氢六氟锑酸盐 | 16950-06-4

• 物质功能分类: 无机化工 - 无机盐 - 金属卤化物及卤酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 类金属盐
• 中文名称: 氢六氟锑酸盐
• 中文别名: 六氟锑酸(V)；氟锑酸；六氟偶锑酸氢(V)
• 英文名称: hexafluoroantimonic acid
• 英文别名: fluoroantimonic acid；Antimonate(1-), hexafluoro-, hydrogen, (OC-6-11)-；antimony(5+);hydron;hexafluoride
• CAS: 16950-06-4
• 化学式: FH*F₅Sb
• 分子量: 236.748
• InChiKey: MBAKFIZHTUAVJN-UHFFFAOYSA-I

物化性质

• 熔点：
  20°C
• 密度：
  2.885 g/mL at 25 °C(lit.)
• 暴露限值：
  ACGIH: TWA 0.5 mg/m3NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
• 稳定性/保质期：
  在常温常压下稳定，避免与水溶液、碱金属、碱土金属以及许多有机和无机活性化学药品接触。

计算性质

• 辛醇/水分配系数(LogP)：
  1.87
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  1
• 氢受体数：
  6

安全信息

• TSCA：
  Yes
• 危险等级：
  8
• 危险品标志：
  Xn,C,N
• 安全说明：
  S61
• 危险类别码：
  R20/22,R51/53
• WGK Germany：
  2
• 危险品运输编号：
  UN 2922 8/PG 2
• 包装等级：
  II
• 危险类别：
  8
• 储存条件：
  常温下应密闭避光保存，并放置于通风、干燥处。

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : Fluoroantimonic acid
CAS-No. : 16950-06-4
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute toxicity, Oral (Category 2)
Acute toxicity, Inhalation (Category 2)
Acute toxicity, Dermal (Category 1)
Skin corrosion (Category 1A)
Chronic aquatic toxicity (Category 2)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Very toxic by inhalation, in contact with skin and if swallowed. Causes severe burns. Toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic environment.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Danger
Hazard statement(s)
H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P284 Wear respiratory protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
Supplemental Hazard none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.
R35 Causes severe burns.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S28 After contact with skin, wash immediately with plenty of water.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/ Safety
data sheets.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : HF6Sb
Molecular Weight : 236,76 g/mol
Component Concentration
Fluoroantimonic acid
CAS-No. 16950-06-4 -
EC-No. 241-023-8
Index-No. 051-003-00-9

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Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take
victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
Headache, Nausea
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Special hazards arising from the substance or mixture
Nature of decomposition products not known.
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
The product itself does not burn.

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate
personnel to safe areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Specific end use(s)
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: colourless
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point not applicable
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure 19 hPa at 18 °C
207 hPa at 47 °C
l) Vapour density no data available
m) Relative density 2,885 g/cm3 at 25 °C
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong bases, Alcohols, glass, Keep away from water., Metals
Hazardous decomposition products
Other decomposition products - no data available

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be fatal if inhaled. Material is extremely destructive to the tissue of the
mucous membranes and upper respiratory tract.
Ingestion May be fatal if swallowed. Causes burns.
Skin May be fatal if absorbed through skin. Causes skin burns.
Eyes Causes eye burns.
Signs and Symptoms of Exposure
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
Headache, Nausea
Additional Information
RTECS: Not available

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
Toxic to aquatic life with long lasting effects.

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: 2922 IMDG: 2922 IATA: 2922
UN proper shipping name
ADR/RID: CORROSIVE LIQUID, TOXIC, N.O.S. (Fluoroantimonic acid)
IMDG: CORROSIVE LIQUID, TOXIC, N.O.S. (Fluoroantimonic acid)
IATA: Corrosive liquid, toxic, n.o.s. (Fluoroantimonic acid)
Transport hazard class(es)
ADR/RID: 8 (6.1) IMDG: 8 (6.1) IATA: 8 (6.1)
Packaging group
ADR/RID: I IMDG: I IATA: I
Environmental hazards
ADR/RID: yes IMDG Marine Pollutant: yes IATA: no
Special precautions for user
no data available

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Section 15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available

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Section 16. OTHER INFORMATION
Further information
Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

