N-(三苯甲基)甲基丙烯酰胺 | 275371-79-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 中文名称: N-(三苯甲基)甲基丙烯酰胺
• 英文名称: N-triphenylmethylmethacrylamide
• 英文别名: N-(Triphenylmethyl)methacrylamide；2-methyl-N-tritylprop-2-enamide
• CAS: 275371-79-4
• 化学式: C₂₃H₂₁NO
• 分子量: 327.426
• InChiKey: UTYRFBWBJRYRSO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三苯甲胺 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 21.0h， 以68%的产率得到N-(三苯甲基)甲基丙烯酰胺
  参考文献：
  名称：

  N-三苯基甲基甲基丙烯酰胺的立体有择自由基聚合导致高度等规螺旋聚合物

  摘要：

  N-三苯基甲基甲基丙烯酰胺 (TrMAM) 和 N-[二(4-丁基苯基) 苯基甲基] 甲基丙烯酰胺 (DBuTrMAM) 使用自由基引发剂聚合。由TrMAM得到的聚合物PTrMAM不溶于普通溶剂，但溶于硫酸中定量得到聚甲基丙烯酰胺。PTrMAM 在硫酸-d2 中的 1H NMR 谱表明衍生的聚甲基丙烯酰胺几乎是 100% 等规的。另一方面，DBuTrMAM 产生聚合物 PDBuTrMAM，可溶于 THF 和氯仿，其在硫酸-d2 中的 NMR 谱与 PTrMAM 相似。TrMAM 和 DBuTrMAM 在旋光溶剂 (-)- 或 (+)- 薄荷醇中的聚合得到具有主要单手螺旋结构的旋光聚合物。单体没有溶解在甲醇-氯仿混合物中。

  DOI：

  10.1021/ja035871y

文献信息

• [EN] FORCE-RESPONSIVE POLYMERSOMES AND NANOREACTORS; PROCESSES UTILIZING THE SAME<br/>[FR] POLYMERSOMES ET NANORÉACTEURS SENSIBLES À LA FORCE; PROCÉDÉS LES UTILISANT
  申请人：ADOLPHE MERKLE INSTITUTE UNIV OF FRIBOURG

  公开号：WO2019034597A1

  公开（公告）日：2019-02-21

  The mechanically induced melting properties of DNA were employed to achieve force labile membranes is described. Nucleobase pairs were used as mechanophores. Adenine and thymine functionalized complementary amphiphilic block copolymers were self-assembled into polymersomes. The nucleobases formed hydrogen bonds which were disrupted upon force stimulation. The exposure of the disconnected nucleobases to the hydrophobic matrix of the membranes lead to a change of permeability which permitted the exchange of water-soluble molecules throughout the polymer matrix. Moreover, the encapsulation of horseradish peroxidase enabled the reaction of luminol with hydrogen peroxide to yield a luminescence producing species similar to the marine bioluminescence. Moreover, the same nano-reactors were employed to catalyze the formation of a polyacrylamide gel when force was applied. Insights into the change of permeability of supramolecular networks upon force are provided. These systems are useful for drug delivery, as nanoreactors and for the selective release of curing agents for 3D printing, or fragrances.

  DNA的机械诱导熔化特性被用来实现易受力破裂的膜。核碱基对被用作机械感受器。腺嘌呤和胸腺嘧啶功能化的互补两性分块共聚物自组装成聚合体囊。核碱基形成氢键，在受力刺激下被破坏。断开的核碱基暴露在膜的疏水基质中，导致渗透性的改变，从而允许水溶性分子在聚合物基质中交换。此外，封装辣根过氧化物酶使得辣根酰胺与过氧化氢反应产生类似海洋生物发光的发光物种。此外，当施加力时，相同的纳米反应器被用来催化聚丙烯酰胺凝胶的形成。提供了关于受力下超分子网络渗透性变化的见解。这些系统可用于药物传递、纳米反应器以及用于3D打印的固化剂或香料的选择性释放。
• LOW VISCOSITY, LOW VOLATILITY LUBRICATING OIL BASESTOCKS
  申请人：Patil Abhimanyu O.

  公开号：US20150275127A1

  公开（公告）日：2015-10-01

  This disclosure provides low viscosity, low volatility alkylated siloxane compounds and alkylated alkoxy silane compounds. This disclosure also provides processes for producing the alkylated siloxane compounds and alkylated alkoxy silane compounds, and lubricating oil basestocks and lubricating oils containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds. This disclosure further provides a method for improving one or more of solubility and dispersancy of polar additives and/or sludge in a lubricating oil by using as the lubricating oil a formulated oil containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds.

