原子上具有至少一个氨基或单取代氨基的 1,3,5-三嗪衍生物与二元醇反应，从而在每个氨基或单取代氨基中引入羟基烷基；以及通过上述方法获得的 1,3,5-三嗪衍生物。这样制得的各种改性取代的 1,3,5-三嗪衍生物通常以混合物的形式获得。这些衍生物可作为高纯度化合物通过有机化合物的一般分离方法分离出来，这些化合物可用于说明书中提到的各种应用中。根据用途（例如用作改性添加剂，特别是阻燃剂和树脂增塑剂），反应混合物可以不经分离直接使用。所获得的许多取代三嗪衍生物都比较难以合成或价格昂贵。由于许多衍生物在物理性质（如在水和各种有机溶剂中的溶解性、高温稳定性、熔点、沸点和碱性）方面都很有趣，因此它们被认为比传统的衍生物具有更广泛的用途。
• US6127538A
  申请人：——

  公开号：US6127538A

  公开（公告）日：2000-10-03
• Method for modifying 1,3,5-triazine derivatives
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US06127538A1

  公开（公告）日：2000-10-03

  A method for modifying 1,3,5-triazine derivatives characterized by heating and reacting a 1,3,5-triazine derivatives having at least one amino or mono-substituted amino group on a carbon atom or atoms on its ring with an alcohol in the presence of a metal catalyst and a hydrogen atom to introduce an alkyl group or an alkenyl group into each amino or mono-substituted amino group; another method for modifying 1,3,5-triazine derivatives characterized by heating and reacting a 1,3,5-triazine derivatives having at least one amino or mono-substituted amino group on a carbon atom or atoms on its ring with a dihydric alcohol in the presence of a metal catalyst and a hydrogen atom to introduce an alkyl group having a hydroxyl group into each amino or mono-substituted amino group; and 1,3,5-triazine derivatives obtained by the methods. The various modified sustituted 1,3,5-triazine derivatives thus produced are generally obtained as a mixture. These derivatives can be isolated as compounds having high-purity by a normal separation method for organic compounds, and the compounds are usable in the various applications mentioned in the specification.

  一种用于修改1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢原子的存在下，通过加热并将至少具有一个氨基或单取代氨基团的1,3,5-三嗪衍生物与醇反应，将烷基基团或烯基基团引入每个氨基或单取代氨基团；另一种用于修改1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢原子的存在下，通过加热并将至少具有一个氨基或单取代氨基团的1,3,5-三嗪衍生物与二元醇反应，将具有羟基的烷基基团引入每个氨基或单取代氨基团；以及通过这些方法获得的1,3,5-三嗪衍生物。因此产生的各种改性取代的1,3,5-三嗪衍生物通常作为混合物获得。这些衍生物可以通过常规有机化合物分离方法分离为高纯度的化合物，并且这些化合物可用于规范中提到的各种应用。