1,8-octamethylene-2,2'-bis(2-oxazoline) | 42469-21-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑啉类
• 英文名称: 1,8-octamethylene-2,2'-bis(2-oxazoline)
• 英文别名: Bis-<Δ2-oxazolinyl-(2)>-octan；2,2'-(Octane-1,8-diyl)bis(4,5-dihydro-1,3-oxazole)；2-[8-(4,5-dihydro-1,3-oxazol-2-yl)octyl]-4,5-dihydro-1,3-oxazole
• CAS: 42469-21-6
• 化学式: C₁₄H₂₄N₂O₂
• 分子量: 252.357
• InChiKey: MPPNPBNSYXFIBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  18
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  43.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N'-bis-(2-chloro-ethyl)-decanediamide 在 potassium hydroxide 作用下， 以 甲醇 为溶剂， 反应 6.0h， 生成 1,8-octamethylene-2,2'-bis(2-oxazoline)
  参考文献：
  名称：

  与脂肪族双（2-恶唑啉）s交联的聚（2-恶唑啉）水凝胶：性质，细胞毒性和细胞培养

  摘要：

  由2-乙基-2-恶唑啉和三个双（2-恶唑啉）交联剂（1,4-丁烯-2,2'-双（2-恶唑啉），1,6-己二甲基-2,2'组成的一系列水凝胶准备了双（2-恶唑啉）和1,8-八亚甲基-2-2,2'-双（2-恶唑啉）。水凝胶的不同之处在于脂肪族交联剂链的长度和交联剂的百分比（2-10％）。研究了交联剂的类型和百分比对溶胀性能，机械性能和水状态的影响。溶胀在水中的范围从2至20度，与交联剂的适当选择的平衡，杨氏模量可以从10kPa至几乎100千帕来改变。为了评估医疗应用的潜力，测量了提取物的细胞毒性和对鼠成纤维细胞的接触毒性。具有包含较短脂肪族的交联剂的水凝胶对成纤维细胞具有低毒性。此外，分析了在水凝胶中孵育12天的胰腺β细胞的活力和增殖。©2015 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学2016，54，1548年至1559年

  DOI：

  10.1002/pola.28009

文献信息

• PEARLESCENT PIGMENT
  申请人：Kitamura Takeaki

  公开号：US20100249304A1

  公开（公告）日：2010-09-30

  A pearlescent pigment ( 100 ) includes: a flaky substrate ( 10 ); a titanium dioxide layer ( 20 ) that is formed on the flaky substrate ( 10 ); and an oxazoline compound layer ( 40 ) that is formed on the titanium dioxide layer ( 20 ) with the titanium dioxide layer ( 20 ) being interposed between the flaky substrate ( 10 ) and the oxazoline compound layer ( 40 ), and serves as a top surface of the pearlescent pigment ( 100 ).

  一种珠光色颜料（100），包括：一片状基底（10）；在片状基底（10）上形成的二氧化钛层（20）；以及在二氧化钛层（20）上形成的噁唑啉化合物层（40），其中二氧化钛层（20）被夹在片状基底（10）和噁唑啉化合物层（40）之间，作为珠光色颜料（100）的顶部表面。
• BINDER COMPOSITION FOR NON-AQUEOUS SECONDARY BATTERY ELECTRODE
  申请人：Kinoshita Sachiko

  公开号：US20120095131A1

  公开（公告）日：2012-04-19

  Disclosed is a binder composition for a non-aqueous secondary battery electrode, which enables the production of a non-aqueous secondary battery that has excellent adhesion to a current collector or an electrode and can retain a high electric discharge capacity even when charge and discharge are repeated or under a high-temperature environment produced as a result of the generation of heat. Specifically disclosed is a binder composition for a non-aqueous secondary battery electrode, which comprises functional group-containing crosslinked resin microparticles produced by polymerizing the following components (A) to (C): (A) at least one monomer selected from the group consisting of (a) a monomer having one ethylenically unsaturated group per molecule and also having a monofunctional or polyfunctional epoxy group, (b) a monomer having one ethylenically unsaturated group per molecule and also having a monofunctional or polyfunctional amide group, and (c) a monomer having one ethylenically unsaturated group per molecule and also having a monofunctional or polyfunctional hydroxy group; (B) at least one monomer selected from the group consisting of (d) a monomer having one ethylenically unsaturated group per molecule and also having an alkoxysilyl group and (e) a monomer having at least two ethylenically unsaturated groups per molecule; and (C) (k) a monomer which has an ethylenically unsaturated group and is different from the monomers (a) to (e).

