[3,4-dimethyl-1-(trimethylsilylmethyl)-2,5-dihydrogermol-1-yl]methyl-trimethylsilane | 137161-95-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧磷杂环戊烷
• 英文名称: [3,4-dimethyl-1-(trimethylsilylmethyl)-2,5-dihydrogermol-1-yl]methyl-trimethylsilane
• CAS: 137161-95-6
• 化学式: C₁₄H₃₂GeSi₂
• 分子量: 329.169
• InChiKey: DFCSBLNOUBZADX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.54
• 重原子数：
  17.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  1,1,3,3-tetraneopentyl-2,2-bis(trimethylsilylmethyl)-1,3-disila-2-germapropane 以 四氢呋喃 、 乙醇 、 环己烷 、 苯 为溶剂， 生成 [3,4-dimethyl-1-(trimethylsilylmethyl)-2,5-dihydrogermol-1-yl]methyl-trimethylsilane
  参考文献：
  名称：

  Preparations, structures and photolyses of peralkyldisilagermirane and peralkylgermadisilaoxetane

  摘要：

  Three- and four-membered ring systems, peralkyldisilagermirane ([R(2)Si](2)GeR'(2) (1)) and peralkylgermadisilaoxetane ([R(2)SiGeR'(2)SiR(2)]O (2) (R = (t)BuCH(2);R' = Me(3)SiCH(2))) respectively were synthesized and characterized. The structures of 1 and 2 have been determined by X-ray crystallography. The ring of GeSi2O (2) is almost planar. The photolysis of 1 and 2 using a mercury lamp (lambda = 254 nm) gave mainly disilene and disilaoxirane respectively with extrusion of germylene.

  DOI：

  10.1016/0022-328x(95)05814-6

文献信息

• Photochemical decomposition of a new ring system containing one germanium atom: peralkyl-1-germa-2,3,4-trisilacyclobutanes
  作者：Hideo Suzuki、Kazutoshi Okabe、Reiko Kato、Norikazu Sato、Yoko Fukuda、Hamao Watanabe

  DOI：10.1039/c39910001298

  日期：——

  Photolysis of members, a new four-membered ring system containing one germanium atom, peralkylgermatrisilacyclobutanes, [R2Si]3Ge(CH2SiMe3)2(R = Pri, ButCH2), was found to afford the cyclotrisilane with extrusion of germylene (germanediyl).

  通过对含有一个锗原子的新四元环系统--全烷基锗三硅环丁烷 [R2Si]3Ge(CH2SiMe3)2（R = Pri，ButCH2）--的成员进行光解，发现在挤出锗二基（锗二基）后可得到环三硅烷。
• Suzuki, Hideo; Okabe, Kazutoshi; Kato, Reiko, Organometallics, 1993, vol. 12, # 12, p. 4833 - 4842
  作者：Suzuki, Hideo、Okabe, Kazutoshi、Kato, Reiko、Sato, Norikazu、Fukuda, Yoko、Watanabe, Hamao、Goto, Midori

  DOI：——

  日期：——
• Suzuki Hideo, Okabe Kazutoshi, Kato Reiko, Sato Norikazu, Fukuda Yoko, Wa+, Organometallics, 12 (1993) N 12, S 4833-4842
  作者：Suzuki Hideo, Okabe Kazutoshi, Kato Reiko, Sato Norikazu, Fukuda Yoko, Wa+

  DOI：——

  日期：——