制备方法与用途

HF/SbF₅是一种出色的介质，用于制备亚烷基氧盐。

反应信息

• 作为反应物：
  描述：

  氢六氟锑酸盐 生成 五氟化锑
  参考文献：
  名称：

  Ruff, O.; Graf, H.; Heller, W., Chemische Berichte, 1906, vol. 39, p. 4312

  摘要：

  DOI：
• 作为产物：
  描述：

  五氟化锑 生成 氢六氟锑酸盐
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: MVol.B2, 8.5, page 405 - 408

  摘要：

  DOI：
• 作为试剂：
  描述：

  γ-己内酯 、 一氧化碳 在 氢六氟锑酸盐 作用下， 反应 1.0h， 以96%的产率得到2-甲基己二酸
  参考文献：
  名称：

  CARBOXYLATION OF γ-BUTYROLACTONES WITH CARBON MONOXIDE USING HF–SbF₅SUPER ACID

  摘要：

  在含有过量 SbF5 的 HF-SbF5 超酸介质中，γ-丁内酯在 -20 至 30 °C、常压条件下与一氧化碳反应，生成二羧酸，产率良好。

  DOI：

  10.1246/cl.1981.767

文献信息

• N-fluorotriazinium fluorinating agents
  申请人：——

  公开号：US20020123627A1

  公开（公告）日：2002-09-05

  Novel N-fluorotriazinium electrophilic fluorinating agents have the Formula I: 1 wherein three A moieties are independently CR, where each R is, independently, hydrogen, halogen, hydroxyl, (primary, secondary or tertiary) amino, amino, cyano, perfluorothio, hydroxysulfonyl, halosulfonyl, hydrocarbyloxysulfonyl, or a carbon-containing substituent selected from the group consisting of optionally substituted hydrocarbyl, hydrocarbyloxy, hydrocarbyloxycarbonyl, and hydrocarbylthio groups, and at least one R is neither hydrogen nor halogen; two A moieties are independently Z, where each Z is independently nitrogen or a quaternary nitrogen atom and Y is a counterion or group of counterions which are inert to chemical attack by fluorine, or adjacent triazinium moieties are linked by a common R substituent to provide an oligomer or polymer. Preferably the compounds are 1,3,5-triazinium compound in which all R are the same, optionally perfluorinated, alkyl or alkoxy groups; Z 1 and Z 2 are both nitrogen and Y − is triflate. Compounds of Formula I are especially useful in fluorinating carbanionic species or activated aromatic compounds.

  新型N-氟三唑基电泳氟化试剂具有I式：1其中三个A基团独立地为CR，其中每个R独立地为氢、卤素、羟基、（一级、二级或三级）氨基、氨基、氰基、全氟硫基、羟基磺酰基、卤代磺酰基、烃氧基磺酰基或从可选取的含碳取代基团组中选择的含碳取代基团，该组包括可选取的取代的烃基、烃氧基、烃氧羰基和烃硫基基团，并且至少有一个R既不是氢也不是卤素；两个A基团独立地为Z，其中每个Z独立地为氮或季铵氮原子，Y为对氟化学攻击惰性的反离子或反离子组，并且相邻的三唑基团通过共同的R取代基连接以提供寡聚体或聚合物。优选地，化合物是所有R都相同的1,3,5-三唑基化合物，可选地是全氟化的烷基或烷氧基基团；Z1和Z2均为氮，Y-为三氟甲磺酸盐。I式化合物在氟化碳负离子物种或活性芳香化合物方面特别有用。
• Electrophilic fluorination
  申请人：——

  公开号：US20020123657A1

  公开（公告）日：2002-09-05

  N-fluorotriazinium salts, especially those of the following Formula I, are electrophilic fluorinating agents useful in fluorinating, preferably in a nitromethane solvent, carbanionic species and/or activated aromatic compounds: 1 wherein three A moieties are independently CR, where each R is, independently, hydrogen, halogen, (primary, secondary or tertiary) amino, hydroxyl, amino, cyano, perfluorothio hydroxysulfonyl, halosulfonyl, hydrocarbyloxysulfonyl, or a carbon-containing substituent selected from the group consisting of optionally substituted hydrocarbyl, hydrocarbyloxy, hydrocarbyloxycarbonyl, and hydrocarbylthio groups; two A moieties are independently Z, where each Z is independently nitrogen or a quaternary nitrogen atom and Y is a counterion or group of counterions which are inert to chemical attack by fluorine, and oligomers or polymers thereof in which adjacent triazinium moieties are linked by a common R substituent. Preferably the cation of the salt is 2,4,6-trichloro-1,3,5-triazinium.

