10-[4-[[4-(三氟甲基)苯基]二氮烯基]苯氧基]癸烷-1-硫醇 | 301841-85-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 中文名称: 10-[4-[[4-(三氟甲基)苯基]二氮烯基]苯氧基]癸烷-1-硫醇
• 英文名称: 10-(4-{(E)-[4-(Trifluoromethyl)phenyl]diazenyl}phenoxy)decane-1-thiol
• 英文别名: 10-[4-[[4-(trifluoromethyl)phenyl]diazenyl]phenoxy]decane-1-thiol
• CAS: 301841-85-0
• 化学式: C₂₃H₂₉F₃N₂OS
• 分子量: 438.557
• InChiKey: VRUWNMDGDQCTDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  30
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  35
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-(4'-trifluoromethylphenylazo)phenol 生成 10-[4-[[4-(三氟甲基)苯基]二氮烯基]苯氧基]癸烷-1-硫醇
  参考文献：
  名称：

  Optically Induced Switching of Azobenzene Containing Self Assembling Monolayers Investigated by Kelvin Probe and Scanning Force Microscopy

  摘要：

  The light induced switching of self-assembled monolayers containing azobenzenes is observed in situ by the Kelvin probe method. The switching process is optimized by preparing monolayers from mixed solutions of azobenzene thiols and n- alkylene thiols. In a film the efficiency of the E/Z-isomerization depends on both the spacer length between azobenzene group and gold surface as well as the free volume in the film, tuned by the n-alkylene thiol fraction in the mixture. An optimum was found in a mixed self-assembling film containing 33% 4-fluoromethyl-3'-(10-carboxy-decyloxy) azobenzene in a dodecane thiol matrix. The structure of the films were characterized by FTIR and AFM.

  DOI：

  10.1080/10587250108023673

文献信息

• Optically Induced Switching of Azobenzene Containing Self Assembling Monolayers Investigated by Kelvin Probe and Scanning Force Microscopy
  作者：B. Stiller、P. Karageorgiev、Th. Jüngling、D. Prescher、Th. Zetzsche、R. Dietel、G. Knochenhauer、L. Brehmer

  DOI：10.1080/10587250108023673

  日期：2001.1

  The light induced switching of self-assembled monolayers containing azobenzenes is observed in situ by the Kelvin probe method. The switching process is optimized by preparing monolayers from mixed solutions of azobenzene thiols and n- alkylene thiols. In a film the efficiency of the E/Z-isomerization depends on both the spacer length between azobenzene group and gold surface as well as the free volume in the film, tuned by the n-alkylene thiol fraction in the mixture. An optimum was found in a mixed self-assembling film containing 33% 4-fluoromethyl-3'-(10-carboxy-decyloxy) azobenzene in a dodecane thiol matrix. The structure of the films were characterized by FTIR and AFM.