(η(5)-C5Me5)BeCl | 626200-21-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (η(5)-C5Me5)BeCl
• 英文别名: Beryllium chloride 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide (1/1/1)；beryllium;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;chloride
• CAS: 626200-21-3
• 化学式: Be*C₁₀H₁₅*Cl
• 分子量: 179.694
• InChiKey: LVAVTWHLFKLMMC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.43
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (η(5)-C5Me5)BeCl 、 Di-tert-butyl-arsin 在 BuLi 作用下， 以 乙醚 为溶剂， 以70%的产率得到(η(5)-C5Me5)BeAs(t-Bu)2
  参考文献：
  名称：

  The first beryllium diorganoarsenide: synthesis and structure of (η5-C5Me5)BeAs(t-Bu)2

  摘要：

  The compound (eta(2)-C5Me5)BeAs(t-Bu)(2) (1) was prepared by the reaction of (eta(2)-C5Me5)BeCl with LiAs(t-Bu)(2) in diethyl ether at 0 degrees C. The structure of 1 has been determined by X-ray crystallography and is the first structurally characterized diorganoarsenide derivative of beryllium. It is monomeric in the solid state with the As-t-Bu-2 ligand acting as a one electron donor. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01187-5

文献信息

• The first beryllium diorganoarsenide: synthesis and structure of (η5-C5Me5)BeAs(t-Bu)2
  作者：Scott L. Battle、Alan H. Cowley、Andreas Decken、Richard A. Jones、Stefan U. Koschmieder

  DOI：10.1016/s0022-328x(98)01187-5

  日期：1999.6

  The compound (eta(2)-C5Me5)BeAs(t-Bu)(2) (1) was prepared by the reaction of (eta(2)-C5Me5)BeCl with LiAs(t-Bu)(2) in diethyl ether at 0 degrees C. The structure of 1 has been determined by X-ray crystallography and is the first structurally characterized diorganoarsenide derivative of beryllium. It is monomeric in the solid state with the As-t-Bu-2 ligand acting as a one electron donor. (C) 1999 Elsevier Science S.A. All rights reserved.