4,4',4"-trihydroxy-3,3',3",5,5',5"-hexamethyltriphenylmethane | 6204-16-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 4,4',4"-trihydroxy-3,3',3",5,5',5"-hexamethyltriphenylmethane
• 英文别名: 3,5-3',5'-3'',5''-Hexamethyl-4,4',4''-trioxy-triphenylmethan；4,4',4''-Trioxy-3,3',3'',5,5',5''-hexamethyl-triphenylmethan；tris-(4-hydroxy-3,5-dimethyl-phenyl)-methane；Tris-(4-hydroxy-3,5-dimethyl-phenyl)-methan；4,4',4"-methylidyne tris(2,6-dimethylphenol)；1,1,1-tris(3,5-dimethyl-4-hydroxyphenyl)-methane；4,4',4''-Methanetriyltris(2,6-dimethylphenol)；4-[bis(4-hydroxy-3,5-dimethylphenyl)methyl]-2,6-dimethylphenol
• CAS: 6204-16-6
• 化学式: C₂₅H₂₈O₃
• 分子量: 376.496
• InChiKey: FGWOVMNAWIHZRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4,4',4"-trihydroxy-3,3',3",5,5',5"-hexamethyltriphenylmethane 、 苯甲酰氯 生成 tris-(4-benzoyloxy-3,5-dimethyl-phenyl)-methane
  参考文献：
  名称：

  611.二甲苯酚与四卤化碳的缩合

  摘要：

  DOI：

  10.1039/jr9580003009
• 作为产物：
  描述：

  2,6-二甲基苯酚 在 三氯化铝 、 氯仿 作用下， 生成 4,4',4"-trihydroxy-3,3',3",5,5',5"-hexamethyltriphenylmethane
  参考文献：
  名称：

  611.二甲苯酚与四卤化碳的缩合

  摘要：

  DOI：

  10.1039/jr9580003009

文献信息

• PHENOLIC HYDROXYL GROUP-CONTANING COMPOUND, PHENOLIC HYDROXYL GROUP-CONTANING COMPOSITION, (METH)ACRYLOYL GROUP-CONTAINING RESIN, CURABLE COMPOSITION, CURED PRODUCT THEREOF, AND RESIST MATERIAL
  申请人：DIC CORPORATION

  公开号：US20150274636A1

  公开（公告）日：2015-10-01

  The present invention provides a (meth)acryloyl group-containing resin having excellent heat resistance and a phenolic hydroxyl group-containing compound used as a raw material of the resin. A phenolic hydroxyl group-containing compound has a molecular structure represented by general formula (1) below [in the formula, R 1 , R 2 , and R 3 are each independently an alkyl group having 1 to 8 carbon atoms, m and n are each independently an integer of 1 to 4, p is an integer of 0 to 4, V is a hydrogen atom, a (meth)acryloyloxy group, or a hydroxyl group, and W, X, and Y are each independently a (meth)acryloyloxy group or a hydroxyl group], wherein at least one of V, W, X, and Y is a hydroxyl group, and at least one of V, W, X, and Y is a (meth)acryloyloxy group.

  本发明提供了一种具有优异耐热性的含有(meth)丙烯酰基的树脂，以及一种作为该树脂原料的含酚羟基化合物。含酚羟基的化合物具有以下通式(1)所表示的分子结构[在该式中，R1、R2和R3分别独立地为具有1至8个碳原子的烷基基团，m和n分别独立地为1至4的整数，p为0至4的整数，V为氢原子、(meth)丙烯酰氧基或羟基，W、X和Y分别独立地为(meth)丙烯酰氧基或羟基]，其中V、W、X和Y中至少有一个为羟基，至少有一个为(meth)丙烯酰氧基。
• POLYCARBONATE RESIN COMPOSITION AND FORMED PRODUCT THEREOF
  申请人：Monden Toshiki

  公开号：US20110245388A1

  公开（公告）日：2011-10-06

  In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

  在含有聚碳酸酯树脂和聚碳硅烷化合物的聚碳酸酯树脂组合物中，使用聚碳硅烷化合物可以改变聚碳酸酯树脂组合物的表面特性，而不会对聚碳酸酯树脂的固有特性产生不利影响，如透明度、耐热性和机械性能（例如冲击强度）。含有100质量部聚碳酸酯树脂、0.001至1质量部金属盐化合物和0.005至5质量部聚碳硅烷化合物的聚碳酸酯树脂组合物具有显著提高的阻燃性和高透明度，显著减少气体排放和模具污染，同时不会损失冲击强度和耐热性。
• Process for preparing aryl allyl ethers
  申请人：Boriack J. Clinton

  公开号：US20050033094A1

  公开（公告）日：2005-02-10

  A process for preparing an allyl ether including reacting (a) a phenolic compound with (b) an allyl carboxylate or an allyl carbonate in the presence of (c) a transition metal or rare earth metal catalyst complexed with at least one strongly bonded, non-replaceable stable ligand whereby an allyl ether is formed. The ligand of the transition metal or rare earth metal catalyst complex may be (i) an olefinic-containing ligand or aromatic-containing ligand; or (ii) a polymeric ligand or a heteroatom-containing multidentate ligand.

  一种制备烯丙醚的方法，包括在(c)过渡金属或稀土金属催化剂的存在下，通过反应(a)酚类化合物和(b)烯丙酸酯或烯丙酸酯碳酸酯，形成烯丙醚。过渡金属或稀土金属催化剂的配体可以是(i)含有烯烃或芳香基的配体；或者(ii)聚合配体或含有杂原子的多齿配体。其中配体是强键合、不可替换、稳定的。
• [EN] HIGH HEAT MONOMERS AND METHODS OF USE THEREOF<br/>[FR] MONOMÈRES À CHALEUR ÉLEVÉE ET LEURS PROCÉDÉS D'UTILISATION
  申请人：SABIC GLOBAL TECHNOLOGIES BV

  公开号：WO2016014536A1

  公开（公告）日：2016-01-28

  High purity epoxide compounds, methods for preparing the high purity epoxide compounds, and compositions derived from the epoxide compounds are provided. Also provided are materials and articles derived from the epoxide compounds.

  本发明提供了高纯度环氧化合物、制备高纯度环氧化合物的方法以及从环氧化合物衍生的组合物。还提供了从环氧化合物衍生的材料和物品。
• Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom
  申请人：——

  公开号：US20030105268A1

  公开（公告）日：2003-06-05

  A process for manufacturing an &agr;-dihydroxy derivative from an aryl allyl ether wherein such &agr;-dihydroxy derivative can be used to prepare an &agr;-halohydrin intermediate and an epoxy resin prepared therefrom including epoxidizing an &agr;-halohydrin intermediate produced from a halide substitution of an &agr;-dihydroxy derivative which has been obtained by a dihydroxylation reaction of an aryl allyl ether in the presence of an oxidant or in the presence of an oxidant and a catalyst.

  从芳基丙烯醚中制备α-二羟基衍生物的工艺，其中这种α-二羟基衍生物可用于制备α-卤代醇中间体和由此制备的环氧树脂，包括将从α-二羟基衍生物的卤化物取代反应中产生的α-卤代醇中间体环氧化，该α-二羟基衍生物是在氧化剂或氧化剂和催化剂存在下从芳基丙烯醚的双羟基化反应中获得的。