α-Trithiobenzaldehyd | 51703-73-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三噻烷
• 英文名称: α-Trithiobenzaldehyd
• 英文别名: α-Trithiobenzaldehyd =cis 2.trans 4.trans 6-Triphenyl-1.3.5-trithian；α-Trithiobenzaldehyd = 2r,4l,6c-Triphenyl-1.3.5-trithian；α-2,4,6-triphenyl-1,3,5-trithiane
• CAS: 51703-73-2
• 化学式: C₂₁H₁₈S₃
• 分子量: 366.572
• InChiKey: HJHSNTOTXYILIV-DEVVLJCNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  α-Trithiobenzaldehyd 以 乙腈 为溶剂， 生成 [Benzylsulfanyl(phenyl)methyl] benzenecarbodithioate
  参考文献：
  名称：

  Photoinduced ultrafast ring-opening reaction in trithianes in solution

  摘要：

  The ring-opening reaction of trithianes possessing aromatic substituents has been studied using femto-second broadband UV-Vis transient absorption spectroscopy. Photocleavage of the CAS bond occurs during the short-lived (1.5 ps) singlet excited state of trithiane. The products are formed with excess of vibrational energy and cooling of the hot molecules occurs with a 12.1 ps time constant in acetonitrile. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2008.09.055

文献信息

• Photoinduced ultrafast ring-opening reaction in trithianes in solution
  作者：Gotard Burdzinski、Bronislaw Marciniak

  DOI：10.1016/j.cplett.2008.09.055

  日期：2008.11

  The ring-opening reaction of trithianes possessing aromatic substituents has been studied using femto-second broadband UV-Vis transient absorption spectroscopy. Photocleavage of the CAS bond occurs during the short-lived (1.5 ps) singlet excited state of trithiane. The products are formed with excess of vibrational energy and cooling of the hot molecules occurs with a 12.1 ps time constant in acetonitrile. (c) 2008 Elsevier B.V. All rights reserved.