spiro[cyclopentane-1,17'-[3,14]-diazatricyclo[12.3.1.1^3,16]nonadecane]-2',15',18',19'-tetraone | 960506-80-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 英文名称: spiro[cyclopentane-1,17'-[3,14]-diazatricyclo[12.3.1.1^3,16]nonadecane]-2',15',18',19'-tetraone
• CAS: 960506-80-3
• 化学式: C₂₁H₃₀N₂O₄
• 分子量: 374.48
• InChiKey: OADLLXODBRRZNC-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  spiro[cyclopentane-1,17'-[3,14]-diazatricyclo[12.3.1.1^3,16]nonadecane]-2',15',18',19'-tetraone 在 红铝 作用下， 以 甲苯 为溶剂， 反应 15.0h， 以74%的产率得到spiro[cyclopentane-1,17'-[3,14]-diazatricyclo[12.3.1.1^3,16]nonadecane]
  参考文献：
  名称：

  Synthesis of New Tricyclic Spirobispidines via Ring Closing Metathesis Reaction

  摘要：

  New tricyclic spiro compounds based on 3,7-diazabicyclo[3.3.1]-nonane (bispidine) were synthesized by ruthenium-catalyzed ring closing metathesis reactions. The constitution of the newly formed double bond depending on the chain length and various conditions of the RCM reaction was analyzed.

  DOI：

  10.3987/com-07-11063
• 作为产物：
  描述：

  spiro[cyclopentane-1,17'-[3,14]-diazatricyclo[12.3.1.1^3,16]-8-nonadecene]-2',15',18',19'-tetraone 在 10percent Pd/C 氢气 作用下， 以 1,4-二氧六环 、 乙醇 为溶剂， 反应 5.0h， 以94%的产率得到spiro[cyclopentane-1,17'-[3,14]-diazatricyclo[12.3.1.1^3,16]nonadecane]-2',15',18',19'-tetraone
  参考文献：
  名称：

  Synthesis of New Tricyclic Spirobispidines via Ring Closing Metathesis Reaction

  摘要：

  New tricyclic spiro compounds based on 3,7-diazabicyclo[3.3.1]-nonane (bispidine) were synthesized by ruthenium-catalyzed ring closing metathesis reactions. The constitution of the newly formed double bond depending on the chain length and various conditions of the RCM reaction was analyzed.

  DOI：

  10.3987/com-07-11063