  本公开提供低粘度、低挥发性的烷基化硅氧烷化合物和烷基化烷氧硅烷化合物。本公开还提供生产烷基化硅氧烷化合物和烷基化烷氧硅烷化合物的方法，以及含有一种或多种烷基化硅氧烷化合物或一种或多种烷基化烷氧硅烷化合物的润滑油基础油和润滑油。本公开进一步提供一种通过使用含有一种或多种烷基化硅氧烷化合物或一种或多种烷基化烷氧硅烷化合物的配方油作为润滑油，来改善极性添加剂和/或沉淀物在润滑油中的溶解性和分散性的方法。
• SALT TOLERANT ANION EXCHANGE MEDIUM
  申请人：Pall Corporation

  公开号：EP3617257A1

  公开（公告）日：2020-03-04

  Disclosed is an anion exchange porous medium, e.g., a porous membrane, that includes a porous support and a crosslinked cationic polymer coating disposed thereon, wherein the cationic polymer of the crosslinked cationic polymer coating comprises polymerized monomer (A) and polymerized monomer (B) wherein A and B are as defined herein. Also disclosed are methods of preparing the anion exchange porous medium and of treating a fluid containing a biologic.

  公开了一种阴离子交换多孔介质，例如多孔膜，它包括多孔支架和设置在其上的交联阳离子聚合物涂层，其中交联阳离子聚合物涂层的阳离子聚合物包括聚合单体（A）和聚合单体（B），其中 A 和 B 如本文所定义。还公开了制备阴离子交换多孔介质和处理含有生物制剂的流体的方法。
• Use of tristyrylphenol alkoxylate sulfosuccinates in emulsion polymerization and coatings
  申请人：Stepan Company

  公开号：US10040964B2

  公开（公告）日：2018-08-07

  Disclosed are the use of novel surfactants for the synthesis of emulsion polymer latexes, particularly those used in paints, coatings, and pressure sensitive adhesives. The surfactant compositions for emulsion polymer latexes comprise sterically bulky surfactants whose composition comprises at least one alkoxylated polyaryl substituted aromatic sulfosuccinate compound. The novel surfactants provide for the production of stable, small particle size distribution emulsion polymer latexes. The resulting latexes, when formulated into latex paint, impart improvements in water resistance as measured by film opacity, blister resistance and improved leveling characteristics, and when formulated into pressure sensitive adhesives, provide improved water resistance characteristics as measured by film opacity.

  公开了新型表面活性剂在乳液聚合胶乳合成中的用途，特别是在油漆、涂料和压敏胶中的用途。用于乳液聚合胶乳的表面活性剂组合物包括立体笨重的表面活性剂，其组合物包含至少一种烷氧基化多芳基取代芳香族磺基琥珀酸酯化合物。这种新型表面活性剂可用于生产稳定的小粒径分布乳液聚合胶乳。由此产生的胶乳在配制成乳胶漆时，可改善耐水性（以漆膜不透明度、抗起泡性和流平特性来衡量）；在配制成压敏粘合剂时，可改善耐水性（以漆膜不透明度来衡量）。
• Illumination source comprising nanoplatelets and display apparatus having the same
  申请人：NEXDOT

  公开号：US10642139B2

  公开（公告）日：2020-05-05

  Disclosed is a color conversion layer including at least one light emitting material including at least one composite particle surrounded partially or totally by at least one surrounding medium; wherein the light emitting material is configured to emit light in response to an excitation and the at least one composite particle includes a plurality of nanoparticles encapsulated in an inorganic material; and wherein the inorganic material has a difference of refractive index compared to the at least one surrounding medium superior or equal to 0.02 at 450 nm. Also disclosed is an illumination source and a display apparatus.

  公开了一种颜色转换层，包括至少一种发光材料，该发光材料包括至少一种被至少一种周围介质部分或全部包围的复合颗粒；其中，发光材料被配置为响应激发而发光，且至少一种复合颗粒包括封装在无机材料中的多个纳米颗粒；以及其中，无机材料与至少一种周围介质相比，在 450 纳米波长处的折射率差大于或等于 0.02。还公开了一种照明光源和一种显示装置。