1,3,5-三氧杂环己烷与1,3-二氧戊环的聚合物 | 24969-26-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三氧烷
• 中文名称: 1,3,5-三氧杂环己烷与1,3-二氧戊环的聚合物
• 英文名称: 1,3-Dioxolane;1,3,5-trioxane
• CAS: 24969-26-4
• 化学式: C6H12O5
• 分子量: 164.16
• InChiKey: KAUOORLWKQFOHP-UHFFFAOYSA-N

物化性质

• 熔点：
  165-167 °C

计算性质

• 辛醇/水分配系数(LogP)：
  -0.09
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  46.2
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• UV curable non-crystalline acetal terpolymers
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0308045A2

  公开（公告）日：1989-03-22

  Ultraviolet curable terpolymers of trioxane, from at least 65 weight percent to about 75 weight percent of 1,3-dioxolane and from about 2 weight percent to about 20 weight percent of a monoethylenically unsaturated aliphatic diol formal having at least 4 carbon atoms in its main chain, e.g., 4,7-dehydro- 1,3-­dioxepin, which are non-crystalline at room temperature or above are disclosed. These terpolymers, when admixed with a multifunctional crosslinking monomer, e.g., a multifunctional acrylate such as 1,6-hexanediol diacrylate, and a photosensitizer, e.g., a benzoin compound such as benzoin isobutyl ether, can be cured to an insoluble, non-tacky, rubbery state using UV radiation. The thus-cured polymeric materials form useful crosslinked films, and when cryogenically ground to a suitable small particle size can be blended with conventionally prepared crystalline oxymethylene homo-, co- and terpolymers to improve the latters' impact properties.

  本发明公开了可紫外线固化的三元共聚物，其中三元共聚物包括至少 65% 至约 75% 重量百分比的 1,3-二氧戊环，以及约 2% 至约 20% 重量百分比的主链中至少有 4 个碳原子的单乙烯不饱和脂肪族二元醇形式，例如 4,7-脱氢- 1,3-二氧杂环庚烷，在室温或以上条件下为非结晶型。这些三元共聚物与多功能交联单体（如 1,6-己二醇二丙烯酸酯等多功能丙烯酸酯）和光敏剂（如安息香异丁醚等安息香化合物）混合后，可通过紫外线辐射固化成不溶解、不粘连的橡胶状态。这样固化的聚合材料可形成有用的交联薄膜，当低温研磨到合适的小粒径时，可与传统制备的结晶氧亚甲基均聚物、共聚物和三元共聚物混合，以改善后者的冲击性能。
• MODIFIED FLOW CATHETERS AND METHODS OF USE THEREOF
  申请人：SU Tsung-chow

  公开号：US20130253479A1

  公开（公告）日：2013-09-26

  A catheter includes an elongate body defining a continuous enclosed liquid flow channel, at least a portion of the liquid flow channel including a modification having a first surface and a second surface and an included volume between the first surface and the second surface, at least a portion of the included volume defining an elongated air flow channel, at least a portion of the first surface and the second surface coated with a hydrophobic (e.g., superhydrophobic) material. The catheter can be a urinary catheter (e.g., a urine drainage tube connected to a urine collection bag). Methods of flowing liquid through a catheter and of catheterizing a patient are encompassed.
• US4758608A
  申请人：——

  公开号：US4758608A

  公开（公告）日：1988-07-19