  N-氟三唑铵盐，特别是以下式I的盐，在氟化反应中是电亲性氟化试剂，在氟化时特别是在硝基甲烷溶剂中，用于氟化碳负离子物种和/或活化芳香族化合物： 其中三个A基团独立地是CR，其中每个R独立地是氢、卤素、（一级、二级或三级）氨基、羟基、氨基、氰基、全氟硫代羟基磺酰基、卤代磺酰基、烃氧基磺酰基，或者是从可选择取代的烃基、烃氧基、烃氧羰基和烃硫基组成的群中选取的含碳取代基；两个A基团独立地是Z，其中每个Z独立地是氮或者是一个季铵氮原子，Y是一个或一组对氟化学攻击惰性的对离子或对离子基团，以及其寡聚物或聚合物，其中相邻的三唑铵基团由共同的R取代基连接。最好是盐的阳离子是2,4,6-三氯-1,3,5-三唑铵。
• Method of forming cavity between multilayered wirings
  申请人：JSR Corporation

  公开号：US20040132243A1

  公开（公告）日：2004-07-08

  A method of forming a cavity between metallic wirings using a polymer capable of revealing a specific heat resistant temperature and a specific heat decomposition temperature by having a specific repeating unit structure and a specific molecular weight range and of readily forming a cavity structure between metallic wirings in, for example, semiconductors. The method comprises a step of coating the surface of a first dielectric film formed on a semiconductor substrate with a cyclic olefin based addition polymer, a step of patterning the cyclic olefin based addition polymer as a void-forming polymer, a step of forming a metallic wiring in the pattern formed on the void-forming polymer, a step of forming a second dielectric film on the void-forming polymer containing a metallic wiring, and a step of removing the void-forming polymer between the multilayered wirings by heating to form a cavity between the metallic wirings.

  一种利用具有特定重复单元结构和特定分子量范围的聚合物，通过具有特定耐热温度和特定热分解温度的能力来形成金属导线之间空腔的方法，例如在半导体中容易形成空腔结构。该方法包括以下步骤：在半导体衬底上形成第一介电膜的表面上涂覆环状烯基加成聚合物；将环状烯基加成聚合物作为形成空腔的聚合物进行图案化；在形成的空腔聚合物图案上形成金属导线；在包含金属导线的空腔聚合物上形成第二介电膜；通过加热去除多层金属导线之间的空腔聚合物，形成金属导线之间的空腔。
• Cycloolefin addition copolymer and optical transparent material
  申请人：Oshima Noboru

  公开号：US20050171310A1

  公开（公告）日：2005-08-04

  A cyclic olefin addition copolymer obtained by copolymerizing a cyclic olefin compound having a side chain substituent group with a ring structure, such as endo-tricyclo[4.3.0.1 2,5 ]deca-3,7-diene or endo-tricyclo-[4.3.0.1 2,5 ]deca-3-ene, with another cyclic olefin compound such as bicyclo[2.2.1]hept-2-ene, and further with a cyclic olefin compound having a hydrolysable silyl group as needed, or hydrogenating after copolymerization; a composition for crosslinking in which a specific crosslinking agent is incorporated; a crosslinked product obtained by crosslinking the composition; an optical material containing the copolymer, the composition or the crosslinked product; and a method for producing the copolymer in which addition polymerization is conducted using a specific nickel catalyst.

  通过共聚合具有侧链取代基的环烯化合物与另一种环烯化合物共聚合得到的环烯加成共聚物，例如内向三环[4.3.0.1 2,5]癸-3,7-二烯或内向三环[4.3.0.1 2,5]癸-3-烯，再加入需要的具有可水解硅基团的环烯化合物或在共聚合后进行氢化; 包含特定交联剂的交联组合物; 通过交联组合物交联得到的交联产物; 包含共聚物、组合物或交联产物的光学材料; 以及使用特定的镍催化剂进行加成聚合的制备环烯共聚物的方法。
• Olah, George A.; Rasul, Golam; Aniszfeld, Robert, Journal of the American Chemical Society, 1992, vol. 114, # 14, p. 5608 - 5609
  作者：Olah, George A.、Rasul, Golam、Aniszfeld, Robert、Surya Prakash

  DOI：——

  日期：——