  本发明公开了一种用于非水性二次电池电极的粘合剂组合物，该组合物能够生产出具有优异附着力的非水性二次电池，该电池能够在充放电重复或因产生热而产生高温环境下保持高电放电容量。具体而言，本发明公开了一种用于非水性二次电池电极的粘合剂组合物，该组合物包括通过聚合以下组分（A）至（C）制备的含有功能性基团的交联树脂微粒：（A）选自以下组中的至少一种单体，所述组包括（a）每个分子具有一个乙烯基不饱和基团并且还具有单官能或多官能环氧基团的单体，（b）每个分子具有一个乙烯基不饱和基团并且还具有单官能或多官能酰胺基团的单体，以及（c）每个分子具有一个乙烯基不饱和基团并且还具有单官能或多官能羟基团的单体；（B）选自以下组中的至少一种单体，所述组包括（d）每个分子具有一个乙烯基不饱和基团并且还具有烷氧基基团的单体和（e）每个分子具有至少两个乙烯基不饱和基团的单体；以及（C）（k）一种具有乙烯基不饱和基团且与单体（a）至（e）不同的单体。
• CYCLIC CARBODIIMIDE COMPOUND, POLYESTER FILM, BACK SHEET FOR SOLAR CELL MODULE, AND SOLAR CELL MODULE
  申请人：FUJIFILM Corporation

  公开号：US20150068602A1

  公开（公告）日：2015-03-12

  A polyester film including a cyclic carbodiimide compound represented by the following Formula (O-1) has good film thickness uniformity without increase in viscosity. R 1 and R 5 represent an alkyl group, an aryl group, or an alkoxy group; R 2 to R 4 and R 6 to R 8 represent a hydrogen atom, an alkyl group, an aryl group, or an alkoxy group; X 1 and X 2 represent a single bond, —O—, —CO—, —S—, —SO 2 —, —NH—, or —CH 2 —; and L 1 represents a divalent linking group.

  以下是翻译结果： 聚酯薄膜包括一个由以下公式（O-1）表示的环状碳二亚胺化合物，具有良好的膜厚均匀性而不增加粘度。其中，R1和R5表示烷基、芳基或烷氧基；R2至R4和R6至R8表示氢原子、烷基、芳基或烷氧基；X1和X2表示单键、-O-、-CO-、-S-、-SO2-、-NH-或-CH2-；L1表示二价连接基团。
• PHOTOSENSITIVE COMPOSITION, CURED FILM AND PRODUCTION PROCESS THEREOF, AND ELECTRONIC PART
  申请人：JSR CORPORATION

  公开号：US20140234777A1

  公开（公告）日：2014-08-21

  It is an object of the present invention to improve the curability of a resin composition and a photosensitive composition suitably employed to form e.g., a surface protecting film and an interlaminar insulating film of e.g., an electronic part, while reducing the internal stress remaining in a substrate when the composition is used to form a cured film on the substrate. The photosensitive composition includes a resin (A) having a phenolic hydroxyl group, a crosslinking agent (B1) having at least two oxazoline groups and a crosslinking agent (B2) having at least two groups represented by —CH 2 OR (wherein R is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an acetyl group) and a photosensitive acid-generating agent (C).

  本发明的目的是提高树脂组合物和光敏组合物的可固化性，适用于形成电子部件的表面保护膜和层间绝缘膜等，同时在组合物用于在基板上形成固化膜时减少基板中剩余的内部应力。光敏组合物包括具有酚羟基的树脂(A)，至少具有两个噁唑烷基的交联剂(B1)，至少具有两个由—CH2OR（其中R是氢原子，具有1至10个碳原子的烷基或乙酰基）表示的基团的交联剂(B2)和光敏酸发生剂(C)。
• Cross-linked resins and production thereof
  申请人：TAKEDA CHEMICAL INDUSTRIES, Ltd.

  公开号：EP0266708A1

  公开（公告）日：1988-05-11

  A cross-linked resin as obtained by the reaction of a bis (2-oxazoline) compound with an aromatic compound having at least two amino groups shows low water-absorption, excellent in strength, and, in addition, tough and superior in heat-resistance. The resin composition comprising the cross-linked resin and reinforcements and/or fillers can be especially advantageously utilized for preparing a variety of molded articles practically usable in a broad application field, for example, space, aircraft, railway vehicles, automobiles, civil engineering, electrical and electronic appliances, cross-resistant equipment, sports and leisure equipment, medical equipment and industrial parts, as well as in the new application areas where conventional fiber-reinforced resins have hardly been utilized by the reason of insufficient strength, water-absorption, heat-resistance, etc.

  通过双（2-噁唑啉）化合物与至少有两个氨基的芳香族化合物反应得到的交联树脂具有吸水性低、强度高、韧性好、耐热性优等特点。 由交联树脂和增强剂及/或填料组成的树脂组合物特别适用于制备各种模塑制品，这些制品的应用领域非常广泛，例如航天、飞机、铁路车辆、汽车、土木工程、电气和电子设备、防腐设备、运动和休闲设备、医疗设备和工业部件，以及传统的纤维增强树脂因强度、吸水性、耐热性等不足而难以使用的新应用领域。