6-phenyl-1,2,4-trioxan-3-one | 1571903-40-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三氧烷
• 英文名称: 6-phenyl-1,2,4-trioxan-3-one
• 英文别名: 6-Phenyl-1,2,4-trioxan-3-one
• CAS: 1571903-40-6
• 化学式: C₉H₈O₄
• 分子量: 180.16
• InChiKey: ATJLSSMGAYBCGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三光气 、 2-hydroperoxy-2-phenylethanol 在 iron(III) chloride 、 magnesium sulfate 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以88%的产率得到6-phenyl-1,2,4-trioxan-3-one
  参考文献：
  名称：

  磁性纳米颗粒（CoFe 2 O 4）负载的磷钼酸盐是一种高效，绿色，可回收的合成β-羟基氢过氧化物的催化剂

  摘要：

  AbstractMagnetic nanoparticles (CoFe2O4)‐supported phosphomolybdate ([CoFe2O4@SiO2‐PrNH2‐PMo]) was readily prepared and identified as an efficient catalyst for ring‐opening of various epoxides with ethereal hydrogen peroxide (H2O2). The reaction proceeded under mild conditions to give β‐hydroxy hydroperoxides (HHPs) in high yields at room temperature, and the catalyst could be magnetically separated and recycled.magnified image

  DOI：

  10.1002/adsc.201300551

文献信息

• [EN] PROCESS FOR PRODUCING A WOLLASTONITE CONTAINING POLYESTER AND PRODUCTS AND ARTICLES PRODUCED THEREFROM<br/>[FR] PROCEDE DE PRODUCTION D'UN POLYESTER CONTENANT DE LA WOLLASTONITE ET PRODUITS ET ARTICLES OBTENUS A PARTIR DE CE DERNIER
  申请人：DU PONT

  公开号：WO2006028647A1

  公开（公告）日：2006-03-16

  The present invention provides a process for producing a polyester from a polyester composition comprising at least about 1 wt.% wollastonite, based on the total weight of the polyester composition, wherein the wollastonite is added at a temperature of about 240°C or less. The present invention further provides a process for producing a polyester from a polyester composition comprising at least about 1 wt.% wollastonite, based on the total weight of the polyester composition, and about 0.01 wt.% other filler, based on total weight of the polyester composition, wherein the wollastonite is added at a temperature of about 240°C or less. The invention is further directed to polyester products produced by said process and the shaped articles formed therefrom.
• Magnetic Nanoparticles (CoFe₂O₄)-Supported Phosphomolybdate as an Efficient, Green, Recyclable Catalyst for Synthesis of β-Hydroxy Hydroperoxides
  作者：Pei-He Li、Bao-Le Li、Zhi-Min An、Li-Ping Mo、Zhen-Shui Cui、Zhan-Hui Zhang

  DOI：10.1002/adsc.201300551

  日期：2013.10.11

  AbstractMagnetic nanoparticles (CoFe2O4)‐supported phosphomolybdate ([CoFe2O4@SiO2‐PrNH2‐PMo]) was readily prepared and identified as an efficient catalyst for ring‐opening of various epoxides with ethereal hydrogen peroxide (H2O2). The reaction proceeded under mild conditions to give β‐hydroxy hydroperoxides (HHPs) in high yields at room temperature, and the catalyst could be magnetically separated and recycled.magnified image