Triethoxyphosphazen-N-phosphoryldiethylester | 2397-48-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Triethoxyphosphazen-N-phosphoryldiethylester
• 英文别名: triethyl diethoxyphosphinylimidophosphate；Triethyl diethoxyphosphinylimdophosphate；diethoxyphosphoryl-phosphorimidic acid triethyl ester；μ-nitrido-diphosphoric acid pentaethyl ester；N-Triethoxyphosphoranyliden-phosphorsaeure-diethylester-amid；Triethoxyphosphoranyliden-amidophosphorsaeure-diethylester；Phosphorimidic acid, (diethoxyphosphinyl)-, triethyl ester；diethoxyphosphorylimino(triethoxy)-λ5-phosphane
• CAS: 2397-48-0
• 化学式: C₁₀H₂₅NO₆P₂
• 分子量: 317.259
• InChiKey: WUURFNFFHABUBJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.6
• 氢给体数：
  0
• 氢受体数：
  7

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  Triethoxyphosphazen-N-phosphoryldiethylester 在 盐酸 作用下， 生成 N,N-bis(diethoxyphosphino)-N-methylamine
  参考文献：
  名称：

  On imides op the phosphorus acids

  摘要：

  DOI：

  10.1007/bf00909162
• 作为产物：
  描述：

  sodium ethanolate 在 dichlorophosphinylphosphorimidic trichloride 作用下， 以 乙醇 、 苯 为溶剂， 生成 Triethoxyphosphazen-N-phosphoryldiethylester
  参考文献：
  名称：

  Synthesis of trialkyl (dialkoxyphosphorylimido)phosphates

  摘要：

  DOI：

  10.1007/bf00951012

文献信息

• Ethyl ester and silyl ester of imidodiphosphate: An alternative route to access phosphorus-nitrogen-phosphorus bonds via Staudinger reaction
  作者：Jia En Low、Joëlle Levalois-Grützmacher

  DOI：10.1002/hc.21413

  日期：2018.1

  AbstractWe present herein an alternative synthesis route to obtain tetraethyl imidodiphosphate (EtO)2P(O)NH(O)P(OEt)2 (3) and its silylester derivative tetrakis(trimethylsilyl) imidodiphosphate (Me3SiO)2P(O)NH(O)P(OSiMe3)2 (4) involving a phosphorazidate intermediate (1) and the Staudinger reaction. Compared to previous methods, this synthesis route is simpler, more atom efficient, and energetically inexpensive. Moreover, the final compounds are obtained with larger yield and higher purity.
• Complexes of imidophosphoric compounds with BF3
  作者：V. A. Gilyarov、E. I. Matrosov、M. I. Kabachnik

  DOI：10.1007/bf00958009

  日期：1991.3

  IR, P-31 NMR and F-19 NMR spectroscopy was used to study triphenylphosphinimines with substituents at the nitrogen atom and their complexes with boron trifluoride. In the case of aryl or benzyl substituents, BF3 adds to the nitrogen atom, while the state of the phosphorus atom is close to phosphonium. An analogous structure of the intermediate complexes is proposed upon the catalysis of the imide-amide rearrangement by BF3. The introduction of acyl groups such as phosphoryl, thiophosphoryl, and methanesulfonyl groups to the nitrogen atom of the triphenylphosphinimine alters the site of attachment of BF3, which is found at the oxygen atoms of the P = 0 or SO2 groups or to the sulfur atom of the P = S group.
• XODAK A. A.; GILYAROV V. A.; SHCHERBINA T. M.; KABACHNIK M. I., IZV. AN CCCP. CEP. XIM., 1979, HO 8, 1884-1886
  作者：XODAK A. A.、 GILYAROV V. A.、 SHCHERBINA T. M.、 KABACHNIK M. I.

  DOI：——

  日期：——
• STEINBACH, J.;RIESEL, L.;HERRMANN, E.
  作者：STEINBACH, J.、RIESEL, L.、HERRMANN, E.

  DOI：——

  日期：——
• RIESEL, L.;STEINBACH, J.;HERRMANN, E., Z. ANORG. UND ALLG. CHEM., 1983, 502, N 7, 21-28
  作者：RIESEL, L.、STEINBACH, J.、HERRMANN, E.

  DOI：——

  日期：——