butyl dipropylphosphinate | 16984-10-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦酸及其衍生物
• 英文名称: butyl dipropylphosphinate
• 英文别名: dipropyl-phosphinic acid butyl ester；Dipropyl-phosphinsaeure-butylester；Dipropylphosphinsaeure-butylester；Dipropylphosphonsaeure-butylester；1-dipropylphosphoryloxybutane
• CAS: 16984-10-4
• 化学式: C₁₀H₂₃O₂P
• 分子量: 206.265
• InChiKey: MGJKGKKAUKXOPR-UHFFFAOYSA-N

物化性质

• 沸点：
  90.5-91.5 °C(Press: 2.5 Torr)
• 密度：
  0.9389 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  butyl dipropylphosphinate 在 五氯化磷 作用下， 生成 dipropyl-phosphinic acid diethylamide
  参考文献：
  名称：

  Rasumow et al., Zhurnal Obshchei Khimii, 1957, vol. 27, p. 754,757; engl. Ausg. S. 827, 829

  摘要：

  DOI：
• 作为产物：
  描述：

  propyl-phosphinic acid butyl ester 在 sodium 作用下， 生成 butyl dipropylphosphinate
  参考文献：
  名称：

  Kabatschnik et al., Doklady Akademii Nauk SSSR, 1959, vol. 125, p. 1260

  摘要：

  DOI：

文献信息

• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Investigation in the series of phosphonic and phosphonous acid derivatives
  作者：A. I. Razumov、B. G. Liorber、I. V. Berezovskaya、T. A. Tarzivalova

  DOI：10.1007/bf00761339

  日期：1969.9

  Conclusions1.Esters and amides of diallylphosphonic acid and the isopropyl esters of dipropyl and dibutylphosphonic acids were synthesized.2.The antidote effect of certain esters of diallylphosphonic acid was studied.3.Antidotes of anticholinesterase materials were found among organophosphorous compounds of low toxicity. The mechanism of the antidote effect was established in relation to octamethyl

  结论1.合成了二烯丙基膦酸的酯类和酰胺类以及二丙基和二丁基膦酸的异丙酯。2.研究了某些二烯丙基膦酸酯的解毒作用。3.在低毒有机磷化合物中发现了抗胆碱酯酶物质的解毒剂。解毒剂作用的机制是通过“直接”作用与八甲基酯酶和抗胆碱酯酶相关的。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP3144064A2

  公开（公告）日：2017-03-22

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons.

  一种由钯和有机磷化合物组成的载体加氢催化剂组成的组合物，该载体加氢催化剂能选择性地将高度不饱和烃加氢为不饱和烃。
• Mastrjukowa; Schipow; Kabatschnik, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 1450,1451
  作者：Mastrjukowa、Schipow、Kabatschnik

  DOI：——

  日期：——
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP2403642A2

  公开（公告）日：2012-01-11