4'-methacryloxy-4-nitroazobenzene | 41079-23-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 4'-methacryloxy-4-nitroazobenzene
• 英文别名: 4-(p-Nitrophenylazo)phenylmethacrylat；[4-[(4-Nitrophenyl)diazenyl]phenyl] 2-methylprop-2-enoate
• CAS: 41079-23-6
• 化学式: C₁₆H₁₃N₃O₄
• 分子量: 311.297
• InChiKey: SPIMJXMGRSNQIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  96.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-羟基-4-硝基偶氮苯 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以69%的产率得到4'-methacryloxy-4-nitroazobenzene
  参考文献：
  名称：

  Photoinduced Spatial Orientational Order in Methacrylic Azopolymers

  摘要：

  DOI：

  10.1080/15421400701229487

文献信息

• Spacer Length Influence on the Electrooptic Effect of Methacrylic Azopolymer Series
  作者：O. N. Nadtoka、N. A. Davidenko、S. L. Studzinsky、V. G. Syromyatnikov

  DOI：10.1080/15421400802463068

  日期：2008.12.3

  Methacrylic azopolymers with different spacer lengths in side chains have been synthesized. The spectra and kinetics of the electrooptic effect which arises in azo-polymer films after their irradiation by linearly polarized light are investigated. The photo-induced optical anisotropy in the films appears due to a change of the concentration ratio of trans- and cis-isomers of azobenzene fragments. This explains the nature of the electrooptic effect. Owing to a mobility increment of azobenzene fragments by means of the spacer extension, the electrooptic effect becomes more pronounced, and its relaxation time decreases.
• OIL REPELLENT COPOLYMER, METHOD FOR ITS PRODUCTION AND OIL REPELLENT TREATMENT SOLUTION
  申请人：Hoshino Taiki

  公开号：US20090281239A1

  公开（公告）日：2009-11-12

  To provide an oil repellent copolymer capable of forming an oil repellent film which is excellent in durability. An oil repellent copolymer characterized by comprising a repeating unit (A) having a polyfluoroalkyl group, a repeating unit (B) having a fluorescent functional group, and a repeating unit (C) having an ester bond other than an ester bond derived from acrylic acid, and/or a hydroxyl group.
• US8338529B2
  申请人：——

  公开号：US8338529B2

  公开（公告）日：2012-12-25
• Photoinduced Spatial Orientational Order in Methacrylic Azopolymers
  作者：Oksana Nadtoka、Vladimir Syromyatnikov、Lidiya Olkhovik、Oleg Yaroshchuk、Tetyana Bidna

  DOI：10.1080/15421400701229487

  日期：2007.6.11