[4-(2-Prop-2-enoyloxyethoxy)phenyl] 4-[(3-ethyloxetan-3-yl)methoxy]benzoate | 677033-38-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [4-(2-Prop-2-enoyloxyethoxy)phenyl] 4-[(3-ethyloxetan-3-yl)methoxy]benzoate
• CAS: 677033-38-4
• 化学式: C₂₄H₂₆O₇
• 分子量: 426.466
• InChiKey: NKXKLTPJGZHJQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  31
• 可旋转键数：
  13
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-(2-acryloyloxyethoxy)phenol 、 p-(3-ethyl-3-oxetanyl)methoxybenzoic acid 在 4-二甲氨基吡啶 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 生成 [4-(2-Prop-2-enoyloxyethoxy)phenyl] 4-[(3-ethyloxetan-3-yl)methoxy]benzoate
  参考文献：
  名称：

  DIOXETANE COMPOUND, CATIONICALLY POLYMERIZABLE COMPOSITION, OPTICAL FILM AND LIQUID CRYSTAL DISPLAY UNIT

  摘要：

  公开号：

  EP1990339B1

文献信息

• POLYMERIZABLE LIQUID-CRYSTAL COMPOSITION AND LIQUID-CRYSTAL FILM MADE FROM THE COMPOSITION
  申请人：Nippon Oil Corporation

  公开号：EP1803773A1

  公开（公告）日：2007-07-04

  A polymerizable liquid crystalline composition comprises a side chain liquid crystalline polymer obtained by radical-copolymerizing a (meth)acrylic compound has an optically active site and a (meth)acrylic compound having an oxetanyl group, and a cation generator and thus have no functional group the synthesis of which is difficult, such as an epoxy group. The use of the polymerizable liquid crystalline composition provides a cholesteric liquid crystal film which is excellent in a capability of retaining the orientation after being aligned and fixed in a liquid crystal orientation and in mechanical strength without the necessity of a complicated operation such as photo irradiation under an inert gas atmosphere.

  一种可聚合液晶组合物包含一种侧链液晶聚合物，该聚合物是通过将具有光学活性位点的（甲基）丙烯酸化合物和具有氧杂环丁酰基的（甲基）丙烯酸化合物与阳离子发生器进行自由基共聚而得到的，因此不含环氧基等难以合成的官能团。使用这种可聚合液晶组合物可以得到一种胆甾型液晶膜，这种膜在对齐和固定液晶取向后具有优异的取向保持能力和机械强度，而无需在惰性气体环境下进行光照射等复杂操作。
• LIQUID-CRYSTALLINE COMPOSITION WITH IMPROVED ADHESION, LIQUID-CRYSTAL FILM COMPRISING THE COMPOSITION, AND LIQUID-CRYSTAL DISPLAY ELEMENT EMPLOYING THE FILM
  申请人：Nippon Oil Corporation

  公开号：EP2006351A2

  公开（公告）日：2008-12-24

  The present invention provides a liquid crystal film with improved adhesivity to a tacky adhesive or an adhesive, formed from a liquid crystalline composition comprising a specific (meth)acrylic compound having an oxetane group and a liquid crystalline compound having an oxetane group.

  本发明提供了一种对粘性粘合剂或粘合剂具有更好粘合性的液晶膜，该液晶膜由液晶组合物形成，该液晶组合物包括具有氧杂环丁烷基团的特定（甲基）丙烯酸化合物和具有氧杂环丁烷基团的液晶化合物。
• (Meth)acrylic compound having an oxetanyl group and liquid crystal film produced by using the same
  申请人：Nippon Oil Corporation

  公开号：EP1405850B1

  公开（公告）日：2007-03-07
• DIOXETANE COMPOUND, CATIONICALLY POLYMERIZABLE COMPOSITION, OPTICAL FILM, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Seki Takashi

  公开号：US20090068379A1

  公开（公告）日：2009-03-12

  A novel dioxetane compound is provided having a cationically polymerizable oxetane group, which compound is excellent in compatibility with a liquid crystalline compound and a non-liquid crystalline compound. An optical film is also provided with excellent liquid crystal orientation retention properties and mechanical strength, produced by aligning a composition of the dioxetane compound and a cationically polymerizable compound in a liquid crystal orientation and fixing the liquid crystal orientation by polymerization. Further, a liquid crystal display device is provided with the optical film.
• Liquid Crystalline Composition with Improved Adhesivity, Liquid Crystal Film Comprising the Composition, and Liquid Crystal Display Device Equipped with the Film
  申请人：Seki Takashi

  公开号：US20090208673A1

  公开（公告）日：2009-08-20

  The present invention provides a liquid crystal film with improved adhesivity to a tacky adhesive or an adhesive, formed from a liquid crystalline composition comprising a specific (meth)acrylic compound having an oxetane group and a liquid crystalline compound having an oxetane group.