Di-(1-methyl-3-chlorpropyl)phosphit | 42008-77-5

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: Di-(1-methyl-3-chlorpropyl)phosphit
• 英文别名: phosphonic acid bis-(3-chloro-1-methyl-propyl) ester；phosphorous acid bis-(3-chloro-1-methyl-propyl) ester
• CAS: 42008-77-5
• 化学式: C₈H₁₇Cl₂O₃P
• 分子量: 263.101
• InChiKey: HIQWNQYWZARVFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.44
• 重原子数：
  14.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.53
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  phosphorochloridous acid bis-(3-chloro-1-methyl-propyl) ester 在 水 作用下， 以 氯仿 为溶剂， 生成 Di-(1-methyl-3-chlorpropyl)phosphit
  参考文献：
  名称：

  Reaction of phosphorous acid chlorides with oxetanes

  摘要：

  DOI：

  10.1007/bf00854034

文献信息

• RESIN AND ARTICLE MOLDED THEREFROM
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1640405A1

  公开（公告）日：2006-03-29

  The resin of the invention comprises both a phosphorus-containing residue having a bicycloalkyl structure and a specific divalent phenol residue. The invention provides a resin having excellent optical properties, which is colorless and transparent, has a high refractive index and is optically low dispersive, as well as its molded product.

  本发明的树脂由具有双环烷基结构的含磷残基和特定的二价酚残基组成。本发明提供了一种具有优异光学性能的树脂及其模塑产品，该树脂无色透明，折射率高，光学色散性低。
• Resin composition and articles molded therefrom
  申请人：——

  公开号：US20030013836A1

  公开（公告）日：2003-01-16

  According to the present invention, a resin composition having a high refractive index and low dispersion characteristics is provided. THE resin composition comprises a carbonate residue, a phosphonic acid residue represented by the following structural formula (1), and a dihydric phenol residue represented by the following structural formula (2), wherein the mol fractions of the phosphonic acid residue and the carbonate residue satisfy equation (3). 1 [In structural formula (1), R1 represents an organic group, X1 represents oxygen, sulfur or selenium, and the resin composition may contain two or more different phosphonic acid residues having different R1 or X1. In structural formula (2), R2 is independently selected from the group consisting of a hydrogen atom, a halogen atom, a hydrocarbyl group and a nitro group, and p and q are integers such that p+q=0 to 8, and the hydrocarbyl group is selected from the group consisting of an aliphatic group having 1-20 carbon atoms, and an aromatic group. Y1 is selected from the group consisting of a single bond, an oxygen atom, a sulfur atom, an alkylene group, an alkylidene group, a cycloalkylene group, a cycloalkylidene group, a halo-substituted alkylene group, a halo-substituted alkylidene group, a phenylalkylidene group, a carbonyl group, a sulfone group, an aliphatic phosphine oxide group, an aromatic phosphine oxide group, an alkylsilane group, a dialkylsilane group, and a fluorene group. The resin composition may contain two or more different dihydric phenol residues having different R2 or Y1.] 1>( a )/{( a )+( b )}≧0.5  (3) [In equation (3), (a) represents the number of moles of the phosphonic acid residues, and (b) represents the number of moles of the carbonate residues.]

  根据本发明，提供了一种具有高折射率和低分散特性的树脂组合物。该树脂组合物包括碳酸酯残留物、由以下结构式（1）表示的膦酸残留物和由以下结构式（2）表示的二水酚残留物，其中膦酸残留物和碳酸酯残留物的摩尔分数满足式（3）。 1 [在结构式（1）中，R1 代表有机基团，X1 代表氧、硫或硒，树脂组合物可包含两个或多个具有不同 R1 或 X1 的不同膦酸残基。在结构式（2）中，R2 独立地选自氢原子、卤素原子、烃基和硝基组成的组，p 和 q 是整数，使得 p+q=0 至 8，烃基选自具有 1-20 个碳原子的脂肪族基团和芳香族基团组成的组。Y1 选自单键、氧原子、硫原子、亚烷基、亚烷基、环亚烷基、环亚烷基、卤代亚烷基、卤代亚烷基、苯基亚烷基、羰基、砜基、脂肪族氧化膦基、芳香族氧化膦基、烷基硅烷基、二烷基硅烷基和芴基组成的组。树脂组合物可以包含两种或两种以上具有不同 R2 或 Y1.&rsqb； 1>( a )/{( a )+( b ) }≧0.5 (3) 在公式 (3) 中，(a) 表示膦酸残留物的摩尔数，(b) 表示碳酸盐残留物的摩尔数；
• RESIN COMPOSITION AND ARTICLES MOLDED THEREFROM
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1270646B1

  公开（公告）日：2008-11-26
• Resin and article molded therefrom
  申请人：Takanishi Keijiro

  公开号：US20060287464A1

  公开（公告）日：2006-12-21

  The resin of the invention comprises both a phosphorus-containing residue having a bicycloalkyl structure and a specific divalent phenol residue. The invention provides a resin having excellent optical properties, which is colorless and transparent, has a high refractive index and is optically low dispersive, as well as its molded product.
• US6750313B2
  申请人：——

  公开号：US6750313B2

  公开（公告）日：2004-06-15