| 12133-32-3

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相碱土金属化合物
• CAS: 12133-32-3
• 化学式: CaMg
• 分子量: 64.383
• InChiKey: ZFXVRMSLJDYJCH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.76
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  calcium 、 magnesium 以 neat (no solvent, gas phase) 为溶剂， 生成 magnesium dimer 、 、 calcium dimer
  参考文献：
  名称：

  Laser induced fluorescence of the MgCa molecule

  摘要：

  Using the radiation of several ion laser lines and of a tunable dye laser, the first gas phase spectra of the MgCa molecule have been obtained. The laser induced fluorescence spectra have been assigned to the A 1Σ+–X 1Σ+, B 1Π–X 1Σ+, and the C 1Σ+–X 1Σ+ systems. The quantum numbers of the levels belonging to the X 1Σ+ ground state were determined using a quantum mechanical, variational method. The vibrational quantum numbers of the excited levels and the assignment to the different electronic states were obtained from a comparison of the measured and calculated Franck–Condon factors which are in very good agreement.

  DOI：

  10.1063/1.448929

文献信息

• Laser induced fluorescence of the MgCa molecule
  作者：H. Atmanspacher、H. Scheingraber、C. R. Vidal

  DOI：10.1063/1.448929

  日期：1985.4.15

  Using the radiation of several ion laser lines and of a tunable dye laser, the first gas phase spectra of the MgCa molecule have been obtained. The laser induced fluorescence spectra have been assigned to the A 1Σ+–X 1Σ+, B 1Π–X 1Σ+, and the C 1Σ+–X 1Σ+ systems. The quantum numbers of the levels belonging to the X 1Σ+ ground state were determined using a quantum mechanical, variational method. The vibrational quantum numbers of the excited levels and the assignment to the different electronic states were obtained from a comparison of the measured and calculated Franck–Condon factors which are in very good agreement.