1-ferrocenylmethyl-1H-pyrazole | 873932-85-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: 1-ferrocenylmethyl-1H-pyrazole
• 英文别名: ferrocenylmethylpyrazole；1-N-ferrocenylmethylpyrazole；cyclopenta-1,3-diene;1-(cyclopenta-2,4-dien-1-ylmethyl)pyrazole;iron(2+)
• CAS: 873932-85-5
• 化学式: C₁₄H₁₄FeN₂
• 分子量: 266.126
• InChiKey: UZWCTCLVAGKFTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ag(OTf)(PPh3) 、 1-ferrocenylmethyl-1H-pyrazole 以 二氯甲烷 为溶剂， 以75%的产率得到[(ferrocenylmethylpyrazole)AgP(C6H5)3][CF3SO3]
  参考文献：
  名称：

  Gold and silver complexes with the ferrocenyl-pyrazolate ligand FcCH2pz

  摘要：

  We have synthesized a series of gold(l), gold(111) or silver(l) derivatives with ferrocenylmethylpyrazole (pzCH(2)Fc) as ligand. X-ray structure determination for [Au(C6F5)(pzCH(2)Fc)] reveals a linear geometry for the gold centre and association of the molecules in pairs through intermolecular gold(I)-gold(I) interactions of 3.1204(6) angstrom. These molecules are further assembled into chains and the chains into a 3D structure through several hydrogen bonds. [Ag(OTf)(pzCH(2)Fc)] (OTf = triflate) is a dimer with a distorted tetrahedral geometry at the silver(l) centre and the triflate acting as bridging ligand. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.02.017
• 作为产物：
  描述：

  吡唑 、 N,N-dimethylaminomethylferrocene 在 NaHCO₃ 作用下， 以 溶剂黄146 为溶剂， 以30%的产率得到1-ferrocenylmethyl-1H-pyrazole
  参考文献：
  名称：

  Gold and silver complexes with the ferrocenyl-pyrazolate ligand FcCH2pz

  摘要：

  We have synthesized a series of gold(l), gold(111) or silver(l) derivatives with ferrocenylmethylpyrazole (pzCH(2)Fc) as ligand. X-ray structure determination for [Au(C6F5)(pzCH(2)Fc)] reveals a linear geometry for the gold centre and association of the molecules in pairs through intermolecular gold(I)-gold(I) interactions of 3.1204(6) angstrom. These molecules are further assembled into chains and the chains into a 3D structure through several hydrogen bonds. [Ag(OTf)(pzCH(2)Fc)] (OTf = triflate) is a dimer with a distorted tetrahedral geometry at the silver(l) centre and the triflate acting as bridging ligand. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.02.017