1N-(2-pyridyl-2-methyl)-2-phenylazo aniline | 913059-36-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 1N-(2-pyridyl-2-methyl)-2-phenylazo aniline
• 英文别名: 2-phenyldiazenyl-N-(pyridin-2-ylmethyl)aniline
• CAS: 913059-36-6
• 化学式: C₁₈H₁₆N₄
• 分子量: 288.352
• InChiKey: BYUSWUNWGXAWGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  49.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  sodium tetrachloropalladate(II) 、 1N-(2-pyridyl-2-methyl)-2-phenylazo aniline 以 甲醇 为溶剂， 以55%的产率得到(1N-(2-pyridyl-2-methyl)-2-phenylazo anilinate) palladium(II) chloride]
  参考文献：
  名称：

  Syntheses, characterisation and structure of new diazoketiminato chelates of palladium(II) incorporating a tridentate (N,N,N) azo ligand

  摘要：

  The 1N-(2-pyridyl-2-methyl)-2-arylazo aniline, HL [where HL = ArN=NC6H4N(H)(CH2C5H4N); Ar=C6H5 (for HL1) or p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)], ligands were prepared by treating the appropriate 2-(arylazo) aniline with 2-chloromethyl pyridine. Reactions of Na2PdCl4 with HL afforded (L)PdCl complexes. HL binds palladium(II) in a tridentate fashion (N,N,N) forming a new diazoketiminato chelate, dissociating the amino proton. The X-ray structure of (L-1)PdCl was determined. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.03.019

文献信息

• Synthesis, structure and properties of delocalized transition metal chelates: Diazoketiminato chelates of Co(III) and Pt(II)
  作者：Debprasad Patra、Poulami Pattanayak、Jahar Lal Pratihar、Surajit Chattopadhyay

  DOI：10.1016/j.poly.2007.08.029

  日期：2007.11

  The reactions of HL 1 [where HL is 1N-(2-pyridyl-2-methyl)-2-arylazoaniline and is formulated as ArN = NC6H4N(H)(CH2C5H4N); Ar = C6H5 (for HL1) or p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)] with K2PtCl4 and Co(ClO4)3 · 6H2O afforded the (L)PtCl and [(L)2Co]ClO4 complexes, respectively. The HL ligands bind the platinum(II) and cobalt(III) centres in a tridentate (N,N,N) fashion, forming new diazoketiminato

  HL 1的反应[其中HL是1 N-（2-吡啶基-2-甲基）-2-芳基偶氮苯胺，其公式为：ArN = NC 6 H 4 N（H）（CH 2 C 5 H 4 N）；Ar = C 6 H 5（对于HL 1）或p -MeC 6 H 4（对于HL 2）或p -ClC 6 H 4（对于HL 3）]，带有K 2 PtCl 4和Co（ClO 4）3  ·6H 2个O分别提供（L）PtCl和[（L）2 Co] ClO 4配合物。HL配体以三齿（N，N，N）方式结合铂（II）和钴（III）中心，在解离氨基质子时形成新的重氮基螯合螯合物。测定了（L 3）PtCl和[（L 3）2 Co] ClO 4的X射线结构。已经检查了新配合物的氧化还